The transport of entropy perturbations within the combustor flow-field can be simulated by solving the governing equation, Eq. 6, superimposed on the underlying flow-field LES. This work does not address the issue of entropy generation, only its transport. Therefore, a generic artificial “entropy source term” [47] is applied, which injects highly localised entropy perturbations into the combustor chamber. In order to introduce entropy perturbations with a sufficiently high bandwidth to allow behaviour across a range of frequencies to be studied, a time-impulsive entropy source term, \(\dot {Q}_{\textit {\normalsize {s}}}\), is injected, defined by a sharp Gaussian shape function in time, which approximately mimics a time delta-function. This injection is highly localised spatially, occurring only on the mean flame heat release rate field – see Fig. 3b. This mean flame front location approximately coincides with the location at which entropy could in practice be generated by an appropriate flame. The entropy source term, \(\dot {Q}_{\textit {\normalsize {s}}}\), is then expressed as:
$$ \dot{Q}_{\textit{\normalsize{s}}}(x,y,z,t)= \frac{\overline{\dot{Q}}_{h} (x,y,z)}{{\iiint_{\Omega}} \overline{\dot{Q}}_{h}(x,y,z) \, \text{d}{V}} \cdot G_{\textit{in}}(t), \ \text{where} \ G_{\textit{in}}(t) = \frac{1}{\sqrt{\pi} {\Delta} \tau_{1}} \exp \left[-\left( \frac{t}{\Delta \tau_{1}} \right)^{2} \right], $$
(11)
where Ω denotes the computational domain and V denotes the total domain volume. \(\overline {\dot {Q}}_{h} / ({\iiint _{\Omega }} \overline {\dot {Q}}_{h}\, \text {d}{V})\) thus denotes the normalised mean heat release rate spatial field, which gives the mean flame front for entropy injection. The temporal evolution of \(\dot {Q}_{\textit {\normalsize {s}}}\) is defined by the Gaussian shape function, G
in
(t), where Δτ
1 represents the “dispersion time” and has a small value of 1.414 ms, to give a highly time-impulsive signal (see Fig. 7a). G
in
is also equal to the spatially-integrated entropy source, \({\iiint _{\Omega }} \dot {Q}_{\textit {\normalsize {s}}} \, \text {d}{V}\), which is also denoted \(\dot {Q}_{\Omega }\).
By adding \(\dot {Q}_{\textit {\normalsize {s}}}\) as an artificially imposed entropy source on the right-hand side of the entropy transport equation, Eq. 6, we obtain:
$$ \underbrace{\frac{\partial S }{\partial t} + \textit{\textbf{u}} \cdot \pmb{\nabla} S}_{\textit{\normalsize{A}}_{\textit{\normalsize{s}}}} = \underbrace{ \frac{k}{\rho c_{p}} \frac{\partial^{2} S}{\partial x_{i} \partial x_{i}}}_{\textit{\normalsize{D}}_{\textit{\normalsize{s}}}} + \underbrace{ \frac{1}{\rho c_{p} \overline{T} {V}} \left( \tau '_{\textit{ij}} \frac{ \partial \overline{u}_{i}}{\partial x_{j}} + \overline{\tau}_{\textit{ij}} \frac{ \partial u_{i}^{\prime}}{\partial x_{j}} \right)}_{\textit{\normalsize{P}}_{\textit{\normalsize{s}}}} + \ \dot{Q}_{\textit{\normalsize{s}}}, $$
(12)
where \(S=\breve {s^{\prime }}/{V}\) denotes the volume concentration of the normalised entropy perturbation, \(\breve {s^{\prime }}\). The advection, diffusion and production of entropy concentration are defined as A
s
= A/V, D
s
= D/V and P
s
= P/V, respectively. Equation 12 is the “forced entropy transport equation”. It is decoupled from the Navier-Stokes equations and is implemented in a superimposed manner within the ReactingFOAM LES solver. In solving for it, a first-order implicit Euler scheme for its time derivatives (e.g., ∂
S/∂
t) is used, and a second-order central difference scheme for its spatial discretisation (e.g., ∇S) is applied.
