Abstract
Chemoselective hydrogenation of nerol was investigated over Pt/SiO2, Pt/H-Y and Pt/H-MCM-41 catalysts. The initial total reaction rates decreased in following order: Pt/H-Y > Pt/SiO2 > Pt/H-MCM-41. Nerol hydrogenation was found to be an apparent structure sensitive reaction. The selectivities to citronellol at 30% conversion of nerol were 65%, 55% and 25% over Pt/SiO2, Pt/H-MCM-41 and Pt/H-Y, respectively.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
D. Pybus and C. Sell (eds), The chemistry of fragrances, (The Royal Society of Chemistry, Cambridge, UK, 1999), p. 54.
U. K. Singh, M. N. Sysak and M. A. Vannice, J. Catal. 191 (2000) 181.
R. Hubaut, React. Kinet. Catal. Lett. 46 (1992) 25.
P. H. G. Zarbin, A. Reckziegel, E. Plass, A. R. M. de Oliveira, F. Simonelli and F. de A. Marques, J. Braz., Chern. Soc. 11 (2000) 572.
P. Ma ¨ki-Arvela, L.-P. Tiainen, M. Lindblad, K. Demirkan, N. Kumar, R. Sjo ¨holm, T. Ollonqvist, J. Va ¨yrynen, T. Salmi and D. Yu. Murzin, Appl. Catal. A:Gen. 241 (2003) 271.
A. A. Wismeijer, A. P. G. Kieboom and H. van Bekkum, Appl. Catal. 25 (1986) 181.
H.-G. Goebbel, T. Gerlach, G. Wegner, H. Fuchs, S. Unterver-richt and A. Salden, WO 2004007411 (2004)
D. Tas, R. F. Parton, K. Vercruysse and P. A. Jacobs Stud. Surf. Sci. Catal., H. Chon, S.-K. Ibm and Y. S. Uh (eds. ) Vol. 105, (Elsevier, Amsterdam, 1997) 1261 p.
V. V. Goidin, V. V. Molchanov, R. A. Buyanov, G. A. Tolstikov and A. I. Lukashevich, RU 2196762 (2003)
E. L. Woroch, I. Cole and J. W. Cole, US 2990422, (1961)
S. A. Voitkevich, N. N. Zelenetskii, V. V. Kashnikov and O. N. Zhuchkova, Maslozhirovaya Promyshlennost 2 (1975) 28.
A. Pak, D. Sokolskii and S. Konuspaev, Kinet. Katal. 21 (1979) 670.
D. Sokolskii, A. Pak and S. Konuspaev, Kinet. Katal. 20 (1979) 884.
J. Court, J. Jablonski and S. Hamar-Thibault, Stud. Surf. Sci. Catal., M. Guisnet, J. Barbier, J. Barrault, C. Bouchoule, D. Duprez, G. Pe ´rot and C. Montasssier (eds) Vol. 78 (Elsevier, Amsterdam, 1993) 155 p.
A. F. Trasarti, A. J. Marchi and C. R. Apesteguý ´a, J. Catal. 224 (2004) 484.
J. Haje ´k, N. Kumar, P. Ma ¨ki-Arvela, T. Salmi, D. Yu. Murzin, I. Paseka, T. Heikkila ¨, E. Laine, P. Laukkanen and J. Va ¨yrynen, Appl. Catal. A: Gen. 251 (2003) 385.
N. Kumar, P. Ma ¨ki-Arvela, J. Haje ´k, T. Salmi, D. Yu. Murzin, T. Heikkila ¨, E. Laine, P. Laukkanen and J. Va ¨yrynen, Microp. Mesop. Mater. 69(3) (2004) 173.
S. Coman, M. Florea, F. Cacti, V. I. Parvalescu, P. A. Jacobs, C. Danumah and S. Kaliaguine, Chem. Commun. 21 (1999) 2175.
N. Kumar, F. Klingstedt and L.-E. Lindfors, Stud. Surf. Sci. Catal. A. Carma, F. V. Melo, S. Mendioroz and J. L. G. Fierro (eds) Vol. 130 (Elsevier, Amsterdam, 2000), 2981 p.
J. S. Beck, US Patent 5057296 (1991)
C. A. Emeis, J. Catal. 141 (1993) 347.
K. Kinoshita and P. Stonehart, Modern Aspects of Electro-chemistry, J. O. M. Bockris and B. E. Conway (eds) (Plenum Press, New York, 1977).
R. A. van Santen, P. W. van Leeuwen, J. A. Moulijn and P. A. Averlill (eds) Stud. Surf. Sci. Catal. 2nd ed., Vol. 123, (Elsevier, Amsterdam, 1999) 375 p.
J. S. Yu, J. Y. Kim and L. Kevan, Microporous Mater. 40 (2000) 135.
F. Iosif, S. Coman, V. Pârvulescu, P. Grange, S. Delsarte, D. De Vos and P. Jacobs, Chem. Comm., 11 (2004) 1292.
D. Kubicka, N. Kumar, P. Ma ¨ki-Arvela, M. Tiitta, V. Niemi, H. Karhu, T. Salmi and D. Yu. Murzin, J. Catal. (in press).
C. Hoang-Van and O. Zegaoui, Appl. Catal., A:Gen. 164 (1997) 91.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Mäki-Arvela, P., Kumar, N., Paseka, I. et al. Support Effects in Nerol Hydrogenation over Pt/SiO2, Pt/H-Y and Pt/H-MCM-41 Catalysts. Catalysis Letters 98, 173–179 (2004). https://doi.org/10.1007/s10562-004-8677-y
Issue Date:
DOI: https://doi.org/10.1007/s10562-004-8677-y