Skip to main content
Log in

Preparation and Performance Evaluation of P(St-AM) Microencapsulated Gel-Breaking Agents with Core-Shell Structure

  • INNOVATIVE TECHNOLOGIES OF OIL AND GAS
  • Published:
Chemistry and Technology of Fuels and Oils Aims and scope

Utilizing emulsion polymerization, a microcapsule breaker with a polystyrene-polyacrylamide core-shell structure was synthesized. Ammonium persulfate served as the breaker, polystyrene as the shell, and polyacrylamide as the drug-carrying agent. The results demonstrated that the synthesized microencapsulated gel-breaker exhibited a uniform spherical shape, superior water dispersion, and enhanced thermal stability. Conductivity tests indicated that the core-shell structure of the microcapsules effectively regulated the release of ammonium persulfate as a gel-breaking agent, resulting in delayed polymer gel-breaking.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

References

  1. Y. Qian, P. Guo, Y. Wang, et al., “Advances in Laboratory-Scale Hydraulic Fracturing Experiments,” Advances in Civil Engineering, 2020, (2020)

  2. M. A. A. Mahesh Chandra Patel, Mazlin Bt Idress, Anirbid Sircar, “Development of a Novel Surfactant-Based Viscoelastic Fluid System as an Alternative Nonpolymeric Fracturing Fluid and Comparative Analysis with Traditional Guar Gum Gel Fluid,” Polymers, 15, 2444(2023)

  3. C. Zhang, Y. Wang, Z. Wang, et al., “Mechanism Analysis of Enhancing the Temperature and Shear Resistance of Hydroxypropyl Guar Gum Fracturing Fluid by Boron-Functionalized Nanosilica Colloidal Crosslinker,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 676, 132154(2023)

    Article  CAS  Google Scholar 

  4. L. W. Guoyan Ma, Chao Hao, Chunbao Du, et al., “Thermal and Rheological Performances Evaluation of a Modified Biopolymer for Fracturing Fluid System,” Molecules (Basel, Switzerland), 27, 7776(2022)

  5. Q. Tang, Z. Huang, B. Wang, H. Lu, “Surfactant-free aqueous foams stabilized with synergy of xanthan-based amphiphilic biopolymer and nanoparticle as potential hydraulic fracturing fluids,” Colloids & Surfaces A: Phys. Eng. Asp, 603, 125215(2020)

    Article  CAS  Google Scholar 

  6. M. Ishii, S. Murata, K. Ishitsuka, et al, “Stability of novel cellulose-nanofiber-containing foam as environmentally friendly fracturing fluid,” Journal of Petroleum Science and Engineering, 208, 109512(2022)

    Article  CAS  Google Scholar 

  7. O. Budiman, S. Alajmei, “Seawater-Based Fracturing Fluid: A Review,” ACS Omega, 8, 41022-41038(2023)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  8. M. Zhao, S. Liu, Z. Gao, et al., “The spontaneous imbibition mechanisms for enhanced oil recovery by gel breaking fluid of clean fracturing fluid,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 650, 129568(2022)

    Article  CAS  Google Scholar 

  9. M. Zhao, X. Yan, Y. Cheng, et al., “Study on the Imbibition Performance and Mechanism of a Fracturing Fluid and Its Gel Breaking Liquid,” Energy & Fuels, 36, 13028-13036(2022)

    Article  CAS  Google Scholar 

  10. J. Cen, X. Huang, A. Liu, J.-C. Yao, “Identification of discontinuous parameters in contaminant convection–reaction– diffusion model of recovered fracturing fluid,” Communications in Nonlinear Science and Numerical Simulation, 128, 107634(2024)

    Article  Google Scholar 

  11. X. Dong, W. Li, Q. Liu, et al., “Research on the Convection-Reaction-Diffusion Model of Contaminants in Fracturing Flowback Fluid in Non-Equidistant Artificial Fractures with Arbitrary Inclination in (3+1)-Dimensional Space-Time,” ACS Omega, 8, 17901-17921(2023)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  12. T. Bollhorst, K. Rezwan, M. Maas, “Colloidal capsules: nano- and microcapsules with colloidal particle shells,” Chemical Society Reviews, 46, 2091-2126(2017)

    Article  CAS  PubMed  Google Scholar 

  13. E. Koh and Y. T. Lee, “Preparation of Ligand Brush Nanocapsules for Robust Self-Controlled Antimicrobial Activity with Low Cytotoxicity at Target pH and Humidity,” Pharmaceutics, 14, 280(2022)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  14. S. T. Pham, K. A. Tieu, S. Wan, et al, “Intrinsic Effect of Nanoparticles on the Mechanical Rupture of Doubled-Shell Colloidal Capsule via In Situ TEM Mechanical Testing and STEM Interfacial Analysis,” Small (Weinheim an der Bergstrasse, Germany), 16, e2001978(2020)

  15. Y. Sun, J. Shi, Z. Cai, et al, “Mussel-inspired capsules toward reaction-triggered cargo release,” Materials Chemistry Frontiers, 5, 792-798(2021)

    Article  CAS  Google Scholar 

  16. Lieqiang Liao, Xinjian Jia, H. Lou, et al. “Supramolecular gel formation regulated by water content in organic solvents: self-assembly mechanism and biomedical applications,” RSC Advances, 11, 11519-11528(2021).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zhongbin Ye.

Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 2, pp. 79–82, March– April, 2024.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, T., Ye, Z. & Liu, D. Preparation and Performance Evaluation of P(St-AM) Microencapsulated Gel-Breaking Agents with Core-Shell Structure. Chem Technol Fuels Oils 60, 309–314 (2024). https://doi.org/10.1007/s10553-024-01685-y

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10553-024-01685-y

Keywords

Navigation