Abstract
The insoluble Wilkinson catalyst RhCl[P(m-C6H4SO3)Na)3]3 changes from inert to very active by supported on mesoporous material SBA-15, and the catalyst is stable, easy to separate from products, clean, and can be reused directly. This catalyst combines the advantages of homogeneous catalysts and heterogeneous catalysts very well.
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Huang, J., Jiang, T., Han, B. et al. Insoluble Wilkinson Catalyst RhCl(TPPTS)3 Supported on SBA-15 for Heterogeneous Hydrogenation with and Without Supercritical CO2 . Catalysis Letters 98, 225–228 (2004). https://doi.org/10.1007/s10562-004-8684-z
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DOI: https://doi.org/10.1007/s10562-004-8684-z