Skip to main content
SpringerLink
Log in

Promotion effects of Pt and Rh on catalytic performances of Mo/HZSM-5 and Mo/HMCM-22 in selective methane-to-benzene reaction

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

The promotion effects of Pt and Rh on catalytic performances of Mo/HZSM-5 and Mo/HMCM-22 in selective methane-to-benzene reaction were studied in the presence of additive H2. The selectivity to naphthalene was effectively suppressed and highly selective and stable benzene formation was obtained by the addition of noble metal to the Mo/HZSM-5 and Mo/HMCM-22 catalysts, due to the suppression of carbon deposition on the Brønsted acid sites of zeolite.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. Wang L. Tao M. Xie G. Xu J. Huang Y. Xu (1993) Catal. Lett. 21 35 Occurrence Handle1:CAS:528:DyaK2cXkvVKiurY%3D Occurrence Handle10.1007/BF00767368

    Article  CAS  Google Scholar 

  2. F. Solymosi A. Erdohelyi A. Szoke (1995) Catal. Lett. 32 43 Occurrence Handle1:CAS:528:DyaK2MXlvV2lsb8%3D Occurrence Handle10.1007/BF00806100

    Article  CAS  Google Scholar 

  3. L. Chen L. Lin Z. Xu X. Li T. Zhang (1995) J. Catal. 157 190 Occurrence Handle1:CAS:528:DyaK2MXovV2hs7o%3D Occurrence Handle10.1006/jcat.1995.1279

    Article  CAS  Google Scholar 

  4. D. Wang J.H. Lunsford M.P. Rosynek (1996) Top. Catal. 3 289 Occurrence Handle1:CAS:528:DyaK28XlvFKmsL0%3D Occurrence Handle10.1007/BF02113855

    Article  CAS  Google Scholar 

  5. F. Solymosi A. Szöke J. Cserényi (1996) Catal. Lett. 39 157 Occurrence Handle1:CAS:528:DyaK28Xkt1Ciur8%3D Occurrence Handle10.1007/BF00805576

    Article  CAS  Google Scholar 

  6. F. Solymosi J. Cserényi A. Szöke T. Bánsagi A. Oszkó (1997) J. Catal. 165 156 Occurrence Handle10.1006/jcat.1997.1478

    Article  Google Scholar 

  7. L. Wang Y. Xu X. Wong W. Xui X. Guo (1997) Appl. Catal. A 152 173 Occurrence Handle1:CAS:528:DyaK2sXitVKlurg%3D Occurrence Handle10.1016/S0926-860X(96)00366-3

    Article  CAS  Google Scholar 

  8. S. Liu, Q. Dong, R. Ohnishi and M. Ichikawa, Chem. Commun. (1997) 1455

  9. D. Wang J.H. Lunsford M.P. Rosynek (1997) J. Catal. 169 347 Occurrence Handle1:CAS:528:DyaK2sXksVKntrc%3D Occurrence Handle10.1006/jcat.1997.1712

    Article  CAS  Google Scholar 

  10. R.W. Borry E.C. Lu Y.H. Kim E. Iglesia (1998) Stud. Surf. Sci. Catal. 119 403 Occurrence Handle1:CAS:528:DyaK1cXms1Gmurs%3D Occurrence Handle10.1016/S0167-2991(98)80465-5

    Article  CAS  Google Scholar 

  11. Y. Xu L. Lin (1999) Appl. Catal. A 188 53 Occurrence Handle1:CAS:528:DyaK1MXntVaisb4%3D Occurrence Handle10.1016/S0926-860X(99)00210-0

    Article  CAS  Google Scholar 

  12. S. Li C. Zhang Q. Kan D. Wang T. Wu L. Lin (1999) Appl. Catal. A 187 199 Occurrence Handle1:CAS:528:DyaK1MXmsFWqurY%3D Occurrence Handle10.1016/S0926-860X(99)00231-8

    Article  CAS  Google Scholar 

  13. F. Solymosi L. Bugyi A. Oszko (1999) Catal. Lett. 57 103 Occurrence Handle1:CAS:528:DyaK1MXhvVyjs7g%3D Occurrence Handle10.1023/A:1019095515497

    Article  CAS  Google Scholar 

  14. F. Solymosi L. Bugyi A. Oszko I. Hovarth (1999) J. Catal. 185 160 Occurrence Handle1:CAS:528:DyaK1MXktVSlsL0%3D Occurrence Handle10.1006/jcat.1999.2491

