Abstract
Data from long-term monitoring sites are vital for biogeochemical process understanding, and for model development. Implicitly or explicitly, information provided by both monitoring and modelling must be extrapolated in order to have wider scientific and policy utility. In many cases, large-scale modelling utilises little of the data available from long-term monitoring, instead relying on simplified models and limited, often highly uncertain, data for parameterisation. Here, we propose a new approach whereby outputs from model applications to long-term monitoring sites are upscaled to the wider landscape using a simple statistical method. For the 22 lakes and streams of the UK Acid Waters Monitoring Network (AWMN), standardised concentrations (Z scores) for Acid Neutralising Capacity (ANC), dissolved organic carbon, nitrate and sulphate show high temporal coherence among sites. This coherence permits annual mean solute concentrations at a new site to be predicted by back-transforming Z scores derived from observations or model applications at other sites. The approach requires limited observational data for the new site, such as annual mean estimates from two synoptic surveys. Several illustrative applications of the method suggest that it is effective at predicting long-term ANC change in upland surface waters, and may have wider application. Because it is possible to parameterise and constrain more sophisticated models with data from intensively monitored sites, the extrapolation of model outputs to policy relevant scales using this approach could provide a more robust, and less computationally demanding, alternative to the application of simple generalised models using extrapolated input data.









Similar content being viewed by others
References
Aherne JA, Futter MN, Dillon PJ (2008) The impacts of future climate change and sulphur emission reductions on acidification recovery at Plastic Lake, Ontario. Hydrol Earth Syst Sci 12:383–392
Algesten G, Sobek S, Berstrom A-K, Ågren A, Tranvik L, Jansson M (2003) Role of lakes for organic carbon cycling in the boreal zone. Global Change Biol 10:141–147
Beier C, Moldan F, Wright RF (2003) Terrestrial ecosystem recovery—Modelling the effects of reduced acidic inputs and increased inputs of sea-salts induced by global change. Ambio 32:275–282
Belyazid S, Westling O, Sverdrup H (2006) Modelling changes in forest soil chemistry at 16 Swedish coniferous forest sites following deposition reduction. Environ Pollut 144:596–609
Bishop K, Buffam I, Erlandsson M, Fölster J, Laudon H, Seibert S, Temnerud J (2008) Aqua Incognita: the unknown headwaters. Hydrol Process 22:1239–1242
Blenckner T, Adrian R, Livingstone DM, Jennings E, Weyhenmeyer GA, George DG, Jankowski T, Järvinen M, Nic Aonghusa C, Nöges T, Straile D, Teubner K (2007) Large-scale climatic signatures in lakes across Europe: a meta-analysis. Global Change Biol 13:1314–1326
Chen L, Driscoll CT (2005) Regional assessment of the response of the acid-base status of lake watersheds in the Adirondack region of New York to changes in atmospheric deposition using PnET-BGC. Environ Sci Technol 39:787–794
Cooper DM (2005) Evidence of sulphur and nitrogen deposition signals at the United Kingdom Acid Waters Monitoring Network sites. Environ Pollut 137:41–54
Cooper DM, Helliwell RC, Coull MC (2004) Predicting acid neutralising capacity from landscape classification: application to Galloway, south-west Scotland. Hydrol Process 18:455–471
Cosby BJ, Hornberger GM, Galloway JN, Wright RF (1985) Modeling the effects of acid deposition: assessment of a lumped parameter model of soil and streamwater chemistry. Water Resour Res 21:51–63
Cosby BJ, Ferrier RC, Jenkins A, Wright RF (2001) Modelling the effects of acid deposition: refinements, adjustments and inclusion of nitrogen dynamics in the MAGIC model. Hydrol Earth Syst Sci 5:499–517
Davies JJL, Jenkins A, Monteith DT, Evans CD, Cooper DM (2005) Trends in surface water chemistry of acidified UK Freshwaters, 1988–2002. Environ Pollut 137:27–40
Dillon PJ, Molot LA (2005) Long-term trends in catchment export and lake retention of dissolved organic carbon, dissolved organic nitrogen, total iron, and total phosphorus: The Dorset, Ontario, study, 1978–1998. J Geophys Res Biogeosci 110:G01002
Erlandsson M, Buffam I, Fölster J, Laudon H, Temnerud J, Weyhenmeyer G, Bishop K (2008) Thirty-five years of synchrony in the organic matter concentrations of Swedish rivers explained by variation in flow and sulphate. Global Change Biol 14:1191–1198
Evans CD (2005) Modelling the effects of climate change on an acidic upland stream. Biogeochemistry 74:21–46
