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Influence of the Reaction Temperature on the 3-Hexyne Semi-Hydrogenation Catalyzed by a Palladium(II) Complex

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Abstract

The dichlorobis (tridecylamine) palladium(II) complex, pure and supported on γ-Al2O3, was used as catalyst for the semi-hydrogenation of 3-hexyne. The complex was characterized by centesimal composition, XPS and IR. The influence of the temperature was studied. The supported Pd complex resulted an active and stereo selective system for the production of (Z)-3-hexene.

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Acknowledgments

Financial support by UNL, CONICET and ANPCyT, and the donation of FTIR and XPS equipment by JICA, are acknowledged. The authors also acknowledge José Paredes for technical support.

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Authors and Affiliations

  1. Química Inorgánica, Departamento de Química, Facultad de Ingeniería Química, Universidad Nacional Del Litoral (UNL), 3000 Santiago del Estero, Santa Fe, 2829, Argentina

    D. A. Liprandi, E. A. Cagnola, M. E. Quiroga & P. C. L’Argentière

  2. INCAPE, Instituto de Investigaciones en Catálisis y Petroquímica (FIQ-UNL, CONICET), 3000 Santiago del Estero, Santa Fe, 2654, Argentina

    M. E. Quiroga & P. C. L’Argentière

Authors
  1. D. A. Liprandi
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  2. E. A. Cagnola
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  3. M. E. Quiroga
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  4. P. C. L’Argentière
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Correspondence to D. A. Liprandi.

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Liprandi, D.A., Cagnola, E.A., Quiroga, M.E. et al. Influence of the Reaction Temperature on the 3-Hexyne Semi-Hydrogenation Catalyzed by a Palladium(II) Complex. Catal Lett 128, 423–433 (2009). https://doi.org/10.1007/s10562-008-9768-y

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  • DOI: https://doi.org/10.1007/s10562-008-9768-y

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