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Slurry Impregnation of ZrO2 Extrudates: Controlled EggShell Distribution of MoO3, Hydrodesulfurization Activity, Promotion by Co

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Abstract

Catalysts with eggshell/uniform Mo concentration profiles were prepared by a reaction of ZrO2 and ZrO(OH)2 extrudates with an aqueous slurry of MoO3. The thickness of the shell was regulated by the amount of MoO3. CoCO3 was adsorbed onto MoO3/ZrO2 from its aqueous slurry. The ZrO2-supported catalysts were compared to their TiO2-supported and industrial reference Al2O3-supported counterparts in a model reaction of benzothiophene hydrodesulfurization.

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Acknowledgment

The financial support of the Grant Agency of the Czech Republic is gratefully acknowledged (Grants No. 104/06/P034 and 104/06/0705).

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Authors and Affiliations

  1. Institute of Chemical Process Fundamentals of the Academy of Sciences of the Czech Republic, v.v.i., Rozvojová 135, Suchdol, Prague 6, 165 02, Czech Republic

    Luděk Kaluža & Miroslav Zdražil

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  1. Luděk Kaluža
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  2. Miroslav Zdražil
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Correspondence to Luděk Kaluža.

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Kaluža, L., Zdražil, M. Slurry Impregnation of ZrO2 Extrudates: Controlled EggShell Distribution of MoO3, Hydrodesulfurization Activity, Promotion by Co. Catal Lett 127, 368–376 (2009). https://doi.org/10.1007/s10562-008-9692-1

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  • DOI: https://doi.org/10.1007/s10562-008-9692-1

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