Abstract
The effect of calcium and potassium on the physiochemical properties and performance of V2O5/ZrO2 catalyst for oxidative dehydrogenation of propane was studied in the temperature range of 385–400 °C. The vanadia loading was kept constant at 5 VOx/nm2 and the atomic ratio A/V (A=Ca, K) was varied from 0.05 to 0.75. The vanadia surface structure was investigated using X-ray diffraction analysis (XRD), electron paramagnetic resonance (EPR), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). The redox property of the catalysts was studied by temperature programmed reduction (TPR) and temperature programmed oxidation (TPO) whereas surface acidity was measured by temperature programmed desorption (TPD) of ammonia. Calcium and potassium both interact with the surface V=O and stabilize the +5 oxidation state of vanadium. Interaction between calcium and vanadium was more intense though surface concentration of calcium was lower than that of potassium. For doped catalysts, the activity was lower due to an increase in reduction temperature as well as a lower extent of reduction and increased resistance to undergo redox cycles. On the other hand, removal of surface acidic sites by the dopants increased the propene selectivity. Potassium was more effective in decreasing the activity and increasing the propene selectivity.
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S. Albrecht G. Wendt G. Lippold A. Adamski K. Dyrek (1997) Solid State Ionics 101–103 909 Occurrence Handle10.1016/S0167-2738(97)00387-1
Y. Toda T. Ohno F. Hatayama H. Miyata (2001) Appl. Catal. A 207 273 Occurrence Handle10.1016/S0926-860X(00)00657-8
Z. Feng W.S. Postula C. Erkey C.V. Philip A. Akgerman R.G. Anthony (1994) J. Catal. 148 84 Occurrence Handle10.1006/jcat.1994.1188
T. Ohno Y. Bunno F. Hatayama Y. Toda H. Miyata (2001) Appl. Catal. B 30 421 Occurrence Handle10.1016/S0926-3373(00)00257-5
M. De D. Kunzru (2004) Catal. Lett. 96 33 Occurrence Handle10.1023/B:CATL.0000029526.50161.3e
H. Toraya M. Yoshimura S. Somiya (1984) J. Am. Ceram. Soc. 67 C119
G.K. Chuah S. Jaenicke (1997) Appl. Catal. A 163 261 Occurrence Handle10.1016/S0926-860X(97)00103-8
E.E. Platero M.P. Mentruit (1997) Langmuir 13 3150 Occurrence Handle10.1021/la960789k
A. Khodakov J. Yang S. Su E. Iglesia A.T. Bell (1998) J. Catal. 177 343 Occurrence Handle10.1006/jcat.1998.2143
G.T. Went S.T. Oyama A.T. Bell (1990) J. Phys. Chem. 94 4240 Occurrence Handle10.1021/j100373a067
X. Gao J. Jehng I.E. Wachs (2002) J. Catal. 209 43 Occurrence Handle10.1006/jcat.2002.3635
T. Blasco A. Galli J.M. Lopez Nieto F. Trifiro (1997) J. Catal. 169 203 Occurrence Handle10.1006/jcat.1997.1673
P. Rybarczyk H. Berndt J. Radnik M.M. Pohl O. Buyevskaya M. Baerns A. Brückner (2001) J. Catal. 202 45 Occurrence Handle10.1006/jcat.2001.3251
M. Panizza C. Resini F. Raccoli G. Busca R. Catani S. Rossini (2003) Chem. Eng. J. 93 181
W. Chu T. Echizen Y. Kamiya T. Okuhara (2004) Appl. Cat. A 259 199 Occurrence Handle10.1016/j.apcata.2003.09.041
J. Räty T.A. Pakkanen (2001) Appl. Cat. A 208 169 Occurrence Handle10.1016/S0926-860X(00)00704-3
G. Garcia Cortez J.L.G. Fierro M.A. Baňares (2003) Catal. Today 78 219 Occurrence Handle10.1016/S0920-5861(02)00341-3
E.A. Mamedov V. Cortés Corberán (1995) Appl. Catal. A 127 1 Occurrence Handle10.1016/0926-860X(95)00056-9
D. Creaser B. Andersson R.R. Hudgins P.L. Silveston (1999) Appl. Catal. A 187 147 Occurrence Handle10.1016/S0926-860X(99)00201-X
K. Chen A. Khodakov J. Yang A.T. Bell E. Iglesia (1999) J.␣Catal. 186 325
G. Deo I.E. Wachs (1994) J. Catal. 146 323 Occurrence Handle10.1006/jcat.1994.1071
M.A. Bañares M.V. Martínez-Huerta X. Gao J.L.G. Fierro I.E. Wachs (2000) Catal. Today 61 295 Occurrence Handle10.1016/S0920-5861(00)00388-6
J. Van Hengstum J.G. Van Ommen H. Boseh P.J. Gellings (1983) Appl. Catal. A 8 369 Occurrence Handle10.1016/0166-9834(83)85007-6
S. Anniballi F. Cavani A. Guerrini B. Panzacchi F. Trifirò C. Fumagalli R. Leanza G. Mazzoni (2003) Catal. Today 78 117
A. Lemonidou L. Nalbandian I.A. Vasalos (2000) Catal. Today 61 333
F. Roozeboom M.C. Mittelmeijer- Hazeleger J.A. Moulijn J. Medema V.H.J. de Beer Particlede P.J. Gellings (1980) J. Phys. Chem. 84 2783
S. Varma B.N. Wani N.M. Gupta (2001) Appl. Catal. A 205 295
T. Blasco J.M. Lopez Nieto (1997) Appl. Catal. A 157 117
H.W. Zanthoff M. Lahmer M. Baerns E. Klemm M. Seitz G. Emig (1997) J. Catal. 172 203
M.D. Argyle K. Chen C. Resini C. Krebs A.T. Bell E. Iglesia (2004) J. Phys. Chem. B 108 2345
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De, M., Kunzru, D. Effect of calcium and potassium on V2O5/ZrO2 catalyst for oxidative dehydrogenation of propane: a comparative study. Catal Lett 102, 237–246 (2005). https://doi.org/10.1007/s10562-005-5862-6
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DOI: https://doi.org/10.1007/s10562-005-5862-6