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Mesoporous catalytic membranes: Synthetic control of pore size and wall composition

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Abstract

Atomic layer deposition (ALD) on anodic aluminium oxide (AAO) is shown to be a facile, flexible route to the synthesis of catalytic membranes with precise control of pore wall composition and diameters. The oxidative dehydrogenation of cyclohexane was shown to depend strongly on pore diameter and to be more specific than similarly active alumina powder catalysts.

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Authors and Affiliations

  1. Materials Science Division, Argonne National Laboratory, Argonne, IL, 60439, USA

    M.J. Pellin, G. Xiong, J. Birrell, L. Curtiss, C.Y. Han, L. Iton & H.-H. Wang

  2. Chemistry Division, Argonne National Laboratory, Argonne, IL, 60439, USA

    P.C. Stair

  3. Energy Systems Division, Argonne National Laboratory, Argonne, IL, 60439, USA

    J.W. Elam

  4. Department of Chemistry and Center for Catalysis and Surface Science, Northwestern University, Evanston, IL, 60208, USA

    P.C. Stair

  5. Chemical Engineering Department, Northwestern University, Evanston, IL, 60208, USA

    H. Kung & M. Kung

  6. Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO, 80309, USA

    S.M. George

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  1. M.J. Pellin
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  2. P.C. Stair
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  10. H. Kung
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Correspondence to M.J. Pellin.

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Pellin, M., Stair, P., Xiong, G. et al. Mesoporous catalytic membranes: Synthetic control of pore size and wall composition. Catal Lett 102, 127–130 (2005). https://doi.org/10.1007/s10562-005-5843-9

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  • DOI: https://doi.org/10.1007/s10562-005-5843-9

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