Skip to main content
SpringerLink
Log in

Adsorption of commercial glyphosate by MOF-808: a new ZrMOF for water purification

  • Published:
Adsorption Aims and scope Submit manuscript

Abstract

This work reports for the first time the use of MOF-808 for the adsorption of glyphosate from a diluted herbicide formulation (Roundup®). MOF-808 was synthesized in organic solvent (MOF-808(DMF)) or in water (MOF-808(H2O)) to compare the influence of textural characteristics on the adsorption process. In addition, the adsorption performances of these materials were compared to those of the UiO-66 and UiO-66(NH2) series materials, which have the same SBU, allowing us to evaluate the influence of the topicity and functionalization of the ligand on the adsorption capacity of glyphosate. MOF-808 showed the highest adsorption capacity, reaching a qmax equal to 277.01 mg g−1, and good kinetic performance, removing 70.3% of the glyphosate from solution in 10 min and 99.5% after 3 h of contact. MOFs UiO-66 and UiO-66(NH2) had lower qmax values than MOF-808, possibly due to the blockage of their narrow pores by GLY, which prevents them from accessing Zr sites. The results showed an important relationship between the hydrodynamic diameter and the pore size distribution with access to active sites, consequently influencing the adsorption performance of these porous materials.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

Data availability

No datasets were generated or analysed during the current study..

References

  1. Ahmadijokani, F., Molavi, H., Rezakazemi, M., Li, J., Arjmand, M.: Progress in materials science UiO-66 metal – organic frameworks in water treatment: a critical review. Prog. Mater. Sci. 125, 100904 (2022)

    Article  CAS  Google Scholar 

  2. Al-Ghouti, M.A., Da’ana, D.A.: Guidelines for the use and interpretation of adsorption isotherm models: A review. J. Hazard. Mater. 393, 122383 (2020). https://doi.org/10.1016/j.jhazmat.2020.122383

    Article  CAS  PubMed  Google Scholar 

  3. Alves Monteiro da Silva, D., Alves Monteiro da Silva, S., Trigueiro da Silva, S., de Melo Félix, H.R., Ferraro de Andrade Pessoa, G.G., Eraldo Souza Araújo, J.R., Barbosa da Silva, J.H., LessaBulhões, L.E., de Oliveira Santos, J.P.: Riscos para a saúde do trabalhador e boas práticas de segurança do trabalho na aplicação de herbicidas em cana-de-açúcar. Sist. Gestão 17, 80–88 (2022). https://doi.org/10.20985/1980-5160.2022.v17n1.1784

    Article  Google Scholar 

  4. de Amarante Junior, O.P., dos Santos, T.C.R., Brito, N.M., Ribeiro, M.L.: Glifosato: propriedades, toxicidade, usos e legislação. Quim. Nova 25, 589–593 (2002). https://doi.org/10.1590/s0100-40422002000400014

    Article  Google Scholar 

  5. Ardila-Suárez, C., Díaz-Lasprilla, A.M., Díaz-Vaca, L.A., Balbuena, P.B., Baldovino-Medrano, V.G., Ramírez-Caballero, G.E.: Synthesis, characterization, and postsynthetic modification of a micro/mesoporous zirconium-tricarboxylate metal-organic framework: towards the addition of acid active sites. CrystEngComm 21, 3014–3030 (2019). https://doi.org/10.1039/c9ce00218a

    Article  CAS  Google Scholar 

  6. Batten, S.R., Champness, N.R., Chen, X.M., Garcia-Martinez, J., Kitagawa, S., Öhrström, L., O’Keeffe, M., Suh, M.P., Reedijk, J.: Terminology of metal-organic frameworks and coordination polymers (IUPAC recommendations 2013). Pure Appl. Chem. 85, 1715–1724 (2013). https://doi.org/10.1351/PAC-REC-12-11-20

    Article  CAS  Google Scholar 

  7. Bose, S., Senthil Kumar, P., Rangasamy, G., Prasannamedha, G., Kanmani, S.: A review on the applicability of adsorption techniques for remediation of recalcitrant pesticides. Chemosphere 313, 137481 (2023). https://doi.org/10.1016/j.chemosphere.2022.137481

