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Perovskite-Like Mixed Oxides (LaSrMn1−x Ni x O4+δ, 0 ≤ x ≤ 1) as Catalyst for Catalytic NO Decomposition: TPD and TPR Studies

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Abstract

Catalytic NO decomposition on LaSrMn1−x Ni x O4+δ (0 ≤ x ≤ 1) is investigated. The activity of NO decomposition increases dramatically after the substitution of Ni for Mn, but decreases when Mn is completely replaced by Ni (x = 1.0). The optimum value is at x = 0.8. These indicate that the catalytic performance of the samples is contributed by the synergistic effect of Mn and Ni. O2-TPD and H2-TPR experiments are carried out to explain the change of activity. The former indicates that only when oxygen vacancy is created, could the catalyst show enhanced activity for NO decomposition; the latter suggests that the best activity is obtained from catalyst with the most matched redox potentials (in this work, the biggest ΔT and ΔE values). The close relationships between activity and ΔT or ΔE indicate that ΔT and ΔE are important parameters of catalyst for NO decomposition.

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Acknowledgments

Financial support from the Ministry of science and technology of China (2001AA 324060) and the Natural science foundation of China (20177022) is greatly appreciated.

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Authors and Affiliations

  1. Laboratory of Green Chemistry and Process, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 130022, Changchun, China

    Junjiang Zhu, Dehai Xiao, Jing Li & Xiangguang Yang

  2. Laboratory of Catalysis and Materials, Department of Chemical Engineering, Faculty of Engineering, University of Porto, 4200-465, Porto, Portugal

    Junjiang Zhu

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  1. Junjiang Zhu
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  2. Dehai Xiao
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  3. Jing Li
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  4. Xiangguang Yang
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Correspondence to Junjiang Zhu.

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Zhu, J., Xiao, D., Li, J. et al. Perovskite-Like Mixed Oxides (LaSrMn1−x Ni x O4+δ, 0 ≤ x ≤ 1) as Catalyst for Catalytic NO Decomposition: TPD and TPR Studies. Catal Lett 129, 240–246 (2009). https://doi.org/10.1007/s10562-008-9807-8

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  • DOI: https://doi.org/10.1007/s10562-008-9807-8

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