The evaluation of geochemical properties of source rocks can provide an important basis for the accurate evaluation of hydrocarbon resources. In this paper, taking the Tanhai area of the Damintun Sag of Liaohe Oilfield as an example, the chemical properties of source rocks of the Dongying and Shahejie Formations of Paleogene are compared using a large number of geochemical and hydrocarbon generation thermal simulation results. The results show that the organic carbon content of the Dongying and Shahejie Formations in the study area ranges from 0.4% to 3.2%. It is considered that the source rock of the She 3 Member in Paleogene is good source rock. The Dong 3 and Sha 1 Members are the relatively good source rocks. While the Dong 2 Member is a relatively poor source rock, and the Dong 1 Member is the non-source rock. The vitrinite reflectance of Paleogene mudstone in the study area ranges from 0.33 to 0.93%, with an average value of 0.57%, which belongs to the immature to mature stage. Considering that the organic matter types in this area are mainly type IIB–III, the oil generation threshold is set at 2850 m. It is particularly noteworthy that thick coal measure strata are developed in the lower part of the Dong 3 Member and the upper part of the Sha 3 Member, although they are of poor type as oil source rocks, however, they are of great potential value as gas source rocks. The Shahejie source rock has the closest affinity with crude oil. Natural gas in the study area is mainly wet gas and a small amount is dry gas. The ratio of isobutane to n-butane (iC4 /nC4 ) in natural gas increased with decreasing depth, showing a certain migration differentiation effect. It is speculated that the Shahejie Formation source rock is the main source of natural gas in the Taiyangdao – Kuihuadao Structure.
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References
Valenza J. J., Drenzek N., Marques F., et al. Geochemical controls on shale microstructure [J]. Geology, 2023, 41(5): 611-614.
Wang G., Ju Y., Yan Z., et al. Pore structure characteristics of coal–bearing shale using fluid invasion methods: A case study in the Huainan–Huaibei Coalfield in China [J]. Marine and Petroleum Geology, 2015, 62, 1-5.
Asante-Okyere S., Ziggah Y.Y., Marfo S.A. Improved total organic carbon convolutional neural network model based on mineralogy and geophysical well log data [J]. Unconventional Resources, 2021, 1: 1-8.
Andrew D., Bradley D., Moldowan J. Organic geochemistry of oil and source rock strata of the Ordos Basin, north-central China [J]. AAPG Bulletin, 2021, 91(9): 1273-1293.
Liu Y.F., Tang Y.F., Chang Q.H., et al. Development of a novel heat- and shear-resistant nano-silica gelling agent [J]. Nanotechnology Reviews, 2022, 11(1): 2786-2799.
Deng X.Q., Yao T.L., Hu X.F., et al. Characteristics and geological significance of hydrodynamic system on ultra-low permeability reservoir of Yanchang formation in Ordos Basin [J]. Journal of Northwest University (Natural Science Edition), 2011, 41(6): 1044-1050 (in Chinese with English abstract).
Yin S., Dong L., Yang X., et al. Experimental investigation of the petrophysical properties, minerals, elements and pore structures in tight sandstones [J]. Journal of Natural Gas Science and Engineering, 2020, 76(1): 1-14.
Li Q., Liu Z., Chen F., et al. Behavior and controlling factors of methane adsorption in Jurassic continental shale, northeastern Sichuan Basin [J]. Energy Geoscience, 2023, 4(1): 83-92.
Wang H., Zhou S., Li S., et al. Comprehensive characterization and evaluation of deep shales from Wufeng-Longmaxi Formation by LF-NMR technology [J]. Unconventional Resources, 2022, 2: 1-11.
Peters K.E., Walters C.C., Moldowan J.M. The biomarker guide (Volume 2): Biomarkers and isotopes in petroleum exploration and earth history [M]. Cambridge: Cambridge University Press, 2005.
Peters K.E., Moldowan J.M. Guide for the application of biological markets [M]. New Jersey: Prentice-Hall, 1993.
