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Isomerization of 3-methyl(3-13C)pentane over platinum supported sulphated zirconias: reaction mechanisms

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Abstract

This paper studies the isomerization mechanisms of 3-methyl(3-13C)pentane over Pt supported sulphated zirconias (SZs). Pt hydrogenates the reaction intermediates that desorbs, hinders successive isomerizations from occurring and reduces the isomerization steps to two (three with Pt-free SZs). The isomerization is a monomolecular process to which Pt does not participate. Lastly, it is suggested that the ratio between the proportions of methyl migration and ethyl migration could be appreciated as a catalyst intrinsic characteristic.

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References

  1. Hino M., Koyabashi S., Arata K. (1979) J. Am. Chem. Soc. 101:6439

    Article  CAS  Google Scholar 

  2. Yori J.C., Luy J.C., Parera J.M. (1989) Appl. Catal. 46:103

    Article  CAS  Google Scholar 

  3. Focus on Catalysts 5 (2005*) 7

  4. Løften T., Blekkan E.A. (2005)* Appl. Catal. A 299:250

    Google Scholar 

  5. Hino M., Arata K. (1995) Catal. Lett. 30:25

    Article  Google Scholar 

  6. Ebitani K., Konishi J., Hattori H. (1991) J. Catal. 130:257

    Article  CAS  Google Scholar 

  7. Song X.M., Sayari A. (1996) Catal. Rev. Sci. Eng. 38:329

    CAS  Google Scholar 

  8. Arata K. (1996) Appl. Catal. A 146:3

    Article  CAS  Google Scholar 

  9. Cheung T.K., Gates B.C. (1998) Top. Catal. 6:41

    Article  CAS  Google Scholar 

  10. Adeeva V., Liu H.Y., Xu B.G., Sachtler W.M.H. (1998) Top. Catal. 6:61

    Article  CAS  Google Scholar 

  11. Farcasiu D., Li J.Q. (1998) Appli. Catal. A 175:1

    Article  CAS  Google Scholar 

  12. Hong Z., Fogash K.B., Dumesic J.A. (1999) Catal. Today 51:269

    Article  CAS  Google Scholar 

  13. Yadav G., Nair J.J. (1999) Microporous Mesoporous Mater. 33:1

    Article  CAS  Google Scholar 

  14. Yamaguchi T. (2001) Appl. Catal. A 222:237

    Article  CAS  Google Scholar 

  15. Echizen T., Suzuki T., Kamiya Y., Okuhara T. (2004) J. Mol. Catal. A 209:145

    Article  CAS  Google Scholar 

  16. Chao K.J., Wu H.C., Leu L.J. (1995) J. Catal. 157:289

    Article  CAS  Google Scholar 

  17. K. Tomishige, A. Okabe and K. Fujimoto, Appl. Catal. A 194–195 (2000) 383.

  18. Adeeva V., Lei G.D., Sachtler W.M.H. (1994) Appl. Catal. A 118:L11

    Article  CAS  Google Scholar 

  19. Liu H., Adeeva V., Lei G.D., Sachtler W.M.H. (1995) J. Mol. Catal. A 100:35

    Article  CAS  Google Scholar 

  20. Adeeva V., Lei G.D., Sachtler W.M.H. (1995) Catal. Lett. 33:135

    Article  CAS  Google Scholar 

  21. Liu H., Lei G.D., Sachtler W.M.H. (1996) Appl. Catal. A 137:167

    Article  CAS  Google Scholar 

  22. Liu H., Lei G.D., Sachtler W.M.H. (1996) Appl. Catal. A 146:165

    Article  CAS  Google Scholar 

  23. Tabora J.E., Davis R.J. (1996) J. Catal. 162:125

    Article  CAS  Google Scholar 

  24. Suzuki T., Okuhara T. (2001) Catal. Lett. 72:111

    Article  CAS  Google Scholar 

  25. T. Suzuki, T. Okuhara, Chem. Lett. (2000) 470.

  26. Luzgin M.V., Arzumanov S.S., Schmachkova V.P., Kotsarenko N.S., Rogov V.A., Stepanov A.G. (2003) J. Catal. 220:233

    Article  CAS  Google Scholar 

  27. Keller V., Garin F., Maire G. (2000) Phys. Chem. Chem. Phys. 2:2893

    Article  CAS  Google Scholar 

  28. Moreno J.A., Poncelet G. (2001) J. Catal. 203:453

    Article  CAS  Google Scholar 

  29. C. Corolleur, S. Corolleur and F.G. Gault, Bull. Soc. Chim. Fr. (1969) 842

  30. Dartigues J.A., Chambellan A., Corolleur S., Gault F.G., Renouprez A., Morawek B., Dalmai-Imelick G. (1979) Nouv. J. Chim. 3:591

