A novel support of the Ru nanoparticles was achieved by combination of electrostatic force and coordination. The Ru catalyst was used as heterogeneous catalyst for hydrogenation of arene. This catalyst is very active for the hydrogenation of benzene to cyclohexane even under mild conditions. The TOF of this Ru catalyst is 85.3 mol mol−1 h−1 at 20 °C and 1.0 MPa for complete hydrogenation of benzene. The catalytic activity did not decrease after other five runs. The excellent performance of this catalyst demonstrated that there existed synergistic effects among 1,1,3,3-tetramethylguanidinium, mesoporous SBA-15, and Ru nanoparticles.
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(a) A.M. Argo, J.F. Odzak, F.S. Lai and B.C. Gates, Nature 415 (2002) 623; (b) A.T. Bell, Science 299 (2003) 1688; (c) D.R. Rolison, Science 299 (2003) 1698; (d) S. Ozkar and R.G. Finke, J. Am. Chem. Soc. 124 (2002) 5796; (e) J.D. Aiken III and R.G Finke, J Am. Chem. Soc. 121 (1999) 8803; (f) J. Schulz, A. Roucoux and H. Patin, Chem. Eur. J. 6 (2000) 618; (g) J. Schulz, A. Roucoux and H. Patin, Chem. Commun. (1999) 535; (h) R. Raja, T. Khimyak, J.M. Thomas, S. Hermans and B.F.G Johnson, Angew. Chem. Int. Ed. 40 (2001) 4638; (i) O. Vidoni, K. Philippot, C. Amiens, B. Chaudret, O. balmes, J. Malm, J. bovin, F. Senocq and M. Casanove, Angew. Chem. Int. Ed. 38 (1999) 3736; (j) R. Schlogl and S.B.A. Hamid, Angew. Chem. Int. Ed. 43 (2004) 1628.
(a) A. Roucoux, J. Sehullz and H. Patin, Chem. Rev. 102 (2002) 3757; (b) R.G. Finke, in: Metal nanoparticles: synthesis, characterization and Application. eds. D.L. Feldherim and C.A. Foss, Jr., (Marcel Dekker, New York, 2002) Ch. 2, pp. 17–54
(a) P. Landon, P.J. Collier, A.J. Papworth, C.J. Kiely and G.J. Hutchings, Chem. Commun. (2002) 2058; (b) S. Hu and Y. Chen, Ind. Eng. Chem. Res., 40 (2001) 3127; (c) M.A. Keane and P.M. Patterson, J. Chem. Soc. Faraday Trans. 92(8) (1996) 1413.
N. Toshima Y. Shiiraishi T. Teranishi M. Miyake T. Tominaga H. Watanable W. Brijoux H. Bonnemann G. Schmid (2001) Appl. Organometal. Chem. 15 178 Occurrence Handle10.1002/aoc.146
(a) J.M. Thomas, B.F.G. Johnson, R. Raja, G. Sankar and P.A. Midgley, Acc. Chem. Res. 36 (2003) 20; (b) R. Raja, G. Sankar, S.Herman, D.S. Shepherd, S. Bromley, J.M. Thomas and B.F.G. Johnson, Chem. Commun. (1999) 1571; (c) D.S. Shepherd, T. Maschmeyer, B.F.G. Johnson, J.M. Thomas, G. Sankar, D. Ozkaya, W.Z. Zhou and R.D. Oldroyd, Angew. Chem. Int. Ed. 36 (1997) 2242; (d) R. Raja, T. Khimyak, J.M. Thomas, S. Herinan and B.F.G. Johnson, Angew. Chem. Int. Ed. 40 (2001) 4638.
J. Dupont G.S. Fonseca A.P. Umpierre P.F.P. Fichtner S.R. Teixeira (2002) J. Am. Chem. Soc. 124 4228 Occurrence Handle10.1021/ja025818u Occurrence Handle11960449
L.A. Blanchard D. Hancu E.J. Beckman J.F. Brennecke (1999) Nature 399 28 Occurrence Handle10.1038/19887
(a) T. Welton, Chem. Rev. 99 (1999) 2071; (b) P. Wasserscheid and W. Keim, Angew. Chem. Int. Ed. 39 (2000) 3772; (c) M.J. Earle and K.R. Seddon, Pure Appl. Chem. 72 (2000) 1391; (d) R.D. Rogers, K.R. Seddon (eds). Ionic Liquids as Green Solvents: Progress and Prospects, (ACS Symp. Ser. 856, American Chemical Society, Washington, DC, 2003)
J. Huang, T. Jiang, B. Han, H. Gao, Y. Chang, G. Zhao and W. Wu, Chem. Commun. (2003) 1654.
(a) S. Aoki, K. Iwaida, N. Hanamoto, M. Shiro and E. Kimura, J. Am. Chem. Soc. 124 (2002) 5256; (b) P. J. Bailey and S. Pace, Coordin. Chem. Rev. 214 (2001) 91.
J. Huang T. Jiang H. Gao B. Han Z. Liu W. Wu Y. Chang G. Zhao (2004) Angew. Chem. Int. Ed. 43 1397 Occurrence Handle10.1002/anie.200352682
D. Zhao J. Feng Q. Huo N. Melosh G.H. Fredrickson B.F. Chmelka G.D. Stuky (1998) Science 279 548 Occurrence Handle10.1126/science.279.5350.548 Occurrence Handle9438845
(a) G. Suss-Fink, M. Faure and. T. R. Ward, Angew. Chem. Int. Ed. 41 (2002) 99; (b) P.J. Dyson, D.J. Ellis, D.G. Parker and T. Welton, Chem. Commun. 25 (1999).
H.X. Gao B.X. Han J.C. Li T. Jiang Z.M. Liu W.Z. Wu Y.H. Chang J.M. Zhang (2004) Syn. Commun 34 IssueID17 3083 Occurrence Handle10.1081/SCC-200028532
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Huang, J., Jiang, T., Han, B. et al. A Novel Method to Immobilize Ru Nanoparticles on SBA-15 Firmly by Ionic Liquid and Hydrogenation of Arene. Catal Lett 103, 59–62 (2005). https://doi.org/10.1007/s10562-005-6503-9
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DOI: https://doi.org/10.1007/s10562-005-6503-9