Activity patterns for the high temperature water gas shift reaction over oxide catalysts promoted by precious metals show that the performance of iron oxide–chromia catalysts can be significantly improved by promotion with small amounts of rhodium. The results suggest that reactions of hydrogen at the promoter–catalyst interface are the rate controlling process.
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References
BASF, German Offen 254,572 (1911)
D.S. Newsome (1980) Catal. Rev. - Sci. Eng. 21 275
M.V. Twigg (1989) Catalyst Handbook Wolfe Scientific London
D.C. Grenoble M.M. Estadt D.F. Ollis (1981) J. Catal. 67 90 Occurrence Handle10.1016/0021-9517(81)90263-3
C. Rhodes G.J. Hutchings A.M. Ward (1995) Catal. Today 23 43 Occurrence Handle10.1016/0920-5861(94)00135-O
R.L. Keiski T. Salmi P. Niemesto J. Ainassaari V.J. Pohjola (1996) Appl. Catal. A: General 137 349 Occurrence Handle10.1016/0926-860X(95)00315-0
T. Bunluesin R.J. Gorte G.W. Graham (1998) Appl. Catal. B 15 107 Occurrence Handle10.1016/S0926-3373(97)00040-4
T. Shido Y. Iwasawa (1993) J. Catal. 141 71 Occurrence Handle10.1006/jcat.1993.1119
D.L. Trimm Z.I. Onsan (2001) Catal. Rev. - Sci. Eng. 43 31 Occurrence Handle10.1081/CR-100104386
S. Hilaire X. Wang T. Luo R.J. Gorte J. Wagner (2001) Appl. Catal. A: General 215 271 Occurrence Handle10.1016/S0926-860X(01)00535-X
T. Giroux S. Hwang Y. Liu W. Ruettinger L. Shore (2005) Appl. Catal. B 55 185 Occurrence Handle10.1016/j.apcatb.2004.09.021
C. Padeste N.W. Cant D.L. Trimm (1993) Catal. Lett. 18 305 Occurrence Handle10.1007/BF00769451
C. Rhodes B.P. Williams F. King G.J. Hutchings (2002) Catal. Commun. 3 381 Occurrence Handle10.1016/S1566-7367(02)00156-5
Batist P.A. J.H.F. Bouwens G.C.A. Schuit (1972) J. Catal. 25 1 Occurrence Handle10.1016/0021-9517(72)90196-0
J.M. Thomas W.J. Thomas (1997) Principles and Practice of Heterogeneous Catalysis VCH Weinheim
T. Bunluesin H. Cordatos R.J. Gorte (1995) J. Catal. 157 222 Occurrence Handle10.1006/jcat.1995.1282
G.K. Boreskov (1970) Kinet. Catal. 11 374
N.H. Sagert R.M.L. Pouteau (1974) Can. J. Chem. 52 2960
Bradford M.C.J. M.A. Vannice (1996) Ind. Eng. Chem. Res. 35 3171 Occurrence Handle10.1021/ie960016r
D. Martin D. Duprez (1997) J. Phys. Chem. 101 4428
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Lei, Y., Cant, N.W. & Trimm, D.L. Activity Patterns for the ‘‘Water Gas Shift Reaction Over Supported Precious Metal Catalysts’’. Catal Lett 103, 133–136 (2005). https://doi.org/10.1007/s10562-005-6516-4
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DOI: https://doi.org/10.1007/s10562-005-6516-4