Skip to main content
Log in

Catalytic reduction of no over the modified MFI metallosilicalites

  • Published:
Catalysis Letters Aims and scope Submit manuscript

The metallosilicalites (MFI) containing copper ([Cu,Si]), zinc ([Zn,Si]) or both elements ([Cu,Zn,Si]) were prepared and modified as potential catalysts for the NO reduction with propene. The H-[Cu,Si] samples showed the highest activity, which was initially comparable to that of Cu-ZSM-5, but contrary to the latter, it increased with time. The framework Cu or Cu released from the framework probably act as active sites.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1.
Figure 2.
Figure 3.
Figure 4.
Figure 5.
Figure 6.
Figure 7.
Figure 8.
Figure 9.
Figure 10.

Similar content being viewed by others

References

  1. Szostak R. (1989) Molecular Sieves, Principles of Synthesis and Identification. Van Nostrand Reinhold, New York

    Google Scholar 

  2. Torre-Abreu C., Henriques C., Ribeiro F.R., Delahay G., Ribeiro M.F. (1999) Catal. Today 54:407

    Article  CAS  Google Scholar 

  3. Tabata T., Kokitzu M., Okada O. (1994) Catal. Today 22:147

    Article  CAS  Google Scholar 

  4. W. Held and A. Koening, Ger. Offen. DE 3642018 (1987)

  5. Iwamoto M., Yahiro H. (1994) Catal. Today 22:5

    Article  CAS  Google Scholar 

  6. Robson H. (2001) Verified Syntheses of Zeolitic Materials. Elsevier, Amsterdam

    Google Scholar 

  7. Tanaka T., Kokota K., Isomura N., Doi H., Sugiura M. (1998) Appl. Catal. B 16:199

    Article  CAS  Google Scholar 

  8. Gill N.S., Taylor F.B. (1969) Inorg. Synt. 36:136

    Google Scholar 

  9. Gabelica Z., Valange S. (1998) Res. Chem. Intermediates 24:227

    CAS  Google Scholar 

  10. Kowalak S., Janiszewska E., Gierczyńska M., Dolata V., Evmiridis N., Katranas T., Vlessidis A., Tsiatouras V., Roessner F., Schneider E. (2004) Stud. Surf. Sci. Catal. 154:2200

    Article  Google Scholar 

  11. Camblor M.A., Lobo R.F., Koller H., Davis M.E. (1994) Chem. Mater. 6:2193

    Article  CAS  Google Scholar 

  12. Dong M., Wang J., Sun Y. (2001) Micropor. Mesopor. Mater. 43:237

    Article  CAS  Google Scholar 

  13. Henriques C., Ribeiro M.F., Abreu C., Murphy D.M., Poignant F., Saussey J., Lavalley J.C. (1998) Appl. Catal. B 16:79

    Article  CAS  Google Scholar 

  14. Sobczak I., Decyk P., Ziolek M., Daturi M., Lavalley J.C., Kevan L., Prakash A.M. (2002) J. Catal. 207:101

    Article  CAS  Google Scholar 

  15. Cheung T., Bhargava S.K., Hobday M., Foger K. (1996) J. Catal. 158:301

    Article  CAS  Google Scholar 

  16. Aylor A.W., Larsen S.C., Reimer J.A., Bell A.T. (1995) J. Catal. 157:592

    Article  CAS  Google Scholar 

Download references

Acknowledgment

E. Janiszewska expresses her gratitude to the Foundation for Polish Science for the financial support.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ewa Janiszewska.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Janiszewska, E., Kowalak, S., Gierczyńska, M. et al. Catalytic reduction of no over the modified MFI metallosilicalites. Catal Lett 114, 64–70 (2007). https://doi.org/10.1007/s10562-007-9037-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-007-9037-5

Keywords

Navigation