    Article  CAS  Google Scholar 

  15. S. Liu L. Wang R. Ohnishi M. Ichikawa (1999) J. Catal. 181 175 Occurrence Handle1:CAS:528:DyaK1MXpsVyjsw%3D%3D Occurrence Handle10.1006/jcat.1998.2310

    Article  CAS  Google Scholar 

  16. R. Ohnishi S. Liu Q. Dong L. Wang M. Ichikawa (1999) J. Catal. 182 92 Occurrence Handle1:CAS:528:DyaK1MXhtF2hs7o%3D Occurrence Handle10.1006/jcat.1998.2319

    Article  CAS  Google Scholar 

  17. L. Wang R. Ohnishi M. Ichikawa (2000) J. Catal. 190 276 Occurrence Handle1:CAS:528:DC%2BD3cXhsFems70%3D Occurrence Handle10.1006/jcat.1999.2748

    Article  CAS  Google Scholar 

  18. Y. Shu R. Ohnishi M. Ichikawa (2002) J. Catal. 206 134 Occurrence Handle1:CAS:528:DC%2BD38XhtFalt7Y%3D Occurrence Handle10.1006/jcat.2001.3481

    Article  CAS  Google Scholar 

  19. S. Liu R. Ohnishi M. Ichikawa (2003) J. Catal. 220 57 Occurrence Handle1:CAS:528:DC%2BD3sXot1Oisbc%3D Occurrence Handle10.1016/S0021-9517(03)00236-7

    Article  CAS  Google Scholar 

  20. Y. Shu, H. Ma, R. Ohnishi and M. Ichikawa, Chem. Commun. (2003) 86

  21. H. Ma R. Ohnishi M. Ichikawa (2003) Catal. Lett. 89 143 Occurrence Handle1:CAS:528:DC%2BD3sXlsVKmsLw%3D Occurrence Handle10.1023/A:1024796115700

    Article  CAS  Google Scholar 

  22. C. Bouchy I. Schmidt J.R. Anderson C.H.J. Jacobsen E.G. Derouane S.B. Derouane-Abd hamid (2000) J. Mol. Catal. A 163 283 Occurrence Handle1:CAS:528:DC%2BD3MXmtVCiug%3D%3D Occurrence Handle10.1016/S1381-1169(00)00392-7

    Article  CAS  Google Scholar 

  23. S.B. Derouane-Abd hamid J.R. Anderson I. Schmidt C. Bouchy C.H.J. Jacobsen E.G. Derouane (2000) Catal. Today 63 461 Occurrence Handle1:CAS:528:DC%2BD3cXotlKms7g%3D Occurrence Handle10.1016/S0920-5861(00)00492-2

    Article  CAS  Google Scholar 

  24. R.W. Borry SuffixIII Y.H. Kim A. Huffsmith J.A. Reimer E. Iglesia (1999) J. Phys. Chem. B 103 5787 Occurrence Handle1:CAS:528:DyaK1MXjvFamtrw%3D Occurrence Handle10.1021/jp990866v

    Article  CAS  Google Scholar 

  25. W. Ding S. Li G.D. Meitzner E. Iglesia (2001) J. Phys. Chem. B 105 506 Occurrence Handle1:CAS:528:DC%2BD3cXovFaktrY%3D Occurrence Handle10.1021/jp0030692

    Article  CAS  Google Scholar 

  26. J.S. Lee L. Volpe F.H. Ribeiro M. Boudart (1988) J. Catal. 112 44 Occurrence Handle1:CAS:528:DyaL1cXltlGkt7o%3D Occurrence Handle10.1016/0021-9517(88)90119-4

    Article  CAS  Google Scholar 

  27. R. Kojima K. Aika (2001) Appl. Catal. A 219 141 Occurrence Handle1:CAS:528:DC%2BD3MXmsFWjtrY%3D Occurrence Handle10.1016/S0926-860X(01)00676-7

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Catalysis Research Center, Hokkaido University, Kita-ku, N-21 W-10, Sapporo, 001-0021, Japan

    Ryoichi Kojima, Satoshi Kikuchi, Hongtao Ma, Jie Bai & Masaru Ichikawa

Authors
  1. Ryoichi Kojima
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Satoshi Kikuchi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hongtao Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jie Bai
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Masaru Ichikawa
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Masaru Ichikawa.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kojima, R., Kikuchi, S., Ma, H. et al. Promotion effects of Pt and Rh on catalytic performances of Mo/HZSM-5 and Mo/HMCM-22 in selective methane-to-benzene reaction. Catal Lett 110, 15–21 (2006). https://doi.org/10.1007/s10562-006-0087-x

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-006-0087-x

Keywords

Search

Navigation