Evans CD, Monteith DT (2001) Chemical trends at lakes and streams in the UK Acid Waters Monitoring Network, 1988–2000: evidence for recent recovery at a national scale. Hydrol Earth Syst Sci 5:351–366
Evans CD, Jenkins A, Helliwell RC, Ferrier RC (1998) Predicting regional recovery from acidification; the MAGIC model applied to Scotland, England and Wales. Hydrol Earth Syst Sci 2:543–554
Evans CD, Jenkins A, Wright RF (2000) Surface water acidification in the South Pennines. 1. Current status and spatial variability. Environ Pollut 109:11–20
Evans CD, Monteith DT, Harriman R, Jenkins A (2001) Assessing the suitability of acid neutralising capacity as a measure of long-term trends in acidic waters based on two parallel datasets. Water Air Soil Pollut 130:1541–1546
Evans CD, Reynolds B, Jenkins A, Helliwell RC, Curtis CJ, Goodale CL, Ferrier RC, Emmett BA, Pilkington MG, Caporn SJM, Carroll JA, Norris D, Dav ies J, Coull MC (2006) Evidence that soil carbon pool determines susceptibility of semi-natural ecosystems to elevated nitrogen leaching. Ecosystems 9:453–462
Evans C, Hall J, Rowe E, Aherne J, Helliwell R, Jenkins A, Cosby J, Smart S, Howard D, Norris D, Coull M, Bonjean M, Broughton R, O’Hanlon S, Heywood E, Ullyett J (2007) Critical Loads and Dynamic Modelling, Final Report. Report to the Department of the Environment, Food and Rural Affairs under Contract No CPEA 19. 53 pp (http://critloads.ceh.ac.uk/contract_reports.htm)
Evans CD, Reynolds B, Hinton C, Hughes S, Norris D, Grant S, Williams B (2008) Effects of decreasing acid deposition and climate change on acid extremes in an upland stream. Hydrol Earth Syst Sci 12:337–351
Ferrier RC, Helliwell RC, Cosby BJ, Jenkins A, Wright RF (2001) Recovery from acidification of lochs in Galloway, south-west Scotland, UK: 1979–1998. Hydrol Earth Syst Sci 5:421–431
Fölster J, Goransson E, Johansson K, Wilander A (2005) Synchronous variation in water chemistry for 80 lakes in southern Sweden. Environ Monitor Assess 102:389–403
Forsius M, Alveteg M, Jenkins A, Johansson M, Kleemola S, Lükewille A, Posch M, Sverdrup H, Walse C (1998) MAGIC, SAFE and SMART model applications to integrated monitoring sites: Effects of emission reduction scenarios. Water Air Soil Pollut 105:21–30
Fottová D (1995) Regional evaluation of mass element fluxes—GEOMON network of small catchments. Environ Monitor Assess 34:215–221
Futter MN, Helliwell RC, Hutchins M, Aherne J (2009) Modelling the effects of changing climate and nitrogen deposition on nitrate dynamics in a Scottish mountain catchment. Hydrol Res 40:153–166
Gardner M (2008) Long-term proficiency testing for the UK acid waters monitoring network. Accredit Qual Assur 13:255–260
Gbondo-Tugbawa SS, Driscoll CT, Aber JD, Likens GE (2001) Evaluation of an integrated biogeochemical model (PnET-BGC) at a northern hardwood forest ecosystem. Water Resour Res 37:1057–1070
George DG, Talling JF, Rigg E (2000) Factors influencing the temporal coherence of five lakes in the English Lake District. Freshw Biol 43:449–461
Hall J, Ullyett J, Heywood L, Broughton R Fawehinmi J (2004) UK National Focal Centre report. In: Hettellingh J-P, Posch M, Slootweg J (eds) Critical loads and dynamic modelling results. CCE Progress Report 2004. ICP M&M Coordination Centre for Effects. RIVM Report No 259101014/2004. RIVM, Bilthoven, Netherlands, pp 114–134
Helliwell RC, Ferrier RC, Johnston L, Goodwin J, Doughty R (2001) Land use influences on acidification and recovery of freshwaters in Galloway, south-west Scotland. Hydrol Earth Syst Sci 5:451–458
Helliwell RC, Davies JJL, Jenkins A, Evans CD, Coull MC, Reynolds B, Norris D, Ferrier RC (2007) Spatial and seasonal variations in nitrogen leaching and acidity across four acid-impacted regions of the UK. Water Air Soil Pollut 185:3–19
Hettelingh J-P, Posch M, Slootweg J (2008) Critical load, dynamic modelling and impact assessment in Europe: CCE Status Report 2008. Coordination Centre for Effects, Report No 500090003, ISBN No 978-90-6960-211-0
Jenkins A, Cosby BJ, Ferrier RF, Walker TAB, Miller JD (1990) Modelling stream acidification in afforested catchments: an assessment of the relative effects of acid deposition and afforestation. J Hydrol 120:163–181
Jenkins A, Ferrier RC, Helliwell RC (2001) Modelling nitrogen dynamics at Lochnagar, NE Scotland. Hydrol Earth Syst Sci 5:519–528
Knowlton MF, Jones JR (2007) Temporal coherence of water quality variables in a suite of Missouri reservoirs. Lake Reserv Manag 23:49–58
Larssen T (2005) Model prognoses for future acidification recovery of surface waters in Norwayusing long-term monitoring data. Environ Sci Technol 39:7970–7979
Larssen T, Høgåsen T, Cosby BJ (2007) Impact of time series data on calibration and prediction uncertainty for a deterministic hydrogeochemical model. Ecol Model 207:22–33
