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Coarsely Granulated Macroporous Adsorbent for Adsorption Cleaning of Heavy Oil Stock

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Chemistry and Technology of Fuels and Oils Aims and scope

Adsorption method of oil residue upgrading without hydrogen using coarsely granulated macroporous adsorbents with a high mechanical strength, a small surface area, and a large volume of macropores, modified with various additives was investigated. To create a macroporous structure, templates, namely, guar gum and wax emulsion, were tested. Both templates showed high effectiveness, but use of wax made it possible to get adsorbents with a larger pore volume. The process of adsorption-contact cleaning of stock based on cracking residue of visbreaking reduced content of heavy metals by 98 %, while conversion of residue boiling above 540 °C was 75 %. Adsorption-contact cleaning on large coarsely granulated adsorbent can be used to get a feedstock for hydrofining process aimed at getting a low-sulfur marine fuel and a feedstock for catalytic cracking.

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Authors and Affiliations

  1. All-Russian Research Institute of Oil Refining JSC, Moscow, Russia

    R. F. Yuzmukhametova, O. I. Shmelkova, R. E. Boldushevsky, Yu. A. Khamzin, A. A. Shipiltsyna, S. A. Antonov & P. A. Nikulshin

  2. Gubkin University, Moscow, Russia

    R. F. Yuzmukhametova, S. A. Antonov & P. A. Nikulshin

Authors
  1. R. F. Yuzmukhametova
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  2. O. I. Shmelkova
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  3. R. E. Boldushevsky
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  4. Yu. A. Khamzin
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  5. A. A. Shipiltsyna
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  6. S. A. Antonov
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  7. P. A. Nikulshin
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Corresponding author

Correspondence to R. F. Yuzmukhametova.

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Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 4, pp. 9–15 July–August, 2022.

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Yuzmukhametova, R.F., Shmelkova, O.I., Boldushevsky, R.E. et al. Coarsely Granulated Macroporous Adsorbent for Adsorption Cleaning of Heavy Oil Stock. Chem Technol Fuels Oils 58, 582–589 (2022). https://doi.org/10.1007/s10553-022-01423-2

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  • DOI: https://doi.org/10.1007/s10553-022-01423-2

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