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Preparation of Highly Dispersive and Stable Platinum Catalysts Supported on Siliceous SBA-15 Mesoporous Material: Roles of Titania Layer Incorporation and Hydrogen Peroxide Treatment

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Abstract

Roles of titania layer incorporation and hydrogen peroxide treatment in the preparation of highly dispersed platinum catalysts supported on siliceous SBA-15 mesoporous materials were studied by examining the catalysts at each step of the preparation. XRD, TEM, XPS, Raman, IR, CO chemisorptions, EXAFS and XANES techniques were employed to the investigation of the physico-chemical states of platinum and titanium. The platinum particles were uniformly dispersed on SBA-15 ranged from 1 to 2 nm in size by incorporating titania onto the surface of SBA-15 and then treating the impregnating platinum precursor with hydrogen peroxide, even at platinum loading as high as 4 wt.%. The platinum catalysts showed considerably higher catalytic activity in the combustion reactions of both carbon monoxide and methane, suggesting a suitable catalyst for purifying diesel engine exhaust.

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Acknowledgements

This work is a part of the project “Development of Partial Zero Emission Technology for Future Vehicles” funded by the Ministry of Knowledge Economy and we are grateful for its financial support. We acknowledge the Pohang Accelerator Laboratory (PAL) for the XAS measurement.

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Authors and Affiliations

  1. School of Applied Chemical Engineering and Center for Functional Nano Fine Chemicals, Chonnam National University, Youngbong-Dong 300, Gwangju, 500-757, Republic of Korea

    Mi-Young Kim, Se Bi Jung & Gon Seo

  2. Pohang Accelerator Laboratory, San-31 Hyoja-Dong, Pohang, Kyungbuk, 790-784, Republic of Korea

    Min Gyu Kim

  3. Heesung Catalysts Corp., 1251-6 Jungwang-Dong, Shihung, Geonggi, 429-450, Republic of Korea

    Young San You

  4. Department of Chemical Engineering, Chungbuk National University, Cheongju, Chungbuk, 361-763, Republic of Korea

    Jung-Hyun Park & Chae-Ho Shin

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  1. Mi-Young Kim
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  2. Se Bi Jung
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  3. Min Gyu Kim
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  4. Young San You
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  5. Jung-Hyun Park
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  7. Gon Seo
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Correspondence to Gon Seo.

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Kim, MY., Jung, S.B., Kim, M.G. et al. Preparation of Highly Dispersive and Stable Platinum Catalysts Supported on Siliceous SBA-15 Mesoporous Material: Roles of Titania Layer Incorporation and Hydrogen Peroxide Treatment. Catal Lett 129, 194–206 (2009). https://doi.org/10.1007/s10562-008-9790-0

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  • DOI: https://doi.org/10.1007/s10562-008-9790-0

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