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New precursor for the post-synthesis preparation of Fe-ZSM-5 zeolites with low iron content

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A new method for preparing ZSM-5 catalysts containing highly dispersed iron species is presented. Iron(III) oxalate was used as the iron precursor in an aerobic aqueous exchange process. The presence of different iron species inside the zeolite pores was investigated by IR spectroscopy of adsorbed NO, which revealed an excellent iron dispersion. The results were compared with those obtained on a Fe-ZSM-5 catalysts prepared by iron(II) chloride sublimation and on samples prepared by controlled migration of framework iron in isomorphously substituted samples.

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Authors and Affiliations

  1. Faculty of Industrial Chemistry, Technical University ‘‘Gh. Asachi’’ Iasi, 71A, Dimitrie Mangeron Blvd., Iasi, 700050, Romania

    Mircea-Teodor Nechita

  2. Dipartimento di Chimica Inorganica, Chimica Fisica e Chimica dei Materiali, Università di Torino, Via P. Giuria 7, 10125, Torino, Italy

    Gloria Berlier, Gabriele Ricchiardi, Silvia Bordiga & Adriano Zecchina

  3. Centre of Excellence, University of Torino, Italy

    Gloria Berlier, Gabriele Ricchiardi, Silvia Bordiga & Adriano Zecchina

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  1. Mircea-Teodor Nechita
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  2. Gloria Berlier
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  5. Adriano Zecchina
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Correspondence to Adriano Zecchina.

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Nechita, MT., Berlier, G., Ricchiardi, G. et al. New precursor for the post-synthesis preparation of Fe-ZSM-5 zeolites with low iron content. Catal Lett 103, 33–41 (2005). https://doi.org/10.1007/s10562-005-6500-z

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  • DOI: https://doi.org/10.1007/s10562-005-6500-z

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