Abstract
Sorption-based compressors are thermally driven and because of the absence of moving parts they are vibration free, and have the potential for long life. Sorption-based compressors have been reported to operate Joule–Thomson (JT) cryogenic coolers with pure working fluids. However, using mixed refrigerants instead of pure refrigerants is attractive since that would dramatically improve the system coefficient of performance. Our on-going research aims to develop an efficient JT sorption cryocooler, operating with mixed refrigerants, and is focused on studying the characteristics of the sorption compressor cycle. This paper presents the results of an advanced numerical analysis, which is based on a previous model, and its experimental verification. The analysis relates to the ideal cycle of a sorption compressor operating with a gas mixture. Obviously, dynamics and kinetics play a major rule in a real sorption compressor cycle. However, since there are no reported gas-mixture sorption compressors and the existing experience in this field is poor, a preliminary ideal cycle analysis is considered. Satisfying agreement between the numerical and experimental results is obtained and the processes in the sorption cycle are discussed. The outcomes of the current study are the basis for the next phase in which a sorption compressor prototype will be built operating with gas mixtures.
Similar content being viewed by others
Abbreviations
- a:
-
Sips adsorption affinity parameter, 1 MPa−1
- C:
-
Adsorption concentration, gadsorbate kgadsorbent−1
- C0 :
-
Sips saturated adsorption concentration, gadsorbate kgadsorbent−1
- Dev:
-
Deviation, %
- n:
-
Sips heterogeneity parameter
- N:
-
Number of components in the mixture
- p:
-
Pressure, MPa
- T:
-
Temperature, K
- y:
-
Molar fraction in vapor phase
- calc:
-
Calculated
- exp:
-
Experimental
- θ:
-
Property
References
Chorowski, M., Piotrowska, A.: Performance analysis of Joule-Thomson cryocooler supplied with gas mixture. Cryocoolers 17, 397–406 (2012)
Lee, J., Lee, K., Jeong, S.: Experimental study of a mixed refrigerant Joule-Thomson cryocooler using a commercial air-conditioning scroll compressor. Cryogenics 55–56, 47–52 (2013)
Lewis, R., Wang, Y., Bradley, P.E., Huber, M.L., Radebaugh, R., Lee, Y.C.: Experimental investigation of low-pressure refrigerant mixtures for micro cryogenic coolers. Cryogenics 54, 37–43 (2013)
Narasimhan, N.L., Venkatarathnam, G.: A method for estimating the composition of the mixture to be charged to get the desired composition in the circulating in a single stage JT refrigerator operating with mixtures. Cryogenics 50, 93–101 (2010)
Passow, K.L., Skye, H.M., Nellis, G.F., Klein, S.A.: Experimental verification of a precooled mixed gas Joule-Thomson cryoprobe model. Adv. Cryog. Eng. 57, 1198–1205 (2012)
Prakash, M.J., Prasad, M., Rastogi, S.C., Akkimaradi, B.S., Gupta, P.P., Narayanamurthy, H., Srinivasan, K.: Development of a laboratory model of activated charcoal-nitrogen adsorption cryocooler. Cryogenics 40, 481–488 (2000)
Rao, R.R., Prasad, M., Srinivasan, K.: Optimum operating conditions for an adsorption cryocooler: a case of activated carbon + nitrogen system. Cryogenics. 45, 193–197 (2005)
Tzabar, N.: Mixed-refrigerant Joule-Thomson (MR JT) mini-cryocoolers. Adv. Cryog. Eng. 59, 148–154 (2014a)
Tzabar, N.: Binary mixed-refrigerants for steady cooling temperatures between 80 K and 150 K with Joule-Thomson cryocoolers. Cryogenics 64, 70–76 (2014b)
Tzabar, N., Grossman, G.: Nitrogen, methane, and ethane sorption on activated carbon. Cryogenics 51, 499–508 (2011)
Tzabar, N., Grossman, G.: Analysis of an activated-carbon sorption compressor operating with gas mixtures. Cryogenics 52, 491–499 (2012)
Tzabar, N., Lapp, Z.: Experimental investigation on mixed-refrigerant for closed-cycle Joule-Thomson cryocoolers. Adv. Cryog. Eng. 55, 1121–1128 (2010)
Tzabar, N., ter Brake, H.J.M.: Adsorption isotherms and Sips models of nitrogen, methane, ethane, and propane on commercial activated carbons and polyvinylidene chloride. Adsorption 22, 901–914 (2016)
Tzabar, N., Holland, H.J., Vermeer, C.H., ter Brake, H.J.M.: Modeling the adsorption of mixed gases based on pure gas adsorption properties. Mat. Sci. Eng. (2015). https://doi.org/10.1088/1757-899X/101/1/012169
Wu, Y., Zalewski, D.R., ter Brake, H.J.M.: Optimization of the working fluid for a sorption-based Joule-Thomson cooler. Adv. Cryog. Eng. 57, 1789–1796 (2012)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Tzabar, N., ter Brake, H.J.M. Analysis of ideal sorption compressor cycles operating with gas mixtures. Adsorption 24, 325–332 (2018). https://doi.org/10.1007/s10450-018-9937-2
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10450-018-9937-2