    Article  CAS  PubMed  Google Scholar 

  8. Cavka, J.H., Jakobsen, S., Olsbye, U., Guillou, N., Lamberti, C., Bordiga, S., Lillerud, K.P.: A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability. J. Am. Chem. Soc. 130, 13850–13851 (2008). https://doi.org/10.1021/ja8057953

    Article  CAS  PubMed  Google Scholar 

  9. Chavan, S.M., Shearer, G.C., Svelle, S., Olsbye, U., Bonino, F., Ethiraj, J., Lillerud, K.P., Bordiga, S.: Synthesis and characterization of amine-functionalized mixed-ligand metal-organic frameworks of UiO-66 topology. Inorg. Chem. 53, 9509–9515 (2014). https://doi.org/10.1021/ic500607a

    Article  CAS  PubMed  Google Scholar 

  10. Connolly, A., Leahy, M., Jones, K., Kenny, L., Coggins, M.A.: Glyphosate in Irish adults - a pilot study in 2017. Environ. Res. 165, 235–236 (2018). https://doi.org/10.1016/j.envres.2018.04.025

    Article  CAS  PubMed  Google Scholar 

  11. Coutinho, C.F.B., Mazo, L.H.: Complexos metálicos com o herbicida glifosato: revisão. Quim. Nova 28, 1038–1045 (2005)

    Article  CAS  Google Scholar 

  12. DemirDuman, F., Monaco, A., Foulkes, R., Becer, C.R., Forgan, R.S.: Glycopolymer-functionalized MOF-808 nanoparticles as a Cancer-targeted dual drug delivery system for carboplatin and Floxuridine. ACS Appl. Nano Mater. 5, 13862–13873 (2022). https://doi.org/10.1021/acsanm.2c01632

    Article  CAS  Google Scholar 

  13. Diercks, C.S., Kalmutzki, M.J., Diercks, N.J., Yaghi, O.M.: Conceptual advances from Werner complexes to metal-organic frameworks. ACS Cent. Sci. 4, 1457–1464 (2018). https://doi.org/10.1021/acscentsci.8b00677

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  14. Drout, R.J., Kato, S., Chen, H., Son, F.A., Otake, K.I., Islamoglu, T., Snurr, R.Q., Farha, O.K.: Isothermal titration calorimetry to explore the parameter space of organophosphorus agrochemical adsorption in MOFs. J. Am. Chem. Soc. 142, 12357–12366 (2020). https://doi.org/10.1021/jacs.0c04668

    Article  CAS  PubMed  Google Scholar 

  15. Ejsmont, A., Andreo, J., Lanza, A., Galarda, A., Macreadie, L., Wuttke, S., Canossa, S., Ploetz, E., Goscianska, J.: Applications of reticular diversity in metal–organic frameworks: An ever-evolving state of the art. Coord. Chem. Rev. 430, 213655 (2021). https://doi.org/10.1016/j.ccr.2020.213655

    Article  CAS  Google Scholar 

  16. Fang, F., Lv, Q., Li, P., Tao, Y., Zhang, Y., Zhou, Y., Li, X., Li, J.: Screening of hierarchical porous UiO-67 for efficient removal of glyphosate from aqueous solution. J. Environ. Chem. Eng. 10, 107824 (2022). https://doi.org/10.1016/j.jece.2022.107824

    Article  CAS  Google Scholar 

  17. Feng, D., Xia, Y.: Comparisons of glyphosate adsorption properties of different functional Cr-based metal–organic frameworks. J. Sep. Sci. 41, 732–739 (2018). https://doi.org/10.1002/jssc.201700886

    Article  CAS  PubMed  Google Scholar 

  18. Feng, L., Yuan, S., Zhang, L.L., Tan, K., Li, J.L., Kirchon, A., Liu, L.M., Zhang, P., Han, Y., Chabal, Y.J., Zhou, H.C.: Creating hierarchical pores by controlled linker thermolysis in multivariate metal-organic frameworks. J. Am. Chem. Soc. 140, 2363–2372 (2018). https://doi.org/10.1021/jacs.7b12916

