Results of experiments on the kinetics of hydrogen generation by electrochemical dispersion of an aluminum alloy D16 in an aqueous solution of sodium hydroxide under alternating (AC) electric current are provided. It was found that the rate of hydrogen evolution under alternating electric current is significantly greater than the rate of hydrogen evolution in a reaction without the application of an electric current. The use of an alternating current produces Al(OH)3 powders with more highly disperse particles.
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References
A. Z. Zhuk, B. V. Kleimenov, E. I. Shkol’nikov, et al., Aluminum-Hydrogen Energetics, A. E. Sheyndlina (ed.), JIHT RAS, Moscow (2007).
V. V. Kozlyakov, N. P. Stukalova, and A. Yu. Omarov, “Methods for producing hydrogen as a fuel for cars,” Izv. Mosk. Gos. Industr. Univ., 4, No. 17, 35–42 (2009).
R. G. Romanova, A. F. Dresvyannikov, and A. R. Abdullina, “The development of ceramic materials compositions using nanosized precursors,” Vest. Kazan. Tekhnol. Univ., 15, No. 16, 276–280 (2012).
F. Z. Badaev, V. P. Tarasovskii, R. A. Novoselov, et al., “Preparation of aluminum oxide ceramic precursors by dispersion of aluminum alloy D16,” Refract. Ind. Ceram., 56, No. 1, 11–13 (2015).
B. A. Lur’ye, A. E. Chernyshov, N. N. Perova, and B. S. Svetlov, “Kinetics of interaction of aluminum with water and aqueous solutions of alkalis,” Kinetika i Kataliz, 17, No. 6., 1453–1458 (1976).
V. V. Sysoeva, E. D. Artyugina, V. G. Gorodilova, and E. A. Berkman, “On the issue of aluminum corrosion in alkalis,” Zh. Prikl. Khimii, 58, No. 4, 921–924 (1985).
A. Kh. Khairy, F. Z. Badaev, A. Yu. Omarov, and A. I. Eirich, “A study of the kinetics of the interaction of aluminum-magnesium alloys with an aqueous solution of sodium hydroxide,” Izv. Mosk. Gos. Industr. Univ., 1, No. 25, 42–45 (2012).
F. Z. Badaev, V. V. Rybal’chenko, A. Kh. Khairi, et al., “Determination of kinetic parameters of the interaction of aluminum-magnesium alloys with an aqueous solution of sodium hydroxide,” Mashinostr. Inzh. Obrazov., 1, No. 34, 17–20 (2013).
A. Yu. Baimakov, S. Yu. Petrovich, V. A. Lipin, et al., “Generation of hydrogen by reacting powders of metals and alloys of the aluminum-magnesium system with water, acidic, and basic solutions,” Nauch.-Tekhn. Ved. St.-Peterb. Politekhn. Univ., 2, No. 171, 151–157 (2013).
F. Z. Badaev, A. Kh. Khairi, N. A. Kasatova, and A. I. Eirich, “Kinetics of interaction of aluminum-silicon alloys with an aqueous solution of sodium hydroxide,” Mashinostr. Inzh. Obrazov., 2, No. 35, 44–48 (2013).
F. Z. Badaev, A. Kh. Khairi, and A. N. Kasatova, “Kinetics of interaction of aluminum-titanium alloys with an aqueous solution of sodium hydroxide,” Naukoem. Tekhnol. Mashinostr., 1, No. 31, 3–7 (2014).
F. Z. Badaev, A. Kh. Khairi, R. A. Novoselov, and V. P. Tarasovskii, “Kinetic features of interaction of aluminum-copper alloys with aqueous sodium hydroxide solutions,” Mashinostr. Inzh. Obrazov., 2, No. 43, 34–39 (2015).
CRC Handbook of Chemistry and Physics (2010), 90th ed.
A. P. Kreshkov and A. A. Yaroslavtsev, Analytical Chemistry Course. Quantitative Analysis, Khimiya, Moscow (1982).
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Translated from Khimicheskoe i Neftegazovoe Mashinostroenie, No. 12, pp. 23–25, December, 2016.
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Badaev, F.Z., Khairi, A.K., Reznichenko, A.V. et al. Electrochemical Dispersion of Aluminum Alloys in an Aqueous Sodium Hydroxide Solution. Chem Petrol Eng 52, 834–837 (2017). https://doi.org/10.1007/s10556-017-0279-9
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DOI: https://doi.org/10.1007/s10556-017-0279-9