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Thermodynamic Analysis of Reactions for the Synthesis of Petrochemical Products from Oxygenates

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Chemistry and Technology of Fuels and Oils Aims and scope

A thermodynamic analysis of the reactions for the conversion of dimethyl ether into valuable products of the gas and oil industry and of propylene, formaldehyde, and 1,3-butadiene in particular was carried out. The temperature dependence of the equilibrium composition in the reaction for the production of 1,3-butadiene from dimethyl ether was determined. Calculation of the temperature dependence of the equilibrium composition in the reaction of propylene with formaldehyde with the formation of 1,3-dioxane, 1,3-butanediol, and 2-buten-1-ol showed that the main product at equilibrium is 2-buten-1-ol.

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References

  1. S. N. Khadzhiev, M. V. Magomedov, E. G. Peresypkina, Neftekhimiya, 54, No. 4, 243-269 (2014).

    Article  Google Scholar 

  2. S. N. Khadzhiev, M. V. Magomedov, E. G. Peresypkina, Neftekhimiya, 55, No. 5., С. 355-374 (2015).

  3. N. V. Kolesnichenko, Z. M. Bukina, L. E. Kitaev, Neftekhimiya, 56, No. 6, 590-597 (2016).

    Article  Google Scholar 

  4. N. A. Markova, Z. M. Bukina, L. E. Kitaev, Neftekhimiya, 56, No. 6, 639-644 (2016).

    Article  Google Scholar 

  5. É. A. Volnina, M. A. Kipnis, S. N. Khadzhiev, Neftekhimiya, 57, No. 3, 243-262 (2017).

    Google Scholar 

  6. A. M. Gyul’maliev, Kh. M. Kadiev, F. G. Zhagfarov, Khimiya i Tekhnologiya Topliv i Masel, No. 1, 26-29 (2020).

  7. H. J. Prins, On the Condensation of Formaldehyde with some Unsaturated Compounds, In: KNAW, Proceedings, 22 I, 1919-1920, Amsterdam (1919), pp. 51-56.

  8. V. F. Tret’yakov, R. M. Talyshinskii, A. M. Ilolov, et al., Neftekhimiya, 54, No. 3, 195-206 (2014).

    Article  Google Scholar 

  9. V. F. Tret’yakov, A. M. Ilolov, R. M. Talyshinskii, Neftekhimiya, 57, No. 4, 423-440 (2017).

    Google Scholar 

  10. S. N. Khadzhiev, A. L. Maksimov, V. F. Tret’yakov, Neftekhimiya, No. 4, 405-414 (2018).

  11. A. M. Gyul’maliev, V. F. Tret’yakov, R. M. Talyshinskii, et al., Neftekhimiya, 59, No. 5, 529-537 (2019).

    Article  Google Scholar 

  12. A/ L/ Maksimov, V. F. Tret’yakov, R. M. Talyshinskii, et al., NefteGazoKhimiya, No. 2, 44-51 (2019).

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    A. M. Gyul’maliev, Kh. M. Kadiev & R. M. Talyshinskii

  2. Gubkin University, Moscow, Russia

    F. G. Zhagfarov & A. G. Kondrat’ev

Authors
  1. A. M. Gyul’maliev
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  2. Kh. M. Kadiev
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  3. R. M. Talyshinskii
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  4. F. G. Zhagfarov
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  5. A. G. Kondrat’ev
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Corresponding author

Correspondence to A. M. Gyul’maliev.

Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 6, pp. 35–40, November – December, 2021.

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Gyul’maliev, A.M., Kadiev, K.M., Talyshinskii, R.M. et al. Thermodynamic Analysis of Reactions for the Synthesis of Petrochemical Products from Oxygenates. Chem Technol Fuels Oils 57, 906–912 (2022). https://doi.org/10.1007/s10553-022-01327-1

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  • DOI: https://doi.org/10.1007/s10553-022-01327-1

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