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Sonogashira reactions catalyzed by water-soluble, β-cyclodextrin-capped palladium nanoparticles

Catalysis Letters volume 116, pages 94–100 (2007)Cite this article

Abstract

The Sonogashira reaction was efficiently catalyzed by β-cyclodextrin-capped Pd nanoparticles (β-CD/Pd) in aqueous solution at room temperature. In addition, PPh3 was not necessary to be present in the reaction media, and CuI, one major requirement for the typical homogeneous Sonogashira reaction, could be completely omitted without affecting the catalytic activity of β-CD/Pd nanoparticles. This study offers a new example of using β-CD-capped metal nanoparticles as a novel nanocatalyst for catalytic organic reaction in aqueous solution.

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Acknowledgments

The authors thank the National Science Foundation for financial support. The authors would like to thank reviewers for their invaluable comments on the manuscript.

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Authors and Affiliations

  1. Department of Chemistry, Michigan Technological University, Houghton, MI, 49931, USA

    Cuihua Xue, Kumaranand Palaniappan, Ganesh Arumugam, Jian Liu & Haiying Liu

  2. Department of Materials Science and Engineering, Michigan Technological University, Houghton, MI, 49931, USA

    Stephen A. Hackney

Authors
  1. Cuihua Xue
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  2. Kumaranand Palaniappan
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  3. Ganesh Arumugam
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  4. Stephen A. Hackney
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  5. Jian Liu
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  6. Haiying Liu
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Correspondence to Haiying Liu.

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Xue, C., Palaniappan, K., Arumugam, G. et al. Sonogashira reactions catalyzed by water-soluble, β-cyclodextrin-capped palladium nanoparticles. Catal Lett 116, 94–100 (2007). https://doi.org/10.1007/s10562-007-9108-7

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  • DOI: https://doi.org/10.1007/s10562-007-9108-7

Keywords

  • Sonogashira reaction
  • β-CD-capped Pd nanoparticles
  • aqueous media
  • nanocatalyst

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