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Suzuki Cross-Coupling Reaction Catalyzed by the Palladium Complex Pd[N-MorphC(S)NP(O)(OiPr)2-O,S]2

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Abstract

Suzuki cross-coupling reaction between phenyl bromide and phenylboronic acid, catalyzed by the palladium complex Pd[N-MorphC(S)NP(O)(OiPr)2-1,5-O,S)]2 in acetonitrile, toluene, THF or DMF has been investigated. Bases employed for the reaction were Na2CO3, K2CO3 or Cs2CO3. Varying largely the experimental conditions we found that excellent yields of the product were obtained using toluene and K2CO3 at 100 °C at the catalyst amount of 0.02 mmol.

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Acknowledgments

This work was supported by the joint program of CRDF and the Russian Ministry of Education and Science (BRHE 2008 Y5-C-07-09); Russian Science Support Foundation. DAS and MGB thank DAAD for the scholarships (Forschungsstipendien 2008/2009).

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Authors and Affiliations

  1. A. M. Butlerov Chemistry Institute, Kazan State University, Kremlevskaya St. 18, 420008, Kazan, Russian Federation

    Damir A. Safin & Maria G. Babashkina

  2. Institut für Anorganische Chemie, Universität zu Köln, Greinstrasse 6, 50939, Cologne, Germany

    Damir A. Safin, Maria G. Babashkina & Axel Klein

Authors
  1. Damir A. Safin
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  2. Maria G. Babashkina
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  3. Axel Klein
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Correspondence to Damir A. Safin.

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Safin, D.A., Babashkina, M.G. & Klein, A. Suzuki Cross-Coupling Reaction Catalyzed by the Palladium Complex Pd[N-MorphC(S)NP(O)(OiPr)2-O,S]2 . Catal Lett 129, 363–366 (2009). https://doi.org/10.1007/s10562-008-9778-9

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  • DOI: https://doi.org/10.1007/s10562-008-9778-9

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