Terms needed to capture the transport of entropy
In order to fully capture the transport of entropy perturbations, the relative importance of each individual term ( A
s
, D
s
, P
s
) in Eq. 12 must be accurately assessed, especially for the thermal diffusion ( D
s
) and viscous production ( P
s
) terms. The effects of the large-scale resolved flow structures and the sub-grid scale unresolved turbulent eddies both need to be evaluated.
Before solving Eq. 12 using LES, the non-dimensional form of the linearised entropy transport equation, Eq. 6, is derived. The coordinate x, time t, flow speed u, temperature T and shear stress tensor τ
ij
are normalised (denoted \(\breve {()}\)) by the characteristic length L, bulk velocity U, bulk temperature T
b
and dynamic viscosity μ as:
$$ \breve{x} = \frac{x}{L}, \ \ \ \breve{t} = \frac{tU}{L}, \ \ \ \breve{u} = \frac{u}{U}, \ \ \ \breve{T} = \frac{T}{T_{b}}, \ \ \ \breve{\tau}_{\textit{ij}} = \frac{\tau_{\textit{ij}}L}{\mu U}, $$
(13)
the non-dimensional entropy transport equation then becomes:
$$ \frac{\partial \breve{s}^{\prime}}{\partial \breve{t}} + \breve{u}_{i} \frac{\partial \breve{s}^{\prime}}{\partial \breve{x}_{i}} = \frac{1}{\textit{Re} \ \textit{Pr}} \frac{{\partial}^{2} \breve{s}^{\prime}}{\partial \breve{x}^{2}_{i}} + \frac{(\gamma -1) M^{2}}{\textit{Re} \ \breve{T}} \left( \breve{\tau}^{\prime}_{\textit{ij}} \frac{\partial \overline{\breve{u}}_{i}}{\partial \breve{x}_{j}} + \overline{\breve{\tau}}_{\textit{ij}} \frac{\partial \breve{u}^{\prime}_{i}}{\partial \breve{x}_{j}} \right), $$
(14)
where Re = ρ
U
L/μ denotes the bulk flow Reynolds number, and M = U/c denotes the bulk flow Mach number, with c the speed of sound. For the low Mach number ( M << 1), large Reynolds number ( Re >> 10,000) flows typical of industrial gas turbine combustors, the diffusion and production terms on the right-hand side of Eq. 14 become negligible compared to the advection term on the left-hand side, leading to a “purely advective” entropy transport equation:
$$ \frac{\partial \breve{s}^{\prime}}{\partial \breve{t}} + \breve{u}_{i} \frac{\partial \breve{s}^{\prime}}{\partial \breve{x}_{i}} = 0. $$
(15)
Equation 15 indicates that any change in the entropy perturbation strength is primarily caused by the “advective dispersion” of the velocity field, with diffusion and production of entropy having only minor effects. This assumption was applied in previous studies (e.g., [19, 48]), and will be confirmed by LES in this work.
In order to validate above assumption, Eq. 12 is numerically solved using LES by considering both resolved and sub-grid scale effects. Firstly, the thermal diffusion term in Eq. 12 is expressed as:
$$ \textit{\normalsize{D}}_{\textit{\normalsize{s}}} = \alpha_{E} \frac{\partial^{2} S}{\partial x_{i} \partial x_{i}}, \ \ \text{where}\ \ \alpha_{\textit{E}} = \frac{\nu}{\textit{Pr}} + \frac{\nu_{\textit{sgs}}}{\textit{Pr}_{\textit{sgs}}}, $$
(16)
where the coefficient k/(ρ
C
p
) in the original diffusion term is replaced by the “effective thermal diffusivity”, α
E
, and Pr = c
p
μ/k denotes the Prandtl number. The subscript “ sgs” denotes the contributions from the sub-grid scale turbulent eddies, e.g., ν
sgs
the turbulent kinematic viscosity and Pr
sgs
the turbulent Prandtl number, both of which are properly defined in OpenFOAM [32].
