Skip to main content
Log in

Promoting Effect of Pt on Self-activation over NiO–MgO Solid Solution in Oxidative Steam Reforming of Methane

  • Published:
Catalysis Letters Aims and scope Submit manuscript

The addition of Pt on NiO–MgO solid solution enhanced the performance of oxidative steam reforming of methane, especially, the catalyst can be activated during the oxidative reforming of methane at low reaction temperature like 823 K. 0.1% Pt/Ni0.2Mg0.8O exhibited much higher performance than 0.1% Pt/MgO and Ni0.2Mg0.8O. From the comparisons, the additive effect of Pt to Ni0.2Mg0.8O is to promote both the activity of combustion and reforming of methane. This additive effect can be explained by the high combustion activity caused by the synergy of Pt with NiO–MgO solid solution and the high catalyst reducibility.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J.R. Rostrup-Nielsen, in Catalysis Science and Technology, eds, J.R. Anderson and M. Boudart Vol. 5 (Springer–Verlag, New York, 1984) p. 1.

  2. J.R Rostrup-Nielsen (1997) Sekiyu Gakkaishi 40 366

    Google Scholar 

  3. B Li K Maruyama M Nurunnabi K Kunimori K Tomishige (2004) Appl. Catal. A: Gen. 275 157 Occurrence Handle10.1016/j.apcata.2004.07.047

    Article  Google Scholar 

  4. K Tomishige S Kanazawa S Ito K Kunimori (2003) Appl. Catal. A: Gen. 244 71 Occurrence Handle10.1016/S0926-860X(02)00596-3

    Article  Google Scholar 

  5. K Tomishige Y Matsuo Y Yoshinaga Y Sekine M Asadullah K. Fujimoto (2002) Appl. Catal. A: Gen. 223 225 Occurrence Handle10.1016/S0926-860X(01)00757-8

    Article  Google Scholar 

  6. K Takehira (2002) Catal. Surv. Jpn. 6 19

    Google Scholar 

  7. S Liu G Xiong H Dong W Yang (2000) Appl. Catal. A: Gen. 202 141 Occurrence Handle10.1016/S0926-860X(00)00460-9

    Article  Google Scholar 

  8. A.M O’Connor J.R.H Ross (1998) Catal. Today 46 203 Occurrence Handle10.1016/S0920-5861(98)00342-3

    Article  Google Scholar 

  9. P.D.F Vernon M.L.H Green A.K Cheetham A.T Ashcroft (1992) Catal. Today 13 417 Occurrence Handle10.1016/0920-5861(92)80167-L

    Article  Google Scholar 

  10. V.R Choudhary A.M Rajput B Prabhakar (1995) Catal. Lett. 32 391 Occurrence Handle10.1007/BF00813234

    Article  Google Scholar 

  11. T Inui K Saigo Y Fujii Fujioka K. (1995) Catal. Today 26 295 Occurrence Handle10.1016/0920-5861(95)00151-9

    Article  Google Scholar 

  12. V.R Choudhary A.M Rajput (1996) Ind. Eng. Chem. Res. 35 3934 Occurrence Handle10.1021/ie960002l

    Article  Google Scholar 

  13. O Yamazaki K Tomishige K Fujimoto (1996) Appl. Catal. A: Gen. 136 49 Occurrence Handle10.1016/0926-860X(95)00268-5

    Article  Google Scholar 

  14. K Tomishige Y.G Chen K Fujimoto (1999) J. Catal. 181 91 Occurrence Handle10.1006/jcat.1998.2286

    Article  Google Scholar 

  15. Y.G Chen K Tomishige K Yokoyama K Fujimoto (1999) J. Catal. 184 479 Occurrence Handle10.1006/jcat.1999.2469

    Article  Google Scholar 

  16. Y.H Hu E Ruchenstein (2002) Catal. Rev. Sci. Eng. 44 423 Occurrence Handle10.1081/CR-120005742

    Article  Google Scholar 

  17. K Tomishige Y Himeno Y Matsuo Y Yoshinaga K Fujimoto (2000) Ind. Eng. Chem. Res. 39 1891 Occurrence Handle10.1021/ie990884z

    Article  Google Scholar 

  18. K Tomishige (2004) Catal. Today 89 405 Occurrence Handle10.1016/j.cattod.2004.01.003

    Article  Google Scholar 

  19. K Tomishige Y Matsuo Y Yoshinaga M Asadullah Y Sekine K Fujimoto (2002) ACS Symp. Ser. 809 303

    Google Scholar 

  20. K Tomishige Y Nagasawa U Lee Y Iwasawa (1997) Bull. Chem. Soc. Jpn. 70 1607

    Google Scholar 

  21. Y.G Chen K Tomishige K Yokoyama K Fujimoto (1997) Appl. Catal. A: Gen. 165 335 Occurrence Handle10.1016/S0926-860X(97)00216-0

    Article  Google Scholar 

  22. T.B Reed (1971) Free Energy Formation of Binary Compounds MIT Press Cambridge, MA 67

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Keiichi Tomishige.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nurunnabi, M., Li, B., Kunimori, K. et al. Promoting Effect of Pt on Self-activation over NiO–MgO Solid Solution in Oxidative Steam Reforming of Methane. Catal Lett 103, 277–281 (2005). https://doi.org/10.1007/s10562-005-7165-3

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-005-7165-3

Key Words

Navigation