Skip to main content
Log in

Glass Transition of Oil Fractions

  • INNOVATIVE TECHNOLOGIES OF OIL AND GAS
  • Published:
Chemistry and Technology of Fuels and Oils Aims and scope

Glass transition processes occurring in the wide heavy fraction of Kumkolsk oil and its six narrow heavy fractions across the temperature range of 150–370 K were investigated by differential scanning calorimetry. Glass transition in the narrow fractions under study undergoes at different temperatures. Two of the most widely used equations that relate the glass transition temperature of a mixture (wide heavy fraction) and its components (narrow heavy fractions) were tested, both linear additive and inverse-additive relationships.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.

Similar content being viewed by others

References

  1. A. V. Lesikar, Phys. Chem. Glasses., 16(4), 83–90 (1975).

    CAS  Google Scholar 

  2. A. V. Lesikar, J. Chem. Phys., 66, 4263–4276 (1977). https://doi.org/10.1063/1.433736

    Article  CAS  Google Scholar 

  3. S. Lau, J. Pathak, and B. Wunderlich, Macromolecules, 15(5), 1278–1283 (1982).

    Article  CAS  Google Scholar 

  4. M. Aubin, R. E. Prud’homme, Macromolecules, 21(10), 2945–2949 (1988).

    Article  CAS  Google Scholar 

  5. J. E. G. Lipson and S. T. Milner, J. Polym. Sci., Part B: Polym. Phys., 44(24), 3528–3545 (2006).

    Article  CAS  Google Scholar 

  6. J. Gordon, G. Rouse, J. Gibbs, et al., J. Chem. Phys., 66(11), 4971–4976 (1977).

    Article  CAS  Google Scholar 

  7. P. Couchman and F. Karasz, Macromolecules, 11(1), 117–119 (1978).

    Article  CAS  Google Scholar 

  8. T.P. Lodge and T. C. B. McLeish, Macromolecules, 33(14), 5278–5284 (2000).

    Article  CAS  Google Scholar 

  9. J. M. Pochan and C. L. Beatty, Polymer, 20, 879–886 (1979).

    Article  CAS  Google Scholar 

  10. J. Richmond, O. Nilsson, and O. Sandberg, J. Appl. Phys., 56(7), 2065–2067 (1984).

    Article  CAS  Google Scholar 

  11. M. Albert, F. Bosselet, P. Claudy, et al., Thermochim. Acta, 84, 101–110 (1985).

    Article  CAS  Google Scholar 

  12. P. Claudy, J. M. Letoffe, B. Neff, et al., Fuel, 65, 861–864 (1986).

    Article  CAS  Google Scholar 

  13. P. Claudy, J. M. Letoffe, B. Chague, et al., Fuel, 67, 58–61 (1988).

    Article  CAS  Google Scholar 

  14. A. Hansen, E. Larsen, W. Pedersen, et al., Energy Fuels, 5, 914–923 (1991).

    Article  Google Scholar 

  15. H. P. Ronningsen, B. Bjorndal, A. B. Hansen, et al., Energy Fuels, 5, 895–907 (1991).

    Article  Google Scholar 

  16. E. Gimzewski and G. Audley, Thermochim. Acta, 214, 149–155 (1993).

    Article  CAS  Google Scholar 

  17. V. Kutcherov, G. Bäckström, M. Anisimov, et al., Int. J. Thermophys., 14(91), 91–100 (1993).

    Article  CAS  Google Scholar 

  18. V. Kutcherov, A. Lundin, R. G. Ross, et al., Int. J. Thermophys., 15(1), 165–176 (1994).

    Article  CAS  Google Scholar 

  19. V. Kutcherov, A. Chernoutsan, and V. Brazhkin, J. Molecular Liquids, 241, 428–434 (2017).

    Article  CAS  Google Scholar 

  20. V. Kutcherov, Int. J. Thermophys, 27(2), 467–473 (2006).

    Article  CAS  Google Scholar 

  21. V. Kutcherov and A. Chernoutsan, Int. J. Thermophys., 27(2), 474–485 (2006).

    Article  CAS  Google Scholar 

  22. P. Skoglund and Å Fransson, Thermochim. Acta, 276, 27–39 (1996).

    Article  CAS  Google Scholar 

  23. C. A. Angell and W. Sichina, Annals of the New York Academy of Sciences, 279(1), 53–67 (1976).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. G. Kutcherov.

Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 3, pp. 62–64 May–June, 2022.

Rights and permissions

Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kutcherov, V.G., Chernoutsan, A.I. Glass Transition of Oil Fractions. Chem Technol Fuels Oils 58, 484–487 (2022). https://doi.org/10.1007/s10553-022-01411-6

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10553-022-01411-6

Keywords

Navigation