Secondly, the viscous production term in Eq. 12 is now given as:
$$ \textit{\normalsize{P}}_{\textit{\normalsize{s}}} = \frac{1}{\rho c_{p} \overline{T}{V}} \left[ \left( \tau_{\textit{ij}}^{E}\right)' \frac{ \partial \overline{u}_{i}}{\partial x_{j}} + \overline{\tau_{\textit{ij}}^{E}} \frac{ \partial u_{i}^{\prime}}{\partial x_{j}} \right], \ \ \text{where} \ \ \tau^{E}_{\textit{ij}} = \frac{\mu + \mu_{\textit{sgs}}}{2} \left( \frac{\partial u_{i}}{\partial x_{j}} + \frac{\partial u_{j}}{\partial x_{i}} \right), $$
(17)
where μ and μ
sgs
are the laminar and turbulent dynamic viscosity, respectively.
Three types of entropy transport cases are then simulated in order to capture the contributions of the different terms: (i) full entropy advection, diffusion and production, denoted “ A
s
+ D
s
+ P
s
”, (ii) entropy advection plus diffusion, denoted “ A
s
+ D
s
”, in which only the production term is neglected, and (iii) pure entropy advection, denoted “ A
s
”, in which the diffusion and production terms are both neglected. All three cases apply the same entropy source term \(\dot {Q}_{\textit {\normalsize {s}}}\), and use the same unsteady combustor flow-field (see Fig. 3d).
In order to compare the transport of entropy perturbations, the volumetric flux (denoted ϕ) of entropy concentration at the combustor exit is defined as:
$$ \phi = {\iiint_{\Omega}} \left( \textit{\textbf{u}} \cdot \pmb{\nabla} S \right) \text{d}{V} = {\iint_{\partial{\Omega}}} (\boldsymbol{u} \cdot \textit{\textbf{n}}) S \text{d}\mathit{\mathbb{A}}, $$
(18)
where ∂Ω denotes the surface of the domain Ω, \(\mathbb {A}\) denotes the total area of the surface, and vector n denotes the outflow normal direction of the surface. The time-variations of ϕ as calculated using three types of entropy transport are shown in Fig. 7. The exit entropy profiles predicted by all three entropy transport cases are almost identical. Their amplitudes are much smaller than that of the entropy source (see Fig. 7a). As shown in Fig. 7b, the effective thermal diffusion term, D
s
, slightly smooths the time-distribution of ϕ, while the viscous production term, P
s
, marginally increases the magnitude of ϕ within times t = 25 − 30 ms. Overall, both the diffusion and production terms have negligible effects on the entropy transport, suggesting that subsequent studies in this paper need only account for the advective transport term, A
s
. A further study of the entropy source term shows that even with the size of the applied entropy impulse doubled (corresponding to Δτ being halved), the same conclusions can still be drawn, as shown in Fig. 8.
As a final note on these entropy transport equation terms, the relative influence of the entropy production term, P
s
, will depend on the magnitude of the flame-generated entropy waves, which is not included in this study. It is however expected that the flame-generated entropy is orders of magnitude larger than the turbulence-generated entropy. Since the current study does not focus on the generation of entropy waves, but on their advection through the combustion chamber, production terms are neglected in the remainder of this study (i.e., P
s
= 0).
The diffusion term of Eq. 12 can also be neglected (i.e., D
s
= 0), even within such a highly-turbulent reacting flow-field. This can be done because the sub-grid scale turbulence is negligible when compared to the resolved large-scale turbulent structures of the flow, as the LES is well-resolved. This allows us to apply a simplified purely advective entropy equation to study entropy transport in the reminder of the paper:
$$ \underbrace{\frac{\partial S }{\partial t} + \boldsymbol{u} \cdot \pmb{\nabla} S}_{\textit{\normalsize{A}}_{\textit{\normalsize{s}}}} = \dot{Q}_{\textit{\normalsize{s}}}. $$
(19)
Dispersion of entropy transport within combustor flow-fields
The entropy transport equation, in the form of Eq. 19, is now used to investigate some important features of entropy transport. In order to address the issue of whether entropy advective dispersion is dominated by the mean flow profile, or whether unsteady flow features also play an important role, the effect of the “background” combustor flow-field is investigated. The entropy transport equation is firstly simulated, superimposed on the true time-varying flow-field, combining both time-averaged and unsteady flow features. It is then simulated, superimposed on the “frozen” time-averaged flow-field, in which only the mean flow can play a role. In both cases, the same entropy source term, defined in Eq. 11, is applied.