    Article  CAS  PubMed  Google Scholar 

  19. Furukawa, H., Cordova, K.E., O’Keeffe, M., Yaghi, O.M.: The chemistry and applications of metal-organic frameworks. Science (80- ) 341, 1230444 (2013). https://doi.org/10.1126/science.1230444

    Article  CAS  Google Scholar 

  20. Furukawa, H., Gándara, F., Zhang, Y.B., Jiang, J., Queen, W.L., Hudson, M.R., Yaghi, O.M.: Water adsorption in porous metal-organic frameworks and related materials. J. Am. Chem. Soc. 136, 4369–4381 (2014). https://doi.org/10.1021/ja500330a

    Article  CAS  PubMed  Google Scholar 

  21. Galaço, A.R.B.S., Jesus, L.T., Freire, R.O., De Oliveira, M., Serra, O.A.: Experimental and theoretical studies of glyphosate detection in water by an europium luminescent complex and effective adsorption by HKUST-1 and IRMOF-3. J. Agric. Food Chem. 68, 9664–9672 (2020). https://doi.org/10.1021/acs.jafc.0c03574

    Article  CAS  PubMed  Google Scholar 

  22. HormoziJangi, S.R., Akhond, M.: High throughput urease immobilization onto a new metal-organic framework called nanosized electroactive quasi-coral-340 (NEQC-340) for water treatment and safe blood cleaning. Process Biochem. 105, 79–90 (2021). https://doi.org/10.1016/j.procbio.2021.03.027

    Article  CAS  Google Scholar 

  23. Huang, L., Shen, R., Shuai, Q.: Adsorptive removal of pharmaceuticals from water using metal-organic frameworks: A review. J. Environ. Manage. 277, 111389 (2021). https://doi.org/10.1016/j.jenvman.2020.111389

    Article  CAS  PubMed  Google Scholar 

  24. Iwuozor, K.O., Emenike, E.C., Gbadamosi, F.A., Ighalo, J.O., Umenweke, G.C., Iwuchukwu, F.U., Nwakire, C.O., Igwegbe, C.A.: Adsorption of organophosphate pesticides from aqueous solution: a review of recent advances. Springer, Berlin Heidelberg (2022)

    Google Scholar 

  25. Jia, D., Guo, J., Li, J., Duan, Y.: Removal of glyphosate from aqueous solution by CuO coated MIL‐101(Fe). Can. J. Chem. Eng. 101, 1–11 (2022). https://doi.org/10.1002/cjce.24702

  26. Kadhom, M., Deng, B.: Metal-organic frameworks (MOFs) in water filtration membranes for desalination and other applications. Appl. Mater. Today 11, 219–230 (2018). https://doi.org/10.1016/j.apmt.2018.02.008

    Article  Google Scholar 

  27. Kalmutzki, M.J., Hanikel, N., Yaghi, O.M.: Secondary building units as the turning point in the development of the reticular chemistry of MOFs. Sci. Adv. 4, eaat9180 (2018). https://doi.org/10.1126/sciadv.aat9180

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  28. Kandiah, M., Nilsen, M.H., Usseglio, S., Jakobsen, S., Olsbye, U., Tilset, M., Larabi, C., Quadrelli, E.A., Bonino, F., Lillerud, K.P.: Synthesis and stability of tagged UiO-66 Zr-MOFs. Chem. Mater. 22, 6632–6640 (2010). https://doi.org/10.1021/cm102601v

    Article  CAS  Google Scholar 

  29. Kirlikovali, K.O., Hanna, S.L., Son, F.A., Farha, O.K.: Back to the basics: developing advanced metal-organic frameworks using fundamental chemistry concepts. ACS Nanosci. Au (2022). https://doi.org/10.1021/acsnanoscienceau.2c00046

    Article  PubMed  PubMed Central  Google Scholar 

  30. Liu, R., Xie, Y., Cui, K., Xie, J., Zhang, Y., Huang, Y.: Adsorption behavior and adsorption mechanism of glyphosate in water by amino-MIL-101(Fe). J. Phys. Chem. Solids 161, 110403 (2022). https://doi.org/10.1016/j.jpcs.2021.110403

