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Vibrationally Excited CO2 Formed in CO + NO Reaction on Pd(110) Surface in High Surface Temperature Range

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The infrared chemiluminescence spectra of CO2 formed during steady-state CO+NO reaction over Pd(110) indicated that the temperature of the bending vibrational mode was much higher than that of the antisymmetric one at higher surface temperatures such as 800–850 K. Especially, in the high temperature range, more vibrationally excited CO2 was formed from CO+NO reaction than CO+O2 reaction. On the basis of the result, we propose the model structure of reaction intermediates for CO2 formation in CO+NO reaction, which is different from that in CO+O2 reaction.

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Authors and Affiliations

  1. Institute of Materials Science, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki, 305-8573, Japan

    Kenji Nakao, Shin-ichi Ito, Keiichi Tomishige & Kimio Kunimori

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  1. Kenji Nakao
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  2. Shin-ichi Ito
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  3. Keiichi Tomishige
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  4. Kimio Kunimori
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Correspondence to Kimio Kunimori.

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Nakao, K., Ito, Si., Tomishige, K. et al. Vibrationally Excited CO2 Formed in CO + NO Reaction on Pd(110) Surface in High Surface Temperature Range. Catal Lett 103, 179–184 (2005). https://doi.org/10.1007/s10562-005-7151-9

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  • DOI: https://doi.org/10.1007/s10562-005-7151-9

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