Skip to main content
Log in

Calculation of Equilibrium Thermobaric Parameters for the Formation or Dissociation of Hydrates of Multicomponent Gases

  • Published:
Chemical and Petroleum Engineering Aims and scope

An original method for calculating the equilibrium pressure for the formation or dissociation of multicomponent gas hydrates as a function of temperature and composition has been developed. It is applicable to gas and water systems that are in the following phase states: gas–water vapor–ice; gas–water vapor–liquid water. The developed method is suitable for determining the equilibrium conditions for the formation (dissociation) of hydrates of multicomponent gases depending on their composition with an accuracy of about 1%. The novelty of the developed method is protected by a patent of the Russian Federation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. E. P. Zaporozhets and N.A. Shostak, Hydrates [in Russian], Publishing House — Yug, Krasnodar (2014).

  2. V. A. Istomin and V. S. Yakushev, Naturally Occurring Gas Hydrates [in Russian], Nedra, Moscow (1992).

  3. J. Carroll, Natural Gas Hydrates [in Russian], Gulf Professional Publishing, Burlington (2009).

  4. S.-S. Fan and T.-M. Guo, J. Chem. Eng. Data, 44, 829–832 (1999).

    Article  CAS  Google Scholar 

  5. E. Khosravani, G. Moradi, and S. Sajjadifar, J. Chem. Thermodynamics, 57, 286–294 (2013).

    Article  CAS  Google Scholar 

  6. D.-H. Mei, J. Liao, J.-T. Yang, and T.-M. Guo, Ind. Eng. Chem. Res., 35, 4342–4347 (1996).

    Article  CAS  Google Scholar 

  7. M. M. Mooijervan den Heuvel Phase, Behaviour and Structural Aspects of Ternary Clathrate Hydrate Systems [in Russian], Dissertation, Technische Universiteit Delft (2004).

  8. Y.-T. Seo, H. Lee, and J.-H. Yoon, J. Chem. Eng. Data, 46, 381–384 (2001).

    Article  CAS  Google Scholar 

  9. E. D. Sloan and C. A. Koh, Clathrate Hydrates of Natural Gases [in Russian], CRC Press, Boca Raton (2008).

  10. C.-Y. Sun, G.-J. Chen, W. Lin, and T.-M. Guo, J. Chem. Eng. Data, 48, 600–602 (2003).

    Article  CAS  Google Scholar 

  11. E. P. Zaporozhets and N. A. Shostak, Zh. Fiz. Khim., 90, No. 9, 1389–1395 (2016).

    Google Scholar 

  12. Pat. RF No. 2625544, IPC C1 G01N 7/00, G01K 13/00, G01N 25/02, The Method for Determining Thermobaric Parameters of Hydrate Formation in a Multicomponent Mixture [in Russian], Bull. No. 20 (2017).

Download references

The study was carried out with the financial support of the Russian Foundation for Basic Research in the framework of research project No. 16-38-60108.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. P. Zaporozhets.

Additional information

Translated from Khimicheskoe i Neftegazovoe Mashinostroenie, Vol. 54, No. 12, pp. 14–17, December, 2018.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zaporozhets, E.P., Shostak, N.A. Calculation of Equilibrium Thermobaric Parameters for the Formation or Dissociation of Hydrates of Multicomponent Gases. Chem Petrol Eng 54, 883–889 (2019). https://doi.org/10.1007/s10556-019-00567-z

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10556-019-00567-z

Keywords

Navigation