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Combined H2O and CO2 Reforming of Methane Over Ni–Ce–ZrO2 Catalysts for Gas to Liquids (GTL)

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Abstract

Ni–Ce–ZrO2 catalysts with various CeO2/ZrO2 ratios have been prepared by co-precipitation method and applied for combined steam and carbon dioxide reforming of methane (CSCRM) to produce synthesis gas (H2/CO = 2) for gas to liquid (GTL) process. 15% Ni–Ce0.8Zr0.2O2 exhibits the highest activity as well as stability in CSCRM due to finely dispersed NiO with intimate contact with support and high oxygen storage capacity.

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Acknowledgments

The authors would like to acknowledge the financial support of KEMCO and GTL Technology Development Consortium (Korea National Oil Corp., Daelim Industrial Co., LTD, Doosan Mecatec Co., LTD, Hyundai Engineering Co. LTD and SK Energy Co. LTD) under “Energy & Resources Technology Development Programs” of the Ministry of Knowledge Economy, Republic of Korea.

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Authors and Affiliations

  1. Department of Environmental Engineering, Yonsei University, 234 Maeji, Heungeop, Wonju, Gangwon-do, 220-710, South Korea

    Hyun-Seog Roh

  2. Strategic Technologies Research Division, Korea Institute of Energy Research (KIER), 71-2 Jang-dong, Yuseong, Daejeon, 305-343, South Korea

    Kee Young Koo, U. D. Joshi & Wang Lai Yoon

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  1. Hyun-Seog Roh
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  2. Kee Young Koo
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  3. U. D. Joshi
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  4. Wang Lai Yoon
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Correspondence to Hyun-Seog Roh or Wang Lai Yoon.

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Roh, HS., Koo, K.Y., Joshi, U.D. et al. Combined H2O and CO2 Reforming of Methane Over Ni–Ce–ZrO2 Catalysts for Gas to Liquids (GTL). Catal Lett 125, 283–288 (2008). https://doi.org/10.1007/s10562-008-9560-z

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  • DOI: https://doi.org/10.1007/s10562-008-9560-z

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