Dynamic adsorption parameters of CH4, CO, CO2 and N2 gas mixtures on a fixed bed of Ai-Dag (Azerbaijan) natural clinoptilolite were identified. The effects of adsorbate concentration on the effective diffusion coefficient and overall mass-transfer coefficient were determined. Also, the change of clinoptilolite activity with time during CO2 adsorption was studied. A system of equations describing the changes of effective diffusion and mass-transfer coefficients as functions of time was proposed and could be used to design the best industrial adsorbers under unsteady process conditions.
Similar content being viewed by others
References
P. G. Romankov and V. F. Frolov, Mass-transfer Processes in Chemical Engineering [in Russian], Khimiya, Leningrad, 1990, p. 208.
D. Bathen and M. Breitbach, Adsorptionstechnik, Springer, Berlin, 2001, p. 123.
D. D. Do, Adsorption Analysis. Equilibria and Kinetics, Vol. 2, Imperial College Press, London, 2008, p. 337.
F. V. Yusubov, R. I. Zeinalov, and L. T. Neimatova, Uch. Zap., No. 3, 85-91 (1998).
A. C. Melikov and R. A. Bagirov, Gas Drying, Purification and Separation [in Russian], Elm, Baku, 2001,p. 210.
J.-H. Park, J.-N. Kim, S.-H. Cho, et al., Chem. Eng. Sci., 53, No. 23, 3951-3963 (1998).
G. Doetsch, Handbuch der Laplace-Transformation, Springer, Berlin, 1958 [Russian translation, Mir, Moscow, 1958, 326 pp].
A. N. Tikhonov, A. A. Zhukhovitskii, and Ya. Ya. ZaberMw-lcii, Zh. Fiz. Khim., 20, No. 10, 1113 (1946).
M. Dorin, J. Liza, C. Nathalie, et al., Adsorption, 20, 410-510 (2014).
N. Casas, J. Schell, R. Pini, et al., Adsorption, 18, 143-161 (2012).
P. A. Ramachandran, Mass Transfer Process: Modeling, Computations, and Design, 2018, 1072 pp.
D. Basmadiyan, Mass Transfer. Principles and Applications, CRC Press, London, New York, 2005. 13. V. G. Potemkin, Matlab 5-x System of Engineering and Scientific Calculations, Vol. 2, Dialog-MIFI, Moscow, 1998, p. 314.
V. G. Potemkin, Matlab 5-x System of Engineering and Scientific Calculations, Vol. 2, Dialog-MIFI, Moscow, 1998, p. 314.
V. G. Potemkin, Matlab System. Indexed Aide. 0, Dialog-MIFI, Moscow, 1997, p. 350.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 4, pp. 7 – 9, July – August, 2018.
Rights and permissions
About this article
Cite this article
Yusubov, F.V., Ibragimov, C.S. Identification of Dynamic Adsorption Parameters for Separation of Gas Mixtures. Chem Technol Fuels Oils 54, 394–399 (2018). https://doi.org/10.1007/s10553-018-0938-3
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10553-018-0938-3