    Article  CAS  Google Scholar 

  31. Liu, X., Kirlikovali, K.O., Chen, Z., Ma, K., Idrees, K.B., Cao, R., Zhang, X., Islamoglu, T., Liu, Y., Farha, O.K.: Small molecules, big effects: tuning adsorption and catalytic properties of metal-organic frameworks. Chem. Mater. 33, 1444–1454 (2021). https://doi.org/10.1021/acs.chemmater.0c04675

    Article  CAS  Google Scholar 

  32. Logan, M.W., Langevin, S., Xia, Z.: Reversible atmospheric water harvesting using metal-organic frameworks. Sci. Rep. 10, 1–11 (2020). https://doi.org/10.1038/s41598-020-58405-9

    Article  CAS  Google Scholar 

  33. Mali, H., Shah, C., Raghunandan, B.H., Prajapati, A.S., Patel, D.H., Trivedi, U., Subramanian, R.B.: Organophosphate pesticides an emerging environmental contaminant: pollution, toxicity, bioremediation progress, and remaining challenges. J. Environ. Sci. 127, 234–250 (2022). https://doi.org/10.1016/j.jes.2022.04.023

    Article  CAS  Google Scholar 

  34. Manogaran, M., Shukor, M.Y., Yasid, N.A., Johari, W.L.W., Ahmad, S.A.: Isolation and characterization of glyphosate-degrading bacteria isolated from local soils in Malaysia. Rend. Lincei 28, 471–479 (2017). https://doi.org/10.1007/s12210-017-0620-4

    Article  Google Scholar 

  35. Molavi, H., Eskandari, A., Shojaei, A., Mousavi, S.A.: Enhancing CO2/N2 adsorption selectivity via post-synthetic modification of NH2-UiO-66(Zr). Microporous Mesoporous Mater. 257, 193–201 (2018). https://doi.org/10.1016/j.micromeso.2017.08.043

    Article  CAS  Google Scholar 

  36. Naghdi, S., Brown, E., Zendehbad, M., Duong, A., Ipsmiller, W., Biswas, S., Toroker, M.C., Kazemian, H., Eder, D.: Glyphosate adsorption from water using hierarchically porous metal-organic frameworks. Adv. Funct. Mater. 33, 2213862 (2023). https://doi.org/10.1002/adfm.202213862

    Article  CAS  Google Scholar 

  37. Nargis, F., Duong, A., Rehl, E., Bradshaw, C., Kazemian, H.: Highly efficient and low-cost clay-based adsorbent for glyphosate removal from contaminated water. Chem. Eng. Technol. 45, 340–347 (2022). https://doi.org/10.1002/ceat.202100437

    Article  CAS  Google Scholar 

  38. Pankajakshan, A., Sinha, M., Ojha, A.A., Mandal, S.: Water-stable nanoscale zirconium-based metal-organic frameworks for the effective removal of glyphosate from aqueous media. ACS Omega 3, 7832–7839 (2018). https://doi.org/10.1021/acsomega.8b00921

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  39. Pereira, H.A., Hernandes, P.R.T., Netto, M.S., Reske, G.D., Vieceli, V., Oliveira, L.F.S., Dotto, G.L.: Adsorbents for glyphosate removal in contaminated waters: a review. Environ. Chem. Lett. 19, 1525–1543 (2021). https://doi.org/10.1007/s10311-020-01108-4

    Article  CAS  Google Scholar 

  40. Reinsch, H., Waitschat, S., Chavan, S.M., Lillerud, K.P., Stock, N.: A Facile, “Green” route for scalable batch production and continuous synthesis of zirconium MOFs. Eur. J. Inorg. Chem. 2016, 4490–4498 (2016). https://doi.org/10.1002/ejic.201600295

    Article  CAS  Google Scholar 

  41. Rivas-Garcia, T., Espinosa-Calderón, A., Hernández-Vázquez, B., Schwentesius-Rindermann, R.: Overview of environmental and health effects related to glyphosate usage. Sustainability 14, 6868 (2022). https://doi.org/10.3390/su14116868