Entropy perturbation transport in a time-varying flow-field
The transport of entropy perturbations within the time-varying combustor flow-field is simulated, by superimposing Eq. 19 on the time-varying flow-field from the LES. The resulting spatial distributions of entropy concentration, S, at four sequential time instants after the impulsive source injection are shown in Fig. 9. The transport of entropy perturbations is visibly affected by the large-scale unsteady flow features. The central flow separation/recirculation zone has an effect, with entropy transport occurring more quickly towards the side walls, and a small amount of entropy initially pulled upstream and trapped in the central zone.
The time-variation of entropy flux at combustor exit, ϕ, is shown in Fig. 10a. The distribution of ϕ has a much lower peak amplitude and more spread out time-profile compared to the entropy source impulse, due to the advective dispersion arising from the advective transport. A more detailed analysis can be performed by spatially-integrating the entropy transport equation, Eq. 19, over the domain volume V. This gives:
$$ \frac{\partial }{\partial t} \underbrace{\left( {\iiint_{\Omega}} S \text{d}{V} \right)}_{\textit{\normalsize{S}}_{\textit{\small{vol}}}} + \underbrace{ {\iint_{\partial {\Omega}}} (\boldsymbol{u} \cdot \textit{\textbf{n}}) S \text{d} \mathbb{A}}_{{\phi}} = \underbrace{{\iiint_{\Omega}} \dot{Q}_{\textit{\normalsize{s}}} \ \text{d}{V}}_{{\dot{Q}_{\Omega}}}, $$
(20)
where the first term on the left-hand side can be denoted ∂
S
vol
/∂
t, with \(S_{\textit {vol}} = {\iiint _{\Omega }} S \text {d}{V}\) denoting the amount of entropy remaining in the combustor. The second term is the exiting entropy flux, ϕ, defined in Eq. 18. By energy conservation, the sum of ∂
S
vol
/∂
t and ϕ must equal the right-hand side term, \({\iiint _{\Omega }} \dot {Q}_{\textit {\normalsize {s}}} \text {d}{V}\) (denoted \(\dot {Q}_{\Omega }\)), the total amount of entropy injected by the source term. The time-integrals of ∂
S
vol
/∂
t, ϕ and \(\dot {Q}_{\Omega }\) thus satisfy:
$$ S_{\textit{vol}} + {\int}_{t} \phi \text{d}t = {\int}_{t} \dot{Q}_{\Omega} \text{d}t. $$
(21)
The first two terms are plotted in Fig. 10b. The entropy flux, ϕ, starts to exit the combustor chamber at around t = 10 ms, at which point the entropy remaining in the chamber, S
vol
, starts to drop. The exit rate of ϕ is fast for t = 10 – 30 ms, but slows down after t = 30 ms, resulting in a total of 100 ms for all the entropy to leave the domain. The sum of S
vol
and \({\int }_{t} \phi \text {d}t\) always equals the total amount of injected entropy, \({\int }_{t} \dot {Q}_{\Omega }\text {d}t\), obeying the energy conservation law.
In a similar manner as for channel flow advective dispersion (e.g., [19]), the time-variation of ϕ can be approximated by a Gaussian shape function, G
out
:
$$ G_{\textit{out}}(t)=\frac{1}{\sqrt{\pi} {\Delta} \tau_{2}} \exp\left[\frac{-(t-\tau_{2})^{2}}{\Delta {\tau_{2}^{2}}}\right], $$
(22)
where τ
2 and Δτ
2 are the mean delay and dispersion times of G
out
, respectively, and the amplitude is given by \(1/(\sqrt {\pi } {\Delta } \tau _{2})\). Using a non-linear least-squares fitting method [49], τ
2 and Δτ
2 are calculated to be 22.2 ms and 10.44 ms respectively. The increased dispersion time compared to the entropy source results in a wider Gaussian distribution and a lower peak amplitude. The resulting Gaussian shape function, G
out
, generally fits the profile of ϕ well, deviating slightly from the real shape which exhibits a longer tail, as shown in Fig. 10a.
