Abstract
A diode laser is used to measure the absorption spectra of 238UF6 and 235UF6 molecules in the composite vibrational band ν 1 + ν 3 at wavelength γ = 7.68 µm. To determine the possibility of measuring the isotopic ratio 235UF6/238UF6 with the required accuracy, the absorption coefficients of isotopic samples of 235UF6 and 238UF6 are measured, and the sources of errors and ways to minimize them are determined.
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V. M. Piksaikin, G. M. Pshakin, and V. A. Roshchenko, “Review of method and instruments for determining undeclared nuclear materials and activities,” Sci. Global Security, 14, 49–72 (2006).
Z. T. Lu and K. D. Wendt, “Laser-based methods for ultrasensitive trace-isotope analyses,” Rev. Sci. Instrum., 74, 1169–1179 (2003).
E. V. Stepanov, “Methods of high-sensitivity gas analysis of biological marker molecules in investigations of exhaled air,” Trudy Instituta Obshch. Fiz., 61, 5–47 (2005).
I. N. Izosimov, “Laser ultrasensitive analysis of low concentrations of elements,” Fiz. Élement. Chast. At. Yadra, 38, No. 2, 360–408 (2007).
A. I. Nadezhdinskii, Sh. Sh. Nabiev, G. Yu. Grigor’ev, et al., “Fast method for measuring the degree of enrichment of uranium hexafluoride and trace quantities of UF6 and HF in the atmosphere using near-and mid-IR diode lasers,” Opt. Atmos. Okeana, 18, No. 9, 797–806 (2005).
A. G. Berezin, S. L. Malyugin, A. I. Nadezhdinskii, et al., “UF6 enrichment measurements using TDLS techniques,” Spectrochimica Acta A, 66, No. 1, 796–802 (2007).
L. S. Rothman, D. Jacquemart, A. Barbe, et al., “The HITAN 2004 molecular spectroscopic database,” J. Quantitataive Spectroscopy and Radiative Transfer, 96, 139–204 (2005).
M. A. El’yashevich, Atomic and Molecular Spectroscopy (Parts 1, 2, 3). Molecular Spectroscopy (Part 2), KomKniga, Moscow (2007).
Sh. Sh. Nabiev and V. D. Klimov, “Infrared spectroscopy of fluoride molecules in the gas phase and in noble gas solution. Octahedral molecules,” Molecular Phys., 81, No. 2, 395–408 (1994).
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Translated from Atomnaya Énergiya, Vol. 104, No. 5, pp. 302–306, May, 2008.
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Grigor’ev, G.Y., Lebedeva, A.S., Malyugin, S.L. et al. Investigation of 235UF6 and 238UF6 spectra in the mid-IR range. At Energy 104, 398–403 (2008). https://doi.org/10.1007/s10512-008-9046-5
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DOI: https://doi.org/10.1007/s10512-008-9046-5