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Modeling natural attenuation of benzene with analytical and numerical models

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Abstract

Natural attenuation of benzene is a much-accepted technology for remediating low risk sites. To date, numerous protocols have been developed for assessing natural attenuation and measuring indicator parameters. Many models have additionally been developed to describe the advection, dispersion, sorption and biodegradation processes involved. It is evident that while there is extensive guidance in natural attenuation protocols for field sampling methodologies, less emphasis is placed on analyzing natural attenuation data for supporting appropriate model development. This paper presents methodologies for data analysis and interpretation that may be undertaken to achieve data reduction for modeling purposes. A case study is presented to illustrate the use of an analytical and a numerical natural attenuation model at the same site for predicting the time required to achieve the remedial goal at the site.

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References

  • InstitutionalAuthorNameAmerican Society for Testing Materials (ASTM) (1995) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM Philadelphia

    Google Scholar 

  • InstitutionalAuthorNameAmerican Society for Testing and Materials (ASTM) (1998) ASTM Guide for Remediation by Natural Attenuation at Petroleum Release Sites ASTM Philadelphia

    Google Scholar 

  • CE Aziz CJ Newell AR Gonzales P Haas TP Clement Y Sun (1999) BIOCHLOR Natural Attenuation Decision Support System User’s Manual. Prepared for the U.S. Air Force Center for Environmental Excellence Brooks AFB San Antonio, TX

    Google Scholar 

  • Buscheck TE & Alcantar CM (1995) Regression techniques and analytical solutions to demonstrate intrinsic bioremediation. In: Proceedings of the 1995 Battelle International Conference on In Situ and On Site Bioreclamation, San Diego, CA. Battelle Press, Columbus, OH

  • TP Clement (1998) RT3D, A Modular Computer Code for Simulating Reactive Multispecies Transport in 3-Dimensional Groundwater Aquifers. PNNL-SA-11720,Pacific Northwest National laboratory Richland WA

    Google Scholar 

  • P. Domenico (1987) ArticleTitleAn analytical model for multidimensional transport of a decaying contaminant species J. Hydrol. 91 49–58

    Google Scholar 

  • Newell CJ, McLeod RK, & Gonzales JR (1996) BIOSCREEN Natural Attenuation Decision Support System User’s Manual, Version 1.3. EPA/600/R-96/087, Robert S. Kerr Environmental Research Center, Ada, OK

  • HS Rifai CJ Newell JR Gonzales S Dendrou L Kennedy JT Wilson (1997) BIOPLUME III Natural Attenuation Decision Support System Version 1.0 User’s Manual. Prepared for the U.S. Air Force Center for Environmental Excellence Brooks AFB San Antonio, TX

    Google Scholar 

  • MP Suarez HS Rifai (1999) ArticleTitleBiodegradation Rates for Fuel Hydrocarbons and Chlorinated Solvents in Groundwater Biorem. J. 3 IssueID4 337–362

    Google Scholar 

  • Wiedemeier TH & Chapelle FH (1998) Technical Guidelines for Evaluating Monitored Natural Attenuation of Petroleum Hydrocarbons and Chlorinated Solvents in Ground Water at Naval and Marine Corps Facilities. Department of the Navy.

  • TH Wiedemeier HS Rifai CJ Newell JT Wilson (1999) Natural Attenuation of Fuels and Chlorinated Solvents in the Subsurface John Wiley & Sons, Inc. New York, NY

    Google Scholar 

  • T Wiedemeier JT Wilson DH Kampbell RN Miller JE Hansen (1995) Technical Protocol for Implementing Intrinsic Remediation with Long-Term Monitoring for Natural Attenuation of Fuel Contamination Dissolved in Groundwater. Air Force Center for Environmental Excellence Technology Transfer Division, Brooks AFB San Antonio, TX

    Google Scholar 

  • TH Wiedemeier MA Swanson DE Moutoux EK Gordon JT Wilson BH Wilson DH Kampbell JE Hansen P Haas FH Chapelle (1996) Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Groundwater. Air Force Center for Environmental Excellence San Antonio TX

    Google Scholar 

  • M Xu Y Eckstein (1995) ArticleTitleUse of weighted least squares method in evaluation of the relationship between dispersivity and field-scale Ground Water 33 IssueID6 905–908 Occurrence Handle1:CAS:528:DyaK2MXptVGjsrg%3D

    CAS  Google Scholar 

  • X Yang CY Jeng V Kremesec B Fisher L Curran (1995) Natural Attenuation as a Remedial Alternative, Technical Guidance. Amoco Internal Report 29 Amoco Chicago, IL

    Google Scholar 

Download references

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Correspondence to H. S. Rifai.

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This paper was originally intended for the Special Issue on Natural Attenuation Volume I published in Biodegradation 15(6), 2004.

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Rifai, H.S., Rittaler, T. Modeling natural attenuation of benzene with analytical and numerical models. Biodegradation 16, 291–304 (2005). https://doi.org/10.1007/s10532-004-1909-4

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  • DOI: https://doi.org/10.1007/s10532-004-1909-4

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