Glass transition processes occurring in the wide heavy fraction of Kumkolsk oil and its six narrow heavy fractions across the temperature range of 150–370 K were investigated by differential scanning calorimetry. Glass transition in the narrow fractions under study undergoes at different temperatures. Two of the most widely used equations that relate the glass transition temperature of a mixture (wide heavy fraction) and its components (narrow heavy fractions) were tested, both linear additive and inverse-additive relationships.
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References
A. V. Lesikar, Phys. Chem. Glasses., 16(4), 83–90 (1975).
A. V. Lesikar, J. Chem. Phys., 66, 4263–4276 (1977). https://doi.org/10.1063/1.433736
S. Lau, J. Pathak, and B. Wunderlich, Macromolecules, 15(5), 1278–1283 (1982).
M. Aubin, R. E. Prud’homme, Macromolecules, 21(10), 2945–2949 (1988).
J. E. G. Lipson and S. T. Milner, J. Polym. Sci., Part B: Polym. Phys., 44(24), 3528–3545 (2006).
J. Gordon, G. Rouse, J. Gibbs, et al., J. Chem. Phys., 66(11), 4971–4976 (1977).
P. Couchman and F. Karasz, Macromolecules, 11(1), 117–119 (1978).
T.P. Lodge and T. C. B. McLeish, Macromolecules, 33(14), 5278–5284 (2000).
J. M. Pochan and C. L. Beatty, Polymer, 20, 879–886 (1979).
J. Richmond, O. Nilsson, and O. Sandberg, J. Appl. Phys., 56(7), 2065–2067 (1984).
M. Albert, F. Bosselet, P. Claudy, et al., Thermochim. Acta, 84, 101–110 (1985).
P. Claudy, J. M. Letoffe, B. Neff, et al., Fuel, 65, 861–864 (1986).
P. Claudy, J. M. Letoffe, B. Chague, et al., Fuel, 67, 58–61 (1988).
A. Hansen, E. Larsen, W. Pedersen, et al., Energy Fuels, 5, 914–923 (1991).
H. P. Ronningsen, B. Bjorndal, A. B. Hansen, et al., Energy Fuels, 5, 895–907 (1991).
E. Gimzewski and G. Audley, Thermochim. Acta, 214, 149–155 (1993).
V. Kutcherov, G. Bäckström, M. Anisimov, et al., Int. J. Thermophys., 14(91), 91–100 (1993).
V. Kutcherov, A. Lundin, R. G. Ross, et al., Int. J. Thermophys., 15(1), 165–176 (1994).
V. Kutcherov, A. Chernoutsan, and V. Brazhkin, J. Molecular Liquids, 241, 428–434 (2017).
V. Kutcherov, Int. J. Thermophys, 27(2), 467–473 (2006).
V. Kutcherov and A. Chernoutsan, Int. J. Thermophys., 27(2), 474–485 (2006).
P. Skoglund and Å Fransson, Thermochim. Acta, 276, 27–39 (1996).
C. A. Angell and W. Sichina, Annals of the New York Academy of Sciences, 279(1), 53–67 (1976).
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Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 3, pp. 62–64 May–June, 2022.
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Kutcherov, V.G., Chernoutsan, A.I. Glass Transition of Oil Fractions. Chem Technol Fuels Oils 58, 484–487 (2022). https://doi.org/10.1007/s10553-022-01411-6
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DOI: https://doi.org/10.1007/s10553-022-01411-6