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Thermodynamics and Mechanics of the Deformation of “Cross-Linked” Elastomers

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Abstract

Kinematic forms of isothermal deformation of resins or other “cross-linked” elastomers are discussed: homogeneous uniaxial tension, simple homogeneous shear deformation, and biaxial orthogonal homogeneous deformation.

It is shown that not only the conformational entropy of the state of the micromolecular structure changes, but also variation in the internal energy of this structure is possible during equilibrium isothermal deformation of “ cross-linked” elastomers.

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REFERENCES

  1. G. M. Bartenev and Yu. V. Zelenev, Course in Polymer Physics [in Russian], Khimiya, Leningrad (1976).

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Authors and Affiliations

  1. Moscow State University of Engineering Ecology (MGUIE), Moscow, Russia

    B. V. Berdyshev, A. A. Borisov & I. A. Gerasimchuk

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  1. B. V. Berdyshev
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  2. A. A. Borisov
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  3. I. A. Gerasimchuk
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Translated from Khimicheskoe i Neftegazovoe Mashinostroenie, No. 6, pp. 3–5, June, 2005.

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Berdyshev, B.V., Borisov, A.A. & Gerasimchuk, I.A. Thermodynamics and Mechanics of the Deformation of “Cross-Linked” Elastomers. Chem Petrol Eng 41, 293–298 (2005). https://doi.org/10.1007/s10556-005-0105-7

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  • DOI: https://doi.org/10.1007/s10556-005-0105-7

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