Wang W., Liu Q., Jing W., et al. Accumulation Conditions and Pattern of Tight Oil in the Lower Submember of the Fourth Member of the Shahejie Formation in the Damintun Sag, Bohai Bay Basin [J]. Processes, 2023, 11: 135-136.
Yang H., Liu X.Y., Zhang C.L., et al. The main controlling factors and distrubution of low permeability lithologic reservoirs of the Triassic Yanchang Formation in Ordos Basin [J]. Lithologic Reservoirs, 2007, 19(3): 1-6 (in Chinese with English abstract).
Zhang H., Meng X.Z., Pu R.H., et al. Chang 1 lacustrine sediments and oil-source-rock conditions in Zichang-Panlong area [J]. Journal of Northwest University, 2012, 42(1): 82-87 (in Chinese with English abstract).
Yang J., Wang M., Li M., et al. Shale lithology identification using stacking model combined with SMOTE from well logs [J]. Unconventional Resources, 2022, 2: 108-115.
Jarvie D.M., Hill R.J., Pollastro R.M., et al. Evaluation of unconventional natural gas prospects in the Barnett Shale: fractured shale gas model [C]. In: European Asso-ciation of International Organic Geochemists Meeting, Poland, 2023, September 8-12. Poland, Krakow.
John C.L., Jenny L.S., David S.S. Natural fractures in the Spraberry Formation, Midland Basin, Texas: the effects of mechanical stratigraphy on fracture variability and reservoir behavior [J]. AAPG Bulletin American Association of Petroleum Geologists, 2002, 86: 505-524.
Huang X., Gu L., Li S., et al. Absolute adsorption of light hydrocarbons on organic-rich shale: An efficient determination method [J]. Fuel, 2022, 308: 121998.
Yin S., Han C., Wu Z., et al. Developmental characteristics, influencing factors and prediction of fractures for a tight gas sandstone in a gentle structural area of the Ordos Basin, China [J]. Journal of Natural Gas Science and Engineering, 2019, 72(12): 1-14.
Lai J., Wang G. Fractal analysis of tight gas sandstones using High-Pressure Mercury Intrusion techniques [J]. Journal of Natural Gas Science and Engineering, 2015, 24: 185-196.
Curtis M. E., Cardott B. J., Sondergeld C. H., et al. Development of organic porosity in the Woodford Shale with increasing thermal maturity [J]. International Journal of Coal Geology, 2012, 103: 26-31.
Wang X., Liu Y., Hou J., Li S., et al. The relationship between synsedimentary fault activity and reservoir quality - A case study of the Ek1 formation in the Wang Guantun area, China [J]. Interpretation, 2022, 8: 15-24.
Corbett K.P., Friedman M., Spang J. Fracture development and mechanical stratigraphy of Austin Chalk, Texas [J]. AAPG Bulletin American Association of Petroleum Geologists, 1987, 71: 17-28.
Shuai Y., Zhang S., Mi J., et al. Charging time of tight gas in the Upper Paleozoic of the Ordos Basin, central China [J]. Organic Geochemistry, 2013, 64: 38-46.
Luo Z., Xie R., Cai W., et al. Comprehensive logging identification method of shell limestone fractures in the Lower Jurassic Da’anzhai Member in the Dongpo area of the Western Sichuan Depression [J]. Unconventional Resources, 2022, 2: 97-107.
Shanley K.W., Cluff R.M. The evolution of pore-scale fluid-saturation in low permeability sandstone reservoirs [J]. AAPG Bulletin, 2015, 99: 1957-1990.
Shi D.S., Li M.W., Pang X.Q., et al. Fault-fracture mesh petroleum plays in the Zhanhua Depressio, Bohai Bay Basin: Part2. Oil-source correlation and secondary migration mechanisms [J]. Organic Geochemistry, 2004, 36: 203-223.
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Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 3, pp. 125–131 May – June, 2023.
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Yu, Z., Yin, S. Experimental Study on Geochemical Characteristics of Paleogene Source Rocks. Chem Technol Fuels Oils 59, 588–598 (2023). https://doi.org/10.1007/s10553-023-01559-9
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DOI: https://doi.org/10.1007/s10553-023-01559-9