Entropy perturbation transport in the “time-frozen” mean flow-field
The transport of entropy perturbations superimposed on the “time-frozen” mean combustor flow-field (see Fig. 3c) is simulated by fixing the velocity vector, u, in Eq. 19 to its mean value, \(\overline {\textit {\textbf {u}}}\), at each point in space. Four sequential time-snapshots of entropy concentration field after the injection are shown in Fig. 11. The entropy transport is dispersed due to the non-uniform velocity profile. Closer to the combustor side-walls, the flow speeds are higher and the entropy flux reaches the exit plane earlier, while the advection near the centreline is much slower due to the flow recirculation zone. Quite a significant amount of entropy even initially travels back towards the combustor entrance (Fig. 11a–b). As the entropy increasingly exits the domain, the amount of entropy remaining in the combustor decreases (Fig. 11c), with most eventually concentrated in the recirculation zone close to the combustor inlet (Fig. 11d). Although after a sufficiently long time, all of the injected entropy perturbations will leave the combustor, the flow recirculation zone “traps” a small amount of entropy for a long time.
The time-evolution of the exiting entropy flux, ϕ, is shown in Fig. 12a. Compared to the unsteady flow advection case (see Fig. 10a), the shape of ϕ-profile is slightly steeper, with a shorter tail at large times. The time-integrals of ∂
S
vol
/∂
t and ϕ are shown in Fig. 12b. The exiting speed of ϕ is much faster at the beginning (t = 15 – 30 ms) than for the unsteady flow simulation (see Fig. 10b), but then slows down after t = 30 ms, resulting in a much longer total exit time. This delay is due to the “dragging and trapping” effect of the flow recirculation zone, which is the dominant structure in the mean flow-field.
The Gaussian approximation model for ϕ, i.e., G
o
u
t
, now takes values τ
2 and Δτ
2 equal to 20.7 ms and 4.95 ms respectively. This means the time taken for the entropy flux to first reach the combustor exit is almost the same for both time-varying and mean flow-fields, but the mean flow-field has a much weaker dispersion effect overall.
Entropy transport in an equivalent fully-developed pipe flow
Comparison with entropy transport through the mean velocity field of an equivalent pipe geometry is now performed. The motivation for this is to investigate whether an estimate can be obtained for the correct dispersion time, without the need for CFD simulations: the mean turbulent pipe flow profile for a given pipe length and radius are known analytically [47]). As shown in Fig. 13, the original combustor geometry of Fig. 1 is represented as an equivalent straight pipe duct. The pipe diameter, D
p
, matches the height of the combustor chamber straight section, H (0.165 m). The pipe length, L
c
= 0.349 m, is calculated using:
$$ {L_{c} = L_{0} + \frac{L_{1}}{2},} $$
(23)
where L
0 = 0.225 m denotes the distance from the flame to the chamber straight-contraction interface, and L
1 = 0.248 m the distance from this interface to the chamber exit plane (see Fig. 13a). The axial extent of the flame region is assumed much shorter than the total axial length of the combustor, such that a thin flame “sheet” can be assigned to a single axial location ( x = 0.048 m) for calculating L
0. This is the location where the maximum mean heat release rate was measured experimentally [29]. The pipe inlet now corresponds to the thin flame sheet, and the pipe outlet corresponds to the combustor exit plane (see Fig. 13b).
