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In situ Ga K edge XANES study of the activation of Ga/ZSM-5 prepared by chemical vapor deposition of trimethylgallium

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The activation of a dimethylgallium/ZSM-5 precursor to well-defined reduced and oxidized species is studied by in situ Ga K edge XANES. The precursor is prepared by chemical implanting of trimethylgallium on acidic HZSM-5. Subsequent reduction leads to charge-compensating Ga+ species. Direct oxidation of the trimethylgallium precursor leads to various forms of gallium oxide and regeneration of Brønsted acid protons. Oxidation of the reduced Ga+ species yields predominantly to GaO+ species. The GaO+ species exhibit a much higher H2/D2 exchange activity than reduced Ga+ species.

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References

  1. J.R. Mowry R.F. Anderson J.A. Johnson (1985) Oil Gas J. 83 1288

    Google Scholar 

  2. C. Doolan P.R. Pujado (1989) Hydrocarbon Proc. 68–69 72

    Google Scholar 

  3. Kitagawa Y. Sendoda Y. Ono (1986) J. Catal. 101 12

    Google Scholar 

  4. N.S. Gnep J.Y. Doyemet M. Guisnet (1988) J. Mol. Catal. 45 281

    Google Scholar 

  5. M. Guisnet N.S. Gnep F. Alario (1992) Appl. Catal. A: General 89 1

    Google Scholar 

  6. B.S. Kwak W.M.H. Sachtler W.O. Haag (1994) J. Catal. 149 465

    Google Scholar 

  7. B.S. Kwak Sachtler W.M.H. (1994) J. Catal. 145 456

    Google Scholar 

  8. J. Yao R. Mao Particlele van L. Dufresne (1990) Appl. Catal. A: General 65 175

    Google Scholar 

  9. E. Iglesia J.E. Baumgartner G.L. Price (1992) J. Catal. 134 549

    Google Scholar 

  10. G.D. Meitzner E. Iglesia J.E. Baumgarnter E.S. Huang (1993) J.␣Catal. 140 209

    Google Scholar 

  11. J.A. Biscardi E. Iglesia (1996) Catal. Today 31 207

    Google Scholar 

  12. R. Fricke H. Kosslick G. Lischke M. Richter (2000) Chem. Rev. 100 2303

    Google Scholar 

  13. V.R. Choudhary K. Mantri C. Sivadinarayama (2000) Microporous Mesoporous Mater. 37 1

    Google Scholar 

  14. V.B. Kazansky I.R. Subbotina R.A. Santen Particlevan E.J.M. Hensen (2004) J. Catal. 227 263

    Google Scholar 

  15. K.M. Dooley C. Chang G.L. Price (1992) Appl. Catal. A: General 84 17

    Google Scholar 

  16. G.L. Price V. Kanizirev (1990) J. Catal. 126 267

    Google Scholar 

  17. B.S. Kwak W.M.H. Sachtler (1993) J. Catal. 141 729

    Google Scholar 

  18. El.-M. El Malki R.A. Santen Particlevan W.M.H. Sachtler (1999) J. Phys. Chem. B 103 4611

    Google Scholar 

  19. R.J. Nash M.E. Dry C.T. O’Conner (1996) Appl. Catal. A: General 134 285

    Google Scholar 

  20. B.S. Kwak W.M.H. Sachtler (1993) J. Catal. 141 729

    Google Scholar 

  21. M. Garcia-Sanchez P.C.M.M. Magusin E.J.M. Hensen P.C. Thüne X. Rozanska R.A. Santen Particlevan (2003) J. Catal. 219 352

    Google Scholar 

  22. A.C. Wei P.-H. Liu K.-J. Chao E. Yang H.Y. Cheng (2001) Microporous Mesoporous Mater. 47 147

    Google Scholar 

  23. K.-J. Chao A.C. Wei H.C. Wu J.F. Lee (2000) Microporous Mesoporous Mater. 35–36 413

    Google Scholar 

  24. S.J. Geller (1960) Chem. Phys. 33 676

    Google Scholar 

  25. K. Nishi K.I. Shimizu M. Tahamatzu H. Yoshida A. Satsuma T. Ranaka S. Yoshida T. Hattori (1998) J. Phys. Chem. B 102 10190

    Google Scholar 

  26. K. Shimizu M. Takamatsu K. Nishi H. Yoshida A. Satsuma T. Tanaka S. Yoshida T. Hattori (1999) J. Phys. Chem. B 103 1542

    Google Scholar 

  27. N.W. Mitzel, C. Lustig, R.J.F. Berger and N. Runeberg, Angew. Chem. Int. Ed. (2002) 41

  28. R. Boese A.J. Downs T.M. Greene A.W. Hall C.A. Morrison S. Parsons (2003) Organometallics 22 2450

    Google Scholar 

  29. M. Frash R.A. Santen Particlevan (2000) J. Phys. Chem. A 104 2468

    Google Scholar 

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Authors and Affiliations

  1. Schuit Institute of Catalysis, Eindhoven University of Technology, P.O. Box 513, 5600, MB, Eindhoven, The Netherlands

    Emiel J.M. Hensen, Mayela García-Sánchez, Neelesh Rane, Pieter C.M.M. Magusin & R.A. van Santen

  2. Department of Chemistry, National Tsinghua University, Kuang Fu Road, Hsinchu, 30043, Taiwan, ROC

    Pang-Hung Liu & Kuei-Jung Chao

Authors
  1. Emiel J.M. Hensen
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  2. Mayela García-Sánchez
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  3. Neelesh Rane
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  4. Pieter C.M.M. Magusin
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  5. Pang-Hung Liu
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  6. Kuei-Jung Chao
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  7. R.A. van Santen
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Correspondence to Emiel J.M. Hensen.

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Hensen, E.J., García-Sánchez, M., Rane, N. et al. In situ Ga K edge XANES study of the activation of Ga/ZSM-5 prepared by chemical vapor deposition of trimethylgallium. Catal Lett 101, 79–85 (2005). https://doi.org/10.1007/s10562-004-3753-x

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  • DOI: https://doi.org/10.1007/s10562-004-3753-x

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