Abstract
Gas drying by adsorption on molecular sieves is one of the first unit operations in natural gas processing. Nevertheless, the thermal swings during regeneration combined with the presence of a complex gas mixture may lead to early adsorbent fouling. The shaping of adsorbent materials is crucial not only to reduce pressure drop in columns, but also for enhanced thermal and mechanical properties. In this work, synthesized sodium-based zeolite Linde Type A (Na-LTA) in powder was shaped by extrusion into cylindrical pellets using a clay binder followed by calcination at 673 K for 24 h. The produced 2-mm pellets had binder contents of 15 and 20% (w/w). Thereafter, the shaped pellets were subjected to an accelerated aging procedure, which exposes the samples to conditions analogous to those of Temperature Swing Adsorption drying processes with a higher severity. High-resolution water vapor isotherms at 313 K were measured before and after the simulated aging process. Results show that the sample with 20% of binder had an average decrease in water uptake (mol kg−1) of 1.2% after aging, whereas the aged zeolite in powder presented a decrease of 8.1, evidencing a protective effect of the clay binder against thermal fouling.
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Acknowledgements
The authors acknowledged the financial support from PETROBRAS and the Agência Nacional de Petróleo, Gás Natural e Biocombustíveis—ANP, Brazil, through the Clause of Investments in Research, Development and Innovation in contracts for Exploration, Development and Production of Petroleum and Natural Gas. They also thank the CNPq (Conselho Nacional de Desenvolvimento Científico e Tecnológico) process 402561/2007-4, Notice MCY/CNPq nº10/2007, the LEVM (Laboratório de Microscopia Vibracional) for XRD analysis, the Rezaei’s Group from Missouri S&T for the FTIR analysis and the Servicios Centrales de Apoyo a la Investigación from Universidad de Málaga for the XRF analysis. JDLM acknowledges the grant received from the CAPES-PrInt program (Process 88887.311867/2018-00) to fund international collaboration with Rezaei’s group.
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This work has been financially supported by: PETROBRAS and the Agência Nacional de Petróleo, Gás Natural e Biocombustíveis—ANP, Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES), Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq).
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DCM, MBN and DCSA contributed to conception and design of the study. JDLM, DSP, TMA performed all experiments under supervision of DASM, FR, MBN and DCSA. JDLM wrote the first draft of the manuscript. DASM, MBN and DCSA revised, edited and provided a formal analysis of the manuscript. DCSA, FR and MBN acquired and provided funds for the development of this work. All authors approved the submitted version.
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Moreno, J.D.L., da S. Pereira, D., Azevedo, T.M. et al. Hydrothermal stability of Na-LTA shaped with clay binder. Adsorption (2023). https://doi.org/10.1007/s10450-023-00428-5
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DOI: https://doi.org/10.1007/s10450-023-00428-5