Mesoporous TiO2/SBA-15, and Cu/TiO2/SBA-15 Composite Photocatalysts for Photoreduction of CO2 to Methanol
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A series of mesoporous TiO2/SBA-15, Cu/TiO2 and Cu/TiO2/SBA-15 composite photocatalysts were prepared by sol–gel synthesis for photoreduction of CO2 with H2O to methanol. It was found that optimum amount of titanium loading of TiO2/SBA-15 was 45 wt% which exhibited higher photoreduction activity than pure TiO2. An addition of copper on TiO2 or TiO2/SBA-15 catalyst as cocatalyst was found to enhance the catalytic activity because copper serves as an electron trapper and prohibits the recombination of hole and electron.
KeywordsTitanium dioxide Mesoporous silica SBA-15 Carbon dioxide Photoreduction
The authors would like to express thanks to the National Science Council, Taiwan, Republic of China (NSC 97-2221-E-259-016).