Skip to main content
SpringerLink
Log in

Kinetic Study of Catalytic Cracking of n-Heptane on a ZSM-5 Based Mesoporous Catalyst with Small Crystal Size

  • Published:
Chemistry and Technology of Fuels and Oils Aims and scope

The aim of the work was to investigate the mechanism of cracking of n-heptane in the presence of a medium-pore finely crystalline catalyst based on zeolite ZSM-5 and the development of a kinetic model of the mechanism of the thermic and catalytic reaction. The catalyst based on zeolite ZSM-5 has high catalytic activity for the catalytic cracking of n-heptane, high stability, and long life time. The kinetic model includes 12 chemical substances and 11 reactions. The values predicted by the model were in good agreement with the experimental data, and the average relative error in the main products was not greater that 10%. The model showed good agreement between the calculated yields of the final product and the experimental data for the catalytic cracking of n-heptane.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

References

  1. J.H. Lee, S. Kang, Y. Kim, et al. Ind. Eng. Chem. Res., 50, 4264-4279 (2011).

  2. S. M. Sadrameli, Fuel, 140, 102-115 (2015).

    Article  CAS  Google Scholar 

  3. Y. Nakasaka, T. Okamura, H. Konno, et al., Micropor. Mesopor. Mater. 182, 244-249 (2013).

    Article  CAS  Google Scholar 

  4. L. X. Wang, K. Ozawa, T. Komatsu, et al. Appl. Catal. A: Gen., 407, 127-133 (2011).

    Article  CAS  Google Scholar 

  5. D. C. Longstaff, Energy Fuels, 26, 801-809 (2012).

    Article  CAS  Google Scholar 

  6. H. Konno, R. Ohnaka, J. Nishimura, et al. Catal. Sci. Technol., 4, 4265-4273 (2014).

    Article  CAS  Google Scholar 

  7. K. H. Li, J. Valla, J. Garcia-Martinez, Chemcatchem, 6, 46-66 (2014).

    Article  CAS  Google Scholar 

  8. F. Chang, J. Zhou, P. Chen, et al., Asia-Pac. J. Chem. Eng., 8, 618-626 (2013).

    Article  CAS  Google Scholar 

  9. O. Muraza, I. A. Bakare, T. Tago, et al., Fuel, 135, 105-111 (2014).

    Article  CAS  Google Scholar 

  10. H. Mochizuki, T. Yokoi, H. Imai, et al., Apply. Catal. A: Gen., 449, 188-197 (2012).

    Article  CAS  Google Scholar 

  11. L. K. Zhang, S. D. Qu, L. Wang, et al., Catal. Today, 216, 64-70 (2013).

    Article  CAS  Google Scholar 

  12. J. Lee, U. G. Hong, S. Hwang, et al., Fuel Process. Technol., 25-30 (2013).

  13. J. Liu, G.Y. Jiang, Y. Liu, et al., Sci. Rep., 4, 1-6 (2014).

    Google Scholar 

  14. X. H. Meng, C. M. Xu, J. S. Gao, et al., Appl. Catal. A: Gen., 301, 32-38 (2006).

    Article  CAS  Google Scholar 

  15. M. S. H. Ruslan, T. Ganeson, M. Hasan, et al., Asia-Pac. J. Chem. Eng., 9, 743-750 (2014).

    Article  CAS  Google Scholar 

  16. X. H. Meng, C. M. Xu, L. Li, et al., Energy Fuels., 24, 6233-6238 (2010).

    Article  CAS  Google Scholar 

  17. L. D. Tian, J. M. Wang, B. X. Shen, et al., Energy Fuels, 24, 4380-4386 (2010).

    Article  CAS  Google Scholar 

  18. A. Corma, J. Mengual, P. J. Miguel, Appl. Catal. A: Gen., 417, 220-235 (2012).

    Article  Google Scholar 

  19. X. Wang, H. Carabineiro, F. Lemos, et al., J. Mol. Catal. A: Chem., 216, 131-137 (2004).

    Article  CAS  Google Scholar 

  20. Q. Zhang, S. Hu, L. L. Zhang, et al., Green Chem., 16, 77-81 (2014).

    Article  CAS  Google Scholar 

  21. S. L. Zhang, Y. J. Gong, L. L. Zhang, et al., Fuel Process. Technol., 129, 130-138 (2015).

    Article  CAS  Google Scholar 

  22. K. Xiong, C. X. Lu, Z. F. Wang, et al., Fuel, 142, 65-72 (2015).

    Article  CAS  Google Scholar 

  23. H. H. Gao, G. Wang, R. Li, et al., Energy Fuels., 26, 1880-1891 (2012).

    Article  CAS  Google Scholar 

  24. M. Sedighi, K. Keyvanloo, J. Towfighi, Fuel, 109, 432-438 (2013).

    Article  CAS  Google Scholar 

  25. X. H. Meng, C. M. Xu, J. S. Gao, et al., Catal. Commun., 8, 1197-1201 (2007).

    Article  CAS  Google Scholar 

  26. N. Rahimia, R. Karimzadeh, Anal J. Appl. Pyrol., 115, 242-254 (2015).

    Article  Google Scholar 

  27. H. Konno, T. Okamura, T. Kawahara, et al., Chem. Eng. J. 207, 490

Download references

The work was conducted with financial support within the National Program of Finance for Fundamental Investigations (No. 2012CB215001, Chinese Peoples’ Republic) and the program of Support for Talented New Generation Scientists of the University of China (No. NCET-12-0970, Chinese Peoples’ Republic).

Author information

Authors and Affiliations

  1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing, China

    Guili Liu, Shaopeng Guo & Zhichang Liu

Authors
  1. Guili Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shaopeng Guo
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Zhichang Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Guili Liu.

Additional information

Translated from Khimiya i Teknologiya Topliv i Masel, No. 1, pp. 45-51, January-February, 2018.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, G., Guo, S. & Liu, Z. Kinetic Study of Catalytic Cracking of n-Heptane on a ZSM-5 Based Mesoporous Catalyst with Small Crystal Size. Chem Technol Fuels Oils 54, 72–85 (2018). https://doi.org/10.1007/s10553-018-0900-4

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10553-018-0900-4

Key words

Search

Navigation