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Kinetic of thermal degradation of poly(isobornyl methacrylate)

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The kinetic of the thermal degradation of poly(isobornyl methacrylate) (PIBORNMA) was investigated by thermo gravimetric (TG) analysis at different heating rates. TG curves showed that the thermal decomposition of PIBORNMA occurred in one stage. The apparent activation energies of thermal decomposition of PIBORNMA was determined by Tang, Flynn-Wall-Ozawa (FWO), Kissenger–Akahira–Sunose (KAS) and Coats-Redfern methods and the values were 80.30, 84.69, 79.81 and 84.413 kJ/mol, respectively. The mechanism function and pre-exponential factor was determined by master plots method.

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References

  1. Coşkun M., İlter Z., Özdemir E., Demirelli K., Ahmedzade M. (1998) Polym. Degrad. Stab. 60:185

    Article  Google Scholar 

  2. Zulfiqar S., Akhtar N., Zulfiqar M., McNeil I.C. (1989) Polym. Degrad. Stab. 23:299

    Article  CAS  Google Scholar 

  3. Peniche C., Zuldivar D., Bulay A., Roman J.S. (1993) Polym. Degrad. Stab. 40:287

    Article  CAS  Google Scholar 

  4. Manring L.E. (1991) Macromolecules 24:3304

    Article  CAS  Google Scholar 

  5. Oguchi K., Sanni K., Otaga N. (1990) Polym. Eng. Sci. 30(8):449

    Article  CAS  Google Scholar 

  6. Firth W.C., Palmer L.E. (1971) Macromolecules 4:654

    CAS  Google Scholar 

  7. Cais R.E., O’Donell J.E., Bony F.A. (1977) Macromolecules 18:254

    Google Scholar 

  8. Matsuda M., Hara Y. (1972) J. Polym. Sci. Part A: Polym. Chem. 10:838

    Google Scholar 

  9. Flynn J., Wall L. (1966) Polym. Lett. 4:323

    Article  CAS  Google Scholar 

  10. Ozawa T. (1965) Bull. Chem. Soc. Jon. 38:1881

    Article  CAS  Google Scholar 

  11. Doyle C. (1961) J. Apple Polym. Sci. 5:285

    Article  CAS  Google Scholar 

  12. Coats A., Redfern J. (1964) Nature 201:68

    Article  CAS  Google Scholar 

  13. Cried J. Male J., Ortega A. (1989) Thermochim. Acta. 147:377

    Article  Google Scholar 

  14. Nunez L., Fraga F., Villanueva M. (2000) Polymer 41:4635

    Article  CAS  Google Scholar 

  15. Tang W., Liu Y., Zhang H.C., Wang C. (2003) Thermochim. Acta. 408:39

    Article  CAS  Google Scholar 

  16. Kissinger H.F. (1957) Anal. Chem. 29:1702

    Article  CAS  Google Scholar 

  17. Gotor F.J., Criado J.M., Malek J., Koga N. (2000) J. Phys. Chem. A. 104:1077

    Article  Google Scholar 

  18. Perez-Maqueda L.A., Criado J.M., Gotor F.J., Malek J. (2002) J. Phys. Chem. A. 106:2862

    Article  CAS  Google Scholar 

  19. Wanjun T., Yuwen L., Hen Z., Zhiyong W., Cunxin W. (2003) J. Therm. Anal. Cal. 74:309

    Article  CAS  Google Scholar 

  20. Tang W., Liu Y., Yang X., Wang C. (2004) Ind. Eng. Chem. Res. 43:2054

    Article  CAS  Google Scholar 

  21. Ho B.C., Lee Y.D., Chin W.K. (1992) J. Polym. Sci., Part A: Polym. Chem. 30:2389

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science and Arts, Çanakkale Onsekiz Mart University, TR-17020, Çanakkale, Turkey

    Fatih Doğan & İsmet Kaya

  2. Department of Chemistry, Faculty of Science, Ege University, İzmir, Turkey

    Mehmet Yürekli

Authors
  1. Fatih Doğan
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  2. İsmet Kaya
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  3. Mehmet Yürekli
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Correspondence to İsmet Kaya.

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Doğan, F., Kaya, İ. & Yürekli, M. Kinetic of thermal degradation of poly(isobornyl methacrylate). Catal Lett 114, 49–54 (2007). https://doi.org/10.1007/s10562-007-9041-9

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  • DOI: https://doi.org/10.1007/s10562-007-9041-9

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