    CAS  Google Scholar 

  31. Chambellan A., Dartigues J.A., Corolleur S., Gault F.G. (1977) Nouv. J. Chim. 1:41

    CAS  Google Scholar 

  32. Demirci Ü.B., Garin F. (2001) Catal. Lett. 76:45

    Article  CAS  Google Scholar 

  33. C. Corolleur, PhD Thesis, Université de Caen, Caen, France (1969).

  34. Garin F., Gault F.G. (1975) J. Am. Chem. Soc. 97:4466

    Article  CAS  Google Scholar 

  35. F. Garin, PhD Thesis, Université Louis Pasteur, Strasbourg, France (1978).

  36. Demirci Ü.B., Garin F. (2005)* J. Mol. Catal. A 258:46

    Article  CAS  Google Scholar 

  37. Sayari A., Dicko A. (1994) J. Catal. 145:561

    Article  CAS  Google Scholar 

  38. Zhao J., Hoffman G.P., Davis B.H. (1994) Catal. Lett. 24:385

    Article  CAS  Google Scholar 

  39. Ebitani K., Konno H., Tanaka T., Hattori H. (1992) J. Catal. 135:60

    Article  CAS  Google Scholar 

  40. Ebitani K., Tsuji J., Hattori H., Kita H. (1992) J. Catal. 135:609

    Article  CAS  Google Scholar 

  41. Ebitani K., Tanaka T., Hattori H. (1993) Appl. Catal. A 102:79

    Article  CAS  Google Scholar 

  42. Ebitani K., Konno H., Tanaka T., Hattori H. (1993) J. Catal. 143:322

    Article  Google Scholar 

  43. Shishido T., Hattori H. (1996) Appl. Catal. A 146:157

    Article  CAS  Google Scholar 

  44. Shishido T., Tanaka T., Hattori H. (1997) J. Catal. 172:24

    Article  CAS  Google Scholar 

  45. Satoh N., Hayashi J.I., Hattori H. (2000) Appl. Catal. A 202:207

    Article  CAS  Google Scholar 

  46. Föttinger K., Kinger G., Vinek H. (2004) Appl. Catal. A 266:195

    Article  CAS  Google Scholar 

  47. Iglesia E., Soled S.L., Kramer G.M. (1993) J. Catal. 144:238

    Article  CAS  Google Scholar 

  48. Iglesia E., Barton D.G., Soled S.L., Miseo S., Baumgartner J.E., Gates W.E., Fuentes G.A., Meitzner G.D. (1996) Stud. Surf. Sci. Catal. 101:533

    Article  CAS  Google Scholar 

  49. J.C. Duchet, D. Guillaume, A. Monnier, J. van Gestel, G. Szabo, P. Nascimento and S. Decker, Chem. Comm. (1999) 1819

  50. Duchet J.C., Guillaume D., Monnier A., Dujardin C., Gilson J.P., van Gestel J., Szabo G., Nascimento P. (2001) J. Catal. 198:328

    Article  CAS  Google Scholar 

  51. Mills G.A., Heinemann H., Milliken T.H., Oblad A.G. (1953) Ind. Eng. Chem. 45:134

    Article  CAS  Google Scholar 

  52. Bai X., Sachtler W.M.H. (1991) J. Catal. 129:121

    Article  CAS  Google Scholar 

  53. Sachtler W.M.H., Zhang Z. (1993) Adv. Catal. 39:129

    CAS  Google Scholar 

  54. McCarthy T.J., Lei G.D., Sachtler W.M.H. (1996) J. Catal. 159:90

    Article  CAS  Google Scholar 

  55. Manoli J.M., Potvin C., Muhler M., Wild U., Resofszki G., Buchholz T., Paàl Z. (1998) J. Catal. 178:338

    Article  CAS  Google Scholar 

  56. Buchholz T., Wild U., Muhler M., Resofszki G., Paàl Z. (1999) Appl. Catal. A 189:225

    Article  CAS  Google Scholar 

  57. Gault F.G. (1981) Adv. Catal. 30:1

    Article  CAS  Google Scholar 

  58. Vaudagna S.R., Comelli R.A., Figoli N.S. (1997) Catal. Lett. 47:259

    Article  CAS  Google Scholar 

  59. Hua W., Sommer J. (2002) Appl. Catal. A 227:279

    Article  CAS  Google Scholar 

  60. Essayem N., Ben Taârit Y., Feche C., Gayraud P.Y., Sapaly G., Naccache C. (2003) J. Catal. 219:97

    Article  CAS  Google Scholar 

  61. Stichert W., Schüth T., Kuba S., Knözinger H. (2001) J. Catal. 198:277

    Article  CAS  Google Scholar 

  62. Morterra C., Cerrato G., Pinna F., Signoretto M. (1995) J. Catal. 157:109

    Article  CAS  Google Scholar 

  63. Cao C.J., Han S., Chen C.L., Xu N.P., Mou C.Y. (2003) Catal. Comm. 4:511

    Article  CAS  Google Scholar 

  64. Li X., Nagaoka K., Simon L.J., Lercher J.A., Wrabetz S., Jentoft F.C., Breitkopf C., Matysik S., Papp H. (2005) J. Catal. 230:214

    Article  CAS  Google Scholar 

  65. Grau J.M., Yori J.C., Vera C.R., Lovey F.C., Condò A.M., Parera J.M. (2004) Appl. Catal. A 265:141

    Article  CAS  Google Scholar 

  66. Grau J.M., Yori J.C., Parera J.M. (2001) Appl. Catal. A 213:247

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors thank Dr. Georges Poncelet (Unité de Catalyse et Chimie des Matériaux Divisés, Université Catholique de Louvain, Belgium) for providing samples of all the catalysts investigated in the present study.

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Author notes

  1. Ü. B. Demirci

    Present address: TUBITAK MAM Marmara Research Centre, Energy Institute, P.O. Box 21, 41470, Gebze-Kocaeli, Turkey

Authors and Affiliations

  1. Laboratoire des Matériaux, Surfaces, et Procédés pour la Catalyse, UMR 7515-CNRS, ECPM, Université Louis Pasteur, 25 rue Becquerel, 67087, Strasbourg Cedex 2, France

    Ü. B. Demirci & F. Garin

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  1. Ü. B. Demirci
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  2. F. Garin
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Correspondence to Ü. B. Demirci.

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Demirci, Ü.B., Garin, F. Isomerization of 3-methyl(3-13C)pentane over platinum supported sulphated zirconias: reaction mechanisms. Catal Lett 114, 41–48 (2007). https://doi.org/10.1007/s10562-007-9042-8

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  • DOI: https://doi.org/10.1007/s10562-007-9042-8

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