Moldan F, Kronnas V, Wilander A, Karltun E, Cosby BJ (2004) Modelling acidification and recovery of Swedish lakes. Water Air Soil Pollut Focus 4:139–160
Monteith DT, Evans CD (Eds) (2000) UK Acid Waters Monitoring Network: 10 year report. Analysis and interpretation of results April 1988–March 1998. ENSIS Publishing, London, ISBN 1 871275 26 1
Monteith DT, Evans CD (2005) The United Kingdom Acid Waters Monitoring Network: a review of the first 15 years and introduction to the special issue. Environ Pollut 137:3–13
Monteith DT, Evans CD, Reynolds B (2000) Evidence for a link between temporal variations in the nitrate content of UK upland freshwaters and the North Atlantic Oscillation. Hydrol Process 14:1745–1749
Monteith DT, Stoddard JL, Evans CD, de Wit H, Forsius M, Høgåsen T, Wilander A, Skjelkvåle BL, Jeffries DS, Vuorenmaa J, Keller B, Kopácek J, Vesely J (2007) Rising freshwater dissolved organic carbon driven by changes in atmospheric deposition. Nature 450:537–540
NEGTAP (2001) Transboundary Air Pollution: acidification, eutrophication and ground-level ozone in the UK. Report of the National Expert Group on Transboundary Air Pollution. Department for Environment, Food and Rural Affairs, London. ISBN 1 870393 61 9 (www.nbu.ac.uk/negtap)
Nisbet E (2007) Cinderella science. Nature 450:789–790
Oulehle F, Hofmeister J, Hruška J (2007) Modeling of the long-term effect of tree species (Norway spruce and European beech) on soil acidification in the Ore Mountains. Ecol Model 204:359–371
Patrick S, Waters D, Juggins S, Jenkins A (1991) The United Kingdom Acid Waters Monitoring Network: site descriptions and methodology report. Report to the Department of the Environment and Department of the Environment (Northern Ireland). ENSIS Ltd, London. ISBN 1 871275 04 0
Posch M, Reinds GJ (2009) A very simple dynamic soil acidification model for scenario analyses and target load calculations. Environ Model Softw 24:329–340
Reinds GJ, van Oijen M, Heuvelink GBM, Kros H (2008) Bayesian calibration of the VSD soil acidification model using European forest monitoring data. Geoderma 146:475–488
Reinds GJ, Posch M, de Vries W (2009) Modelling the long-term soil response to atmospheric deposition at intensively monitored forest plots in Europe. Environ Pollut 157:1258–1269
Sjøeng AMS, Wright RF, Kaste Ø (2009) Modelling seasonal nitrate concentrations in runoff of a heathland catchment in SW Norway using the MAGIC model: I. Calibration and specification of nitrogen processes. Hydrol Res 40:198–216
Skjelkvåle BL, Stoddard J, Jeffries D, Tørseth K, Høgåsen T Bowman J, Mannio J, Monteith DT, Mosello R, Rogora M, Rzychon D, Vesely J, Wieting J, Wilander A, Worsztynowicz A (2005) Regional scale evidence for improvements in surface water chemistry 1990–2001. Environ Pollut 137:165–176
Sliggers J, Kakebeeke W (eds) (2004) Clearing the air: 25 years of the convention on long-range transboundary air pollution. ECE/EB.AIR/84, United Nations, Geneva. ISBN 92-1-116910-0
Stevens PA, Ormerod SJ, Reynolds B (1997) Final report of the acid waters survey for Wales, vol 1. Main Text Centre for Ecology and Hydrology, Bangor
Tipping E (1996) CHUM: a hydrochemical model for upland catchments. J Hydrol 174:305–330
Wamelink GWW, van Dobben HF, Berendse F (2009) Vegetation succession as affected by decreasing nitrogen deposition, soil characteristics and site management: a modelling approach. For Ecol Manag 258:1762–1773
Watmough SA, Eimers MC, Aherne J, Dillon PJ (2004) Climate effects on stream nitrate concentrations at 16 forested catchments in South Central Ontario. Environ Sci Technol 38:2383–2388
Wright RF, Larssen T, Camarero L, Cosby BJ, Ferrier RC, Helliwell R, Forsius M, Jenkins A, Kopacek J, Majer V, Moldan F, Posch M, Rogora M, Schöpp W (2005) Recovery of acidified European surface waters. Environ Sci Technol 39:64A–72A
Acknowledgements
This study was supported by the UK Department of Environment, Food and Rural Affairs, under Contract AQ0801. We are grateful to the many people and organisations who have helped to maintain the UK Acid Waters Monitoring Network through the many challenges of its 20 years of operation. We also thank two anonymous reviewers for their constructive assessments of the manuscript.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Evans, C.D., Cooper, D.M., Monteith, D.T. et al. Linking monitoring and modelling: can long-term datasets be used more effectively as a basis for large-scale prediction?. Biogeochemistry 101, 211–227 (2010). https://doi.org/10.1007/s10533-010-9413-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10533-010-9413-x

