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Branching of the intermediate N2O decomposition in a steady-state NO + CO + O2 reaction on Pd(110); an angle-resolved desorption study

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The branching of the intermediate N2O decomposition vs. the desorption was studied in a steady-state NO + CO + O2 reaction on Pd(110). Three surface-nitrogen removal processes, i.e., N2O(a) → N2(g) + O(a), N2O(a) → N2O(g) and 2N(a) → N2(g), are operative. Only about 20% of N2O(a) was desorbed without decomposition for a (NO:CO = 1:1) mixture. The fraction increased steeply with increasing surface oxygen.

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Authors and Affiliations

  1. Catalysis Research Center, Hokkaido University, Sapporo, 001-0021, Japan

    Y. -S. Ma, I. I. Rzeznicka & T. Matsushima

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  1. Y. -S. Ma
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  2. I. I. Rzeznicka
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  3. T. Matsushima
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Correspondence to T. Matsushima.

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Ma, Y.S., Rzeznicka, I.I. & Matsushima, T. Branching of the intermediate N2O decomposition in a steady-state NO + CO + O2 reaction on Pd(110); an angle-resolved desorption study. Catal Lett 101, 109–116 (2005). https://doi.org/10.1007/s10562-005-3758-0

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  • DOI: https://doi.org/10.1007/s10562-005-3758-0

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