Abstract
Manganese(II) complexes {[MnII(bpy)2 2+]MeCN} in acetonitrile activate dioxygen for the oxidation of limonene to produce mainly carvone, carveol, limonene oxide, and perillaldehyde. The reaction efficiencies after 24 h reaction time are approximately 5-times higher than those obtained for analogous iron(II) complexes. However, the 5 h long induction period is observed for the common conditions of the reaction. The simultaneous presence of the catalyst, dioxygen and the substrate is necessary for the active species to be formed. When t-BuOOH is present in the reaction mixture, the induction period does not appear. In contrast, the replacement of t-BuOOH by HOOH completely inhibits the reaction. We have proposed a putative mechanism in which a manganese(IV)–hydroperoxo adduct with incorporated substrate is formed during the induction period and it becomes an active catalyst for limonene oxidation.
Similar content being viewed by others
References
Fahlbusch KG, Hammerschmidt FJ, Panten J, Pickenhagen W, Schatkowski D (2002) Flavors and fragrances. In: Ullmann’s Encyclopedia of industrial chemistry. Wiley-VCH, Weinheim
Naróg D, Szczepanik A, Sobkowiak A (2008) Catal Lett 120:320
Groves JT, Nemo TE (1983) J Am Chem Soc 105:5786
De Carvalho ME, Meunier B (1986) New J Chem 10:223
(a) Suslick KS, Cook BR (1987) Chem Commun 200. (b) Van der Made AW, Nolte RJM (1984) J Mol Catal 26:333
Battioni P, Renaud JP, Bartoli JF, Reina-Artiles M, Fort M, Mansuy D (1988) J Am Chem Soc 110:8462
Mansuy D, Bartoli JF, Battioni P, Lyon DK, Finke RG (1991) J Am Chem Soc 113:7222
Borocci S, Marotti F, Mancini G, Monti D, Pastorini A (2001) Langmuir 17:7198
Moghadam M, Tangestaninejad S, Habibi MH, Mirkhani V (2004) J Mol Catal A: Chem 217:9
Lima LF, Cardozo-Filho L, Arroyo PA, Márquez-Alvarez H, Antunes OAC (2005) React Kinet Catal Lett 84:69
Ravikumar KS, Barbier F, Bégué JP, Bonnet-Delpon D (1998) Tetrahedron 54:7457
Raja R, Sankar G, Thomas JM (1999) Chem Commun 829
Bhattacharjee S, Dines TJ, Anderson JA (2004) J Catal 225:398
Bhattacharjee S, Anderson JA (2004) Catal Lett 95:119
Matsushita T, Sawyer DT, Sobkowiak A (1999) J Mol Catal A: Chem 137:127
Lima LF, Corraza ML, Cardozo-Filho L, Márquez-Alvarez H, Antunes OAC (2006) Braz J Chem Eng 23:83
Sobkowiak A, Naróg D, Sawyer DT (2000) J Mol Catal A: Chem 159:247
Pacześniak T, Sobkowiak A (2003) J Mol Catal A: Chem 194:1
Pacześniak T, Sobkowiak A (2004) Pol J Chem 78:1611
Naróg D, Lechowicz U, Pietryga T, Sobkowiak A (2004) J Mol Catal A: Chem 212:25
Sawyer DT, Sobkowiak A, Roberts JL Jr (1995) Electrochemistry for chemists, 2nd edn. Wiley, New York, p 189
Sawyer DT (1991) Oxygen chemistry. Oxford University Press, New York, p 44
Bakul DC, Czernuszewicz RS (1994) New J Chem 18:149
Shul’pin GB, Nizova GV, Kozlov YN, Pechenkina IG (2002) New J Chem 26:1238
Woitiski CB, Kozlov YN, Mandelli D, Nizova GV, Schuchardt U, Shul’pin GB (2004) J Mol Catal A: Chem 222:103
Yin G, Buchalova M, Danby AM, Perkins CM, Kitko D, Carter JD, Scheper WM, Busch DH (2005) J Am Chem Soc 127:17170
Romakh VB, Therrien B, Süss-Fink G, Shul’pin GB (2007) Inorg Chem 46:1315
Liebeskind LS, Gasdaska JR, McCallum JS, Tremont SJ (1989) J Org Chem 54:669
Grigsby WJ, Main L, Nicholson BK (1993) Organometallics 12:397
Sawyer DT, Sobkowiak A, Matsushita T (1996) Acc Chem Res 29:409
Copper SR, Calvin M (1977) J Am Chem Soc 99:6623
Gamelin DR, Kirk ML, Stemmler TL, Pal S, Armstrong WH, Penner-Hahn JE, Solomon EI (1994) J Am Chem Soc 116:2392
Collomb Dunand-Sauthier MN, Deronizer A, Piron A, Pradon X, Ménage S (1998) J Am Chem Soc 120:5373
Baffert C, Dumas S, Chauvin J, Lepretre JC, Collomb MN, Deronizer A (2005) Phys Chem Chem Phys 7:202
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Szczepanik, A., Sobkowiak, A. Manganese(II)-Induced Oxidation of Limonene by Dioxygen. Catal Lett 126, 261–267 (2008). https://doi.org/10.1007/s10562-008-9617-z
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-008-9617-z