Skip to main content
SpringerLink
Log in

Thermodynamics of OxygenateSynthesis by the Fischer-Tropsch Method

  • Published:
Chemistry and Technology of Fuels and Oils Aims and scope

A thermodynamics analysis was carried out on the reactions yielding low-molecular-weight oxygenates in the Fischer-Tropsch synthesis. The temperature dependence of the enthalpy, entropy and Gibbs free energy was determined for these reactions. For different values of the H2/CO ratio in the synthesis gas, pressure and temperature, the maximum equilibrium concentrations of the various classes of oxygenates in the reaction products appear in different thermodynamic parameter regions: saturated alcohol are formed at low temperatures, while aromatic alcohols are formed at higher temperatures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.

Similar content being viewed by others

References

  1. A. P. Steynberg and M. E Dry, Elsevier Fischer-Tropsch Technology – Science & Technology (2004).

  2. A. L. Lapidus and A. Yu. Krylova, Rossiiskii Khimicheskii Zhurnal, 44, No. 1, 43 (2000)/

  3. A. L. Lapidus and A. Yu. Krylova, Uspekhi Khimii, 67, 1032-1043 (1998).

    CAS  Google Scholar 

  4. Kh. M. Khadiev, A. M. Gyul’maliev, M. Ya. Shpirt, et al., Khimiya Tverdogo Topliva, No. 1, 14-26 (2011).

  5. A. Ya. Rozovkii, Rossiiskii Khimicheskii Zhurnal, 47, No. 6, 53-61 (2003).

    Google Scholar 

  6. A. M. Gyul’maliev, I. A. Sultanguzin, and A. V. Fedyukhin, Certificate of State Computer Registration No. 2013660842, November 20, 2013.

  7. A. M. Gyul’maliev, G. S. Golovin, and T. G. Gladun, Theoretical Fundamentals of Coal Chemistry [in Russian], Moskovsk. Gos. Univ., Moscow (2003).

    Google Scholar 

  8. N. F. Stepanov, Linear Algebra Methods in Physical Chemistry [in Russia], Moskovsk. Gos. Univ., Moscow (1976).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    A. M. Gyul’maliev & Kh. M. Kadiev

  2. I. M. Gubkin Russian State University of Oil and Gas, Moscow, Russia

    F.G. Zharfarov

Authors
  1. A. M. Gyul’maliev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Kh. M. Kadiev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. F.G. Zharfarov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. M. Gyul’maliev.

Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 1, pp. 26-29, January-February, 2020.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gyul’maliev, A.M., Kadiev, K.M. & Zharfarov, F. Thermodynamics of OxygenateSynthesis by the Fischer-Tropsch Method. Chem Technol Fuels Oils 56, 36–42 (2020). https://doi.org/10.1007/s10553-020-01108-8

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10553-020-01108-8

Key words

Search

Navigation