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Catalytic Processes Involving Dihydrogen Complexes and Other Sigma-bond Complexes

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The discovery of dihydrogen complexes, L n M(H2), pointed to direct transfer of hydrogen from coordinated H2 ligands to substrates as an operable pathway in catalysis both in homogeneous and heterogeneous systems. Sigma complexes, L n M(η2-H–X) (X=H, Si, C, etc), are indeed relevant in hydrogenation as well as silane alcoholysis and methane conversion.

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    Gregory J. Kubas

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Kubas, G.J. Catalytic Processes Involving Dihydrogen Complexes and Other Sigma-bond Complexes. Catal Lett 104, 79–101 (2005). https://doi.org/10.1007/s10562-005-7440-3

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