    Article  CAS  Google Scholar 

  42. Tao, Y., Fang, F., Lv, Q., Qin, W., He, X., Zhang, Y., Zhou, Y., Li, X., Li, J.: Highly efficient removal of glyphosate from water by hierarchical-pore UiO-66: Selectivity and effects of natural water particles. J. Environ. Manage. 316, 115301 (2022). https://doi.org/10.1016/j.jenvman.2022.115301

    Article  CAS  PubMed  Google Scholar 

  43. Tran, H.N., You, S.J., Hosseini-Bandegharaei, A., Chao, H.P.: Mistakes and inconsistencies regarding adsorption of contaminants from aqueous solutions: a critical review. Water Res. 120, 88–116 (2017). https://doi.org/10.1016/j.watres.2017.04.014

    Article  CAS  PubMed  Google Scholar 

  44. Tranchemontagne, D.J., Hunt, J.R., Yaghi, O.M.: Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0. Tetrahedron 64, 8553–8557 (2008). https://doi.org/10.1016/j.tet.2008.06.036

    Article  CAS  Google Scholar 

  45. Valenzano, L., Civalleri, B., Chavan, S., Bordiga, S., Nilsen, M.H., Jakobsen, S., Lillerud, K.P., Lamberti, C.: Disclosing the complex structure of UiO-66 metal organic framework: a synergic combination of experiment and theory. Chem. Mater. 23, 1700–1718 (2011). https://doi.org/10.1021/cm1022882

    Article  CAS  Google Scholar 

  46. Van Bruggen, A.H.C., He, M.M., Shin, K., Mai, V., Jeong, K.C., Finckh, M.R., Morris, J.G.: Environmental and health effects of the herbicide glyphosate. Sci. Total. Environ. 616–617, 255–268 (2018). https://doi.org/10.1016/j.scitotenv.2017.10.309

    Article  CAS  PubMed  Google Scholar 

  47. Wang, J., Guo, X.: Adsorption kinetic models: physical meanings, applications, and solving methods. J. Hazard. Mater. 390, 122156 (2020). https://doi.org/10.1016/j.jhazmat.2020.122156

    Article  CAS  PubMed  Google Scholar 

  48. Wang, Q., Cui, K.P., Liu, T., Li, C.X., Liu, J., Kong, D.C., Weerasooriya, R., Chen, X.: In situ growth of NH2-MIL-101 metal organic frameworks on biochar for glyphosate adsorption. Chemosphere. 331, 138827 (2023). https://doi.org/10.1016/j.chemosphere.2023.138827

  49. Wen, Y., Feng, M., Zhang, P., Zhou, H.-C., Sharma, V.K., Ma, X.: Metal Organic Frameworks (MOFs) as photocatalysts for the degradation of agricultural pollutants in water. ACS ES&T Eng. 1, 804–826 (2021). https://doi.org/10.1021/acsestengg.1c00051

    Article  CAS  Google Scholar 

  50. Baldi, I., Blair, A., Calaf, G.M., Egeghy, P.P., Forastiere, F., Fritschi, L., Jahnke, G.D., Jameson, C.W., Kromhout, H., Curieux, F. Le., Martin, M.T., McLaughlin, J., Rodriguez, T., Ross, M.K., Rusyn, I.I., Sergi, C.M., Mannetje, A., Zeise, L.: Glyphosate. In: Some organophosphate insecticides and herbicides/ IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, pp 321–399. Iarc Monographs. V.112, Switzerland (2015)

  51. Williams, G.M., Aardema, M., Acquavella, J., Berry, S.C., Brusick, D., Burns, M.M., de Camargo, J.L.V., Garabrant, D., Greim, H.A., Kier, L.D., Kirkland, D.J., Marsh, G., Solomon, K.R., Sorahan, T., Roberts, A., Weed, D.L.: A review of the carcinogenic potential of glyphosate by four independent expert panels and comparison to the IARC assessment. Crit. Rev. Toxicol. 46, 3–20 (2016). https://doi.org/10.1080/10408444.2016.1214677

    Article  CAS  PubMed  Google Scholar 

  52. Xu, J., Liu, J., Li, Z., Wang, X., Xu, Y., Chen, S., Wang, Z.: Optimized synthesis of Zr(iv) metal organic frameworks (MOFs-808) for efficient hydrogen storage. New J. Chem. 43, 4092–4099 (2019). https://doi.org/10.1039/C8NJ06362A