The mean axial flow velocity, \(\overline {u}\), within the pipe is 14.97 m ⋅s
−1, matching the LES-simulated flame-downstream velocity in the test combustor. The axial velocity profile of this pipe flow is time-independent, varying only radially as [47]:
$$ u(r) = u_{\textit{max}} - \frac{2.5u_{\textit{max}}}{20}\ln\left( \frac{R}{R-r}\right), $$
(24)
where r denotes the radial distance from the centreline, R denotes the pipe radius and is equal to D
p
/2 (0.0825 m), and u
max
is the maximum axial velocity, satisfying \(u_{\textit {max}} = 1.2 \overline {u}\). The residence time, τ
RES
, for an entropy perturbation travelling from the flame front (i.e., pipe inlet) to the combustor exit (i.e., pipe outlet) is defined as:
$$ \tau_{\textit{RES}}(r) = \frac{L_{c}}{u(r)}. $$
(25)
An imposed time-impulsive (delta-function) entropy source, \(\dot {Q}_{\textit {ideal}}\), is introduced at the pipe inlet, coinciding with the mean flame front of the real combustor. The time-variation of the responding entropy flux at the pipe outlet, ϕ
ideal
, is equal to the probability density function (PDF) of the analytical pipe residence time τ
RES
, i.e., PDF( τ
RES
) [18]. The predicted maximum amplitude of ϕ
ideal
(180.2 s −1) is ∼1.5 times higher than that predicted using mean combustor flow-field (119.8 s −1), and more than three times higher than that for the time-varying combustor flow-field (57.7 s −1) (see Fig. 14a). Thus the time-varying combustor flow appears to attenuate the peak amplitude of the “flame-to-outlet” entropy relation by a factor of roughly three compared to the equivalent fully-developed pipe flow. The time-evolution of ϕ
ideal
can also be well-estimated by a Gaussian shape function G
ideal
[47] (see Fig. 14b), with its mean delay time calculated to be 19.8 ms. The dispersion time of G
ideal
is equal to 3.10 ms, which is much smaller than those for the mean (4.95 ms) and time-varying (10.44 ms) combustor flow-fields.
The frequency responses of entropy perturbation advecting from flame to exit are obtained via fast Fourier transform (FFT) of the relevant signals (see Fig. 15). For the mean and time-varying combustor flow-fields, the volume-integrated entropy source, \(\dot {Q}_{\Omega }\), and the Gaussian-fitted exiting entropy fluxes, G
out
, are used. The small dispersion time Δτ
1 ensures that \(\dot {Q}_{\Omega }\) is close to the ideal impulse \(\dot {Q}_{\textit {ideal}}\). The fast Fourier transform ratio, \(\text {FFT}({G}_{\textit {out}})/ \text {FFT}(\dot {Q}_{\Omega })\), is then calculated over the frequency domain. For the equivalent fully-developed pipe flow, the delta-function impulsive entropy input, \(\dot {Q}_{\textit {ideal}}\), and the subsequent Gaussian fitted output, G
ideal
, are used, resulting in the fast Fourier transform ratio of \(\text {FFT}({G}_{\textit {ideal}})/ \text {FFT}(\dot {Q}_{\textit {ideal}})\).
Figure 15 shows the frequency response amplitudes for entropy transport within three flow-fields, versus both the reduced frequency, f
∗, and the dimensional frequency, f. The reduced frequency f
∗ is defined as:
$$ f^{*} = \frac{f L_{c}}{\overline{u}}. $$
(26)
For mean bulk velocity \(\overline {u}= 14.97\) m ⋅s
−1 and characteristic length L
c
= 0.349 m, f
∗ ranges between 0 and 8 (see Fig. 15), with the corresponding range of f being [0, 335] Hz (not shown). The frequency response amplitude for the fully-developed pipe flow has the widest bandwidth, with the mean and time-varying combustor flow-fields giving successively reduced bandwidths. The large-scale unsteady flow features (e.g., swirl) in the time-varying combustor flow thus act to reduce the bandwidth of the entropy transport frequency-response, which is a significant effect that cannot be neglected.
Note that although the geometry of the test combustor is representative of industrial geometries, the test flow speed is lower than that for an industrial operating condition [29, 30]. For industrial operating conditions, a Mach number downstream of combustion of M
d
= 0.21 would be typical, corresponding to a mean bulk velocity of \(\overline {u}=\) 179 m ⋅s
−1 (assuming a temperature of T
d
= 1800 K and ratio of specific heats γ = 1.4). The dimensional frequency range would then extend over [0, 4000] Hz for f
∗ in the range [0, 8] (see Fig. 15). As can be seen, despite the presence of advective dispersion, significant entropy strength remains at the combustor exit at low frequencies ( ≤ 500 Hz) for all three flow-fields, and thus the entropy noise is likely to be relevant in cases where a large amount of entropy waves are generated.