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Synthesis and Catalytic Reactivity of MCM-22/ZSM-35 Composites for Olefin Aromatization

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Abstract

A series of MCM-22/ZSM-35 composites has been hydrothermally synthesized and characterized by XRD, SEM, particle size distribution analysis, N2 adsorption and NH3-TPD techniques. Pulse and continuous flow reactions were carried out to evaluate the catalytic performances of these composites in aromatization of olefins, respectively. It was found that MCM-22/ZSM-35 composites could be rapidly crystallized at 174 °C with an optimal gel composition of SiO2/Al2O3=25, Na2O/SiO2=0.11, HMI/SiO2=0.35, and H2O/SiO2=45 (molar ratio), of which the weight ratio of ZSM-35 zeolite in the composite relied on the crystallization time. The coexistence of MCM-22 and ZSM-35 in the composite (MCM-22/ZSM-35=45/55 wt/wt) was observed to exert a notable synergistic effect on the aromatization ability for butene conversion and FCC gasoline updating, possibly due to the intergrowth of some MCM-22 and ZSM-35 layers.

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Authors and Affiliations

  1. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, P.O. Box 110, 116023, P. R. China

    Xionglei Niu, Yueqing Song, Sujuan Xie, Shenglin Liu, Qingxia Wang & Longya Xu

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  1. Xionglei Niu
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  2. Yueqing Song
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  3. Sujuan Xie
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  4. Shenglin Liu
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  5. Qingxia Wang
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  6. Longya Xu
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Correspondence to Longya Xu.

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Niu, X., Song, Y., Xie, S. et al. Synthesis and Catalytic Reactivity of MCM-22/ZSM-35 Composites for Olefin Aromatization. Catal Lett 103, 211–218 (2005). https://doi.org/10.1007/s10562-005-7156-4

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  • DOI: https://doi.org/10.1007/s10562-005-7156-4

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