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Influence of Pt–Pd/TS-1 Catalyst Preparation on Epoxidation of Olefins with Hydrogen Peroxide

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The catalytic performance of the platinum–palladium/titanium silicalite, which was a common catalyst for the direct epoxidation of olefins with hydrogen and oxygen, was tested by epoxidation of allyl chloride with hydrogen peroxide. The epoxidation capacity of the TS-1catalyst was reduced after loading palladium and platinum on it. Ti leaching and crystallinity decrease were observed by XRD and FT-IR. The decomposition of hydrogen peroxide was accelerated by the supported Pd and Pt. These contributed to the loss of epoxidation capacity of TS-1. Ti leaching and crystallinity decrease were probably main causes. We propose that the Ti leaching had the most important influence on the loss of epoxidation capacity

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References

  1. W. Laufer W.F. Hoelderich (2001) Appl. Catal. A: Gen. 213 163 Occurrence Handle10.1016/S0926-860X(00)00900-5

    Article  Google Scholar 

  2. G. Jenser T. Mallal M. Mueciejewski F. Eigenmann A. Baiker (2001) Appl. Catal. A: Gen. 208 125 Occurrence Handle10.1016/S0926-860X(00)00689-X

    Article  Google Scholar 

  3. B. Notari (1996) Adv. Catal. 41 253

    Google Scholar 

  4. X. Guo R. Wang X. Wang J. Hao (2004) Catal. Today 93-95 211 Occurrence Handle10.1016/j.cattod.2004.06.043

    Article  Google Scholar 

  5. R. Wang X. Guo X. Wang J. Hao G. Li J. Xiu (2004) Appl. Catal. A: Gen. 261 7 Occurrence Handle10.1016/j.apcata.2003.10.040

    Article  Google Scholar 

  6. C. Wang X. Guo X. Wang R. Wang J. Hao (2004) Catal. Lett. 96 79 Occurrence Handle10.1023/B:CATL.0000029534.52113.b4

    Article  Google Scholar 

  7. N. Yap R.P. Andres W.N. Delgass (2004) J. Catal. 226 156 Occurrence Handle10.1016/j.jcat.2004.05.016

    Article  Google Scholar 

  8. T.A. Nijhuis B.J. Huizinga M. Makkee J.A. Moulijn (1999) Ind. Eng. Chem. Res. 38 884

    Google Scholar 

  9. C.X. Qi T. Akita M. Okumura M. Haruta (2001) Appl. Catal. A: Gen. 218 81 Occurrence Handle10.1016/S0926-860X(01)00621-4

    Article  Google Scholar 

  10. G. Grosch, U. Muller, M. Schulz, N. Rieber, and H. Wurz, WO 9,747,386 (1997); G.R. Bowman, J.J. Maj, W.H. Clark, WO 9,800,414 (1998); W.H. Clark, J.J. Maj, G.R. Bowman, WO 9,800,415 (1998)

  11. P. Ingallina, M.G. Clerici, L. Rossi, and and G. Belussi, Stud. Surf. Sci. Catal. 92 (1995) 31; T. Tatsumi, K. Yuasa, and H.J. Tominaga, J. Chem. Soc., Chem. Commun. 19 (1992) 1446

  12. R. Meiers U. Diagerdissen W.F. Hoelderich (1998) J. Catal. 176 376 Occurrence Handle10.1006/jcat.1998.2036

    Article  Google Scholar 

  13. A. Sato, and T. Miyake, JP 4,352,771, (1992); A. Sato, M. Oguri, M. Tokumaru, and T. Miyake, JP 2,690,309, (1996)

  14. U. Muller, P. Lingelbach, P. Babler, W. Harder, E. Karsten, “V. Kohl, J. Dembowski, N. Rieber, and M. Fischer, DE 4,425,672 (1996)

  15. R. Meiers W. Holderich (1999) Catal. Lett. 59 161 Occurrence Handle10.1023/A:1019024705869

    Article  Google Scholar 

  16. W. Laufer R. Meiers W. Holderich (1999) J. Mol. Catal. A: Chem. 141 215 Occurrence Handle10.1016/S1381-1169(98)00265-9

    Article  Google Scholar 

  17. M. Taramasso, G. Perego, B. Notari, US 4,410,501 (1983)

  18. E. Astorino J.B. Peri R.J. Willey G. Busca (1995) J. Catal. 157 482 Occurrence Handle10.1006/jcat.1995.1313

    Article  Google Scholar 

  19. T. Armaroli F. Milella B. Notari R.J. Willey G. Busca (2001) Top. Catal. 15 63 Occurrence Handle10.1023/A:1009023930284

    Article  Google Scholar 

  20. K.S. Smirnov B. Graaf Particlevan de (1996) Micropor. Mater. 7 133 Occurrence Handle10.1016/0927-6513(96)00023-5

    Article  Google Scholar 

  21. A. Thangaraj R. Kumar S.P. Mirajkar P. Ratnasamy (1991) J. Catal. 130 1 Occurrence Handle10.1016/0021-9517(91)90086-J

    Article  Google Scholar 

  22. A. Tuel Y. Ben Taârit (1993) Zeolites 13 357 Occurrence Handle10.1016/0144-2449(93)90150-2

    Article  Google Scholar 

  23. C.S. Cundy J.O. Forrest (2004) Micro. Mes. Mat. 72 67 Occurrence Handle10.1016/j.micromeso.2004.04.006

    Article  Google Scholar 

  24. M.G. Clerici G. Bellussi U. Romano (1991) J. Catal. 129 159 Occurrence Handle10.1016/0021-9517(91)90019-Z

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Key Laboratory for Green Chemical Technology of the Ministry of Education of China, School of chemical Engineering & Technology, Tianjin University, Tianjin, 300072, P. R. China

    Qingfa Wang, Li Wang & Zhentao Mi

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  1. Qingfa Wang
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  2. Li Wang
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  3. Zhentao Mi
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Correspondence to Li Wang or Zhentao Mi.

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Wang, Q., Wang, L. & Mi, Z. Influence of Pt–Pd/TS-1 Catalyst Preparation on Epoxidation of Olefins with Hydrogen Peroxide. Catal Lett 103, 161–164 (2005). https://doi.org/10.1007/s10562-005-6526-2

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