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Magnetic Polymer Nanospheres Immobilizing Metalloporphyrins. Catalysis and Reuse to Hydroxylate Cyclohexane with Molecular Oxygen

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Abstract

Magnetic polymer nanospheres immobilizing Co(II) porphyrin or Mn(III) porphyrin were synthesized and their catalytic activities in hydroxylating cyclohexane were comparably investigated. The catalytic results have shown that these magnetic nanospheres are highly efficient and recyclable catalysts and the nanospheres with Mn(III) porphyrin are more active than those with Co(II) porphyrin.

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Acknowledgments

We are grateful to the supports of Guangzhou Municipality Science & Technology Bureau of China, the National Natural Science Foundation of China and National Key Foundation Research Development Project (973) Item of China (No. 2007 CB815306).

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Authors and Affiliations

  1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering & State Key Laboratory of Optoelectronic Material and Technologies, Sun Yat-Sen University, Guangzhou, 510275, People’s Republic of China

    Bo Fu, Ping Zhao, Han-Cheng Yu, Jin-Wang Huang, Jie Liu & Liang-Nian Ji

  2. The Key Laboratory of Gene Engineering of Ministry of Education, Sun Yat-Sen University, Guangzhou, 510275, People’s Republic of China

    Liang-Nian Ji

Authors
  1. Bo Fu
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  2. Ping Zhao
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  3. Han-Cheng Yu
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  4. Jin-Wang Huang
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  5. Jie Liu
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  6. Liang-Nian Ji
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Correspondence to Jin-Wang Huang.

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Fu, B., Zhao, P., Yu, HC. et al. Magnetic Polymer Nanospheres Immobilizing Metalloporphyrins. Catalysis and Reuse to Hydroxylate Cyclohexane with Molecular Oxygen. Catal Lett 127, 411–418 (2009). https://doi.org/10.1007/s10562-008-9715-y

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  • DOI: https://doi.org/10.1007/s10562-008-9715-y

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