    Article  CAS  Google Scholar 

  53. Yaghi, O.M., Kalmutzki M.J., Diercks, C.S.: Introduction to Reticular Chemistry. Wiley – VCH, Weinheim (2019)

  54. Yang, Q., Wang, J., Zhang, W., Liu, F., Yue, X., Liu, Y., Yang, M., Li, Z., Wang, J.: Interface engineering of metal organic framework on graphene oxide with enhanced adsorption capacity for organophosphorus pesticide. Chem. Eng. J. 313, 19–26 (2017). https://doi.org/10.1016/j.cej.2016.12.041

  55. Yang, Q., Wang, J., Chen, X., Yang, W., Pei, H., Hu, N., Li, Z., Suo, Y., Li, T., Wang, J.: The simultaneous detection and removal of organophosphorus pesticides by a novel Zr-MOF based smart adsorbent. J. Mater. Chem. A. 6, 2184–2192 (2018). https://doi.org/10.1039/c7ta08399h

  56. Yang, X., Li, Z., Tang, S.: Tailored design of hierarchically porous UiO-66 with a controlled pore structure and metal sites. Cryst. Growth Des. 21, 6092–6100 (2021). https://doi.org/10.1021/acs.cgd.1c00411

    Article  CAS  Google Scholar 

  57. Zhu, X., Li, B., Yang, J., Li, Y., Zhao, W., Shi, J., Gu, J.: Effective adsorption and enhanced removal of organophosphorus pesticides from aqueous solution by Zr-Based MOFs of UiO-67. ACS Appl. Mater. Interfaces 7, 223–231 (2015). https://doi.org/10.1021/am5059074

    Article  CAS  PubMed  Google Scholar 

Download references

Acknowledgements

The laboratories responsible for the analysis of this work included the Laboratory of Ultra Structure Cellular Carlos Alberto Redins—UFES, the Laboratory of Carbonous Materials—UFES, the Laboratory of Supramolecular Chemistry and Nanotechnology—UFF and the Laboratory of Rare Earths—BSTR/UFPE.

Funding

This research was carried out without funding. The resources used are part of the research budget allocated to professors (authors) and their respective research projects in the Postgraduate Department of Chemistry at the Federal University of Espírito Santo, Brazil.

Author information

Authors and Affiliations

  1. Postgraduate Program in Chemistry, Inorganic Chemistry Laboratory, Federal University of Espírito Santo, Espírito Santo, 29075-910, Brazil

    Caroline B. C. Almeida & Priscilla P. Luz

  2. Laboratory of Nanotechnology and Supramolecular Chemistry, Department of Inorganic Chemistry, Federal Fluminense University, Rio de Janeiro, 24220-900, Brazil

    Célia M. Ronconi, Danilo R. H. de Miranda & Isabela A. A. Bessa

  3. Postgraduate Program in Chemistry, Analytical Chemistry Laboratory, Federal University of Espírito Santo, Espírito Santo, 29075-910, Brazil

    Honério C. de Jesus

Authors
  1. Caroline B. C. Almeida
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Célia M. Ronconi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Danilo R. H. de Miranda
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Isabela A. A. Bessa
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Honério C. de Jesus
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Priscilla P. Luz
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

CB and PP are responsible for defining the methodologies and carrying out all the research.

CM, IB and DR performed the N2 adsorption, DLS and potentiometric titration analyses.

HC supervised and promoted the quantification of phosphorus via ICP-OES.

All authors reviewed the article.

Corresponding author

Correspondence to Priscilla P. Luz.

Ethics declarations

Ethical statement

The authors declare that ethical approval does not apply to this work because humans and/or animals did not participate in the research.

Competing interests

The authors declare no competing interests.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Almeida, C.B.C., Ronconi, C.M., de Miranda, D.R.H. et al. Adsorption of commercial glyphosate by MOF-808: a new ZrMOF for water purification. Adsorption (2024). https://doi.org/10.1007/s10450-024-00451-0

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10450-024-00451-0

Keywords

Search

Navigation