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Convenient Synthesis of Ferrocenylethynyl Ketones via Carbonylative Coupling of Ferrocenylethyne with Aryl Iodides by Using Water as Solvent

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Abstract

Carbonylative coupling reaction of aryl iodides with ferrocenylethyne catalyzed by PdCl2 was carried out using sodium dodecyl sulphonate (SDS) as surfactant and water as solvent. The reaction gave much better yields of aryl ferrocenylethynyl ketones, which proceeded for 6 h at room temperature under a balloon pressure of carbon monoxide with Et3 N as base.

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Acknowledgments

The authors are grateful to the project sponsored by the Scientific Research Foundation for the State Education Ministry (No. 107108).

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Authors and Affiliations

  1. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, 730000, Lanzhou, People’s Republic of China

    Chonglong Li, Xiaolong Li, Qianqian Zhu, Hongyun Cheng, Qianru Lv & Baohua Chen

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  1. Chonglong Li
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  2. Xiaolong Li
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  3. Qianqian Zhu
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  4. Hongyun Cheng
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  5. Qianru Lv
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  6. Baohua Chen
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Correspondence to Baohua Chen.

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Li, C., Li, X., Zhu, Q. et al. Convenient Synthesis of Ferrocenylethynyl Ketones via Carbonylative Coupling of Ferrocenylethyne with Aryl Iodides by Using Water as Solvent. Catal Lett 127, 152–157 (2009). https://doi.org/10.1007/s10562-008-9661-8

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  • DOI: https://doi.org/10.1007/s10562-008-9661-8

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