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Kinetics of alkylation of benzene with propylene in the presence of dimethyldichlorosilane

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Chemistry and Technology of Fuels and Oils Aims and scope

Abstract

The kinetics of alkylation of benzene with propylene in the presence of dimethyldichlorosilane at 130, 150, and 170°C and 1.2–1.8 MPa was investigated. Kinetic equations were derived for a three-stage scheme of this process and its kinetic parameters were calculated. The promoting effect of water on the catalyst at a content in the reaction mixture of under 0.4 mole % was established. Transalkylation of benzene with di- and triisopropylbenzenes was investigated.

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Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 6, pp. 39–42, November– December, 2004

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Kolesnikov, I.M. Kinetics of alkylation of benzene with propylene in the presence of dimethyldichlorosilane. Chem Technol Fuels Oils 40, 403–411 (2004). https://doi.org/10.1007/s10553-005-0009-4

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  • DOI: https://doi.org/10.1007/s10553-005-0009-4

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