Abstract
Flow modeling and hydrogeochemical inversion calculations were performed on the aquifer systems of the Crato-Juazeiro Graben in the Araripe Sedimentary Basin of the Cariri Valley, Northeast Brazil, in order to assess aquifer interconnections through an aquitard of the Araripe Plateau. Steady state hydraulic head numeric calculations with the finite difference method used Modflow software with hydrologically based boundary conditions and a piezometric surface as initial condition. Hydrogeochemical inversion with PHREEQC was performed for two water samples representing typical initial and final waters along the flow path. Flow simulation shows that approximately 20% of all recharge water from the superior aquifer system passes through the Santana aquitard reaching the middle aquifer system. Quantification of mineral dissolution/precipitation processes, ion exchange and microbiological redox reactions taking place in the aquifer systems also indicates hydraulic interconnection of the superior and middle aquifer systems through the Santana aquitard.
Similar content being viewed by others
References
Assine ML (1992) Stratigraphic analysis of the Araripe Basin, Northeast Brazil (Análise Estratigráfica da Bacia do Araripe, Nordeste do Brasil). Revista Brasileira de Geociências 22:289–300
Beurlen K (1971) Facies and ecological conditions of the Santana formation in Araripe Plateau (Brazil Northeast) (As Condições Ecológicas e Faciológicas da Formação Santana, na Chapada do Araripe (Nordeste do Brasil)). Anais da Academia Brasileira de Ciências, Rio de Janeiro 43:411–415
COGERH (Companhia de Gestão dos Recursos Hídricos do Estado do Ceará) (2003) Well Data Sheet (Cadastro de poços)
Dai Z, Samper J (2004) Inverse problem of multicomponent reactive chemical transport in porous media: formulation and applications. Water Resour Res 40:W07407
DNPM (Departamento Nacional de Produção Mineral) (1996) Araripe Sedimentary Basin hydrogeological avaliation project (Projeto Avaliação Hidrogeológica da Bacia Sedimentar do Araripe). Recife, 101 pp
Green WH, Ampt G (1911) Studies of soil physics, part I – the flow of air and water through soils. J Agric Sci 4:1–24
Jacomine PK, Almeida JC, Medeiros LAR (1973) Levantamento exploratório – reconhecimento de solos do Estado do Ceará. Recife. Technical Report 28 (Boletim Técnico 28), convênio MA/DNPEA – SUDENE/DRN
Lecomte KL, Pasquini AI, Depetris PJ (2005) Mineral weathering in a semiarid mountain river: its assessment through PHREEQC inverse modeling. Aquat Geochem 11:173–194
McDonald MG, Harbaugh AW (1984) A modular three-dimensional finite-difference ground-water flow model. U.S. Geol. Surv. Water Resour. Invest. Rep. 83-875, Washington, 528 pp
Mendonça LAR (2001) Water resources of Araripe Plateau (Recursos Hídricos da Chapada do Araripe). Doctoral dissertation, Universidade Federal do Ceará, Fortaleza, 193 pp
Oliveira AA (1988) Laminated limestone of the Cariri, Ceará (Calcáreos Laminados do Cariri, Ceará). Master Thesis, Universidade Federal do Ceará
Parkhurst DL (1995) A computer program for speciation, reaction-path, advective-transport, and inverse geochemical calculations. U.S. Geol. Surv. Water Resour. Invest. Rep. 95-4227, 143 pp
Parkhurst DL, Appelo CAJ (1999) User’s guide to PHREEQC – a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations. U.S. Geol. Surv. Water Resour. Invest. Rep. 99-4259, Colorado
Ponte FC, Appi CJ (1990) Proposta de revisão da Coluna Estratigráfica da Bacia do Araripe. Proc. XXXVI Congresso Brasileiro de Geologia, Natal, pp 211–226
Santiago MMF, Silva CMSV, Mendes Filho J, Frischkorn H (1997) Characterization of groundwater in the Cariri (Ceará, Brazil) by environmental isotopes and electric conductivity. Radiocarbon 39:49–59
Silva MAM (1983) The Araripe Basin, Northeastern Brazil: regional geology and facies analysis of a lower cretaceous evaporitic depositional complex. PhD Thesis, Columbia University, EUA, 290 pp
Silva MAM (1988) Cretaceous evaporites of Araripe Basin: deposition environments and diagenetic story (Evaporitos do Cretáceo da Bacia do Araripe: ambientes de deposição e história diagenética). Bol Geoc PETROBRÁS 2:53–63
Van der Kemp WJM, Appelo CAJ, Walraevens K (2000) Inverse chemical modeling and radiocarbon dating of palaeogroundwaters: the Tertiary Ledo-Paniselian aquifer in Flanders, Belgium. Water Resour Res 36:1277–1287
Wurl J, Giese S, Fausto O, Chale G (2003) Ground water quality research on Cozumel Island, State of Quintana Roo, Mexico. Proc. second international conference on saltwater intrusion and coastal aquifers – monitoring, modeling, and management, Merida, Mexico, pp 1–4
Acknowledgements
The authors wish to thank COGERH (Companhia de Gestão dos Recursos Hídricos do Estado do Ceará) and FUNCAP (Fundação de Amparo à Pesquisa do Estado do Ceará) for logistic and financial support, CAPES (Coordenação de Aperfeiçoamento de Pessoal de Nível Superior—Ministério da Educação—Brazil) for a fellowship of one of the authors (Machado) during postgraduate studies. We thank Dr. A. Donegan for a critical reading of the manuscript and Aquatic Geochemistry reviewers for suggestions for improving it.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Machado, C.J.F., Santiago, M.M.F., Mendonça, L.A.R. et al. Hydrogeochemical and Flow Modeling of Aquitard Percolation in the Cariri Valley-Northeast Brazil. Aquat Geochem 13, 187–196 (2007). https://doi.org/10.1007/s10498-007-9015-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10498-007-9015-y