Skip to main content

Bifunctional activated carbon with dual photocatalysis and adsorption capabilities for efficient phenol removal

Abstract

Bifunctional activated carbons (AC) with the abilities of both photocatalysis and adsorption were fabricated via the sol–gel route combined with hydrothermal treatment and N2 reactivation method. TiO2 was located mainly at the entrance of the surface macropores of AC. Under UV light irradiation, efficient removal of phenol was realized by combination of adsorption and photocatalytic degradation for the obtained bifunctional materials. In insufficient light or dark, phenol removal occurred mainly through adsorption. The prepared bifunctional carbon with a mass ratio of 50 TiO2 per AC ratio exhibited high efficiency for phenol removal. The total phenol removal capacity of 50TiO2/AC was almost 5 times of that of pure AC and 6 times of that pure TiO2 after 10 cycles. The prepared bifunctional carbons possess the advantages of high pollutant removal capability and good recyclability, making them promising for the efficient treatment of lightly polluted aqueous solutions.

This is a preview of subscription content, access via your institution.

References

  • An, X.N., Zeng, H.M.: Functionalization of carbon nanobeads and their use as metal ion adsorbents. Carbon 41, 2889–2896 (2003)

    Article  CAS  Google Scholar 

  • Ao, C.H., Lee, S.C.: Enhancement effect of TiO2 immobilized on activated carbon filter for the photodegradation of pollutants at typical indoor air level. Appl. Catal. B, Environ. 44, 191–205 (2003)

    Article  CAS  Google Scholar 

  • Araña, J., Doña-Rodríguez, J.M., Tello Rendón, E., Garriga Cabo, C., González-Díaz, O., Herrera-Melián, J.A., Pérez-Peña, J., Colón, G., NaVío, J.A.: TiO2 activation by using activated carbon as a support Part I. Surface characterisation and decantability study. Appl. Catal. B, Environ. 44, 161–172 (2003a)

    Article  Google Scholar 

  • Araña, J., Doña-Rodríguez, J.M., Tello Rendón, E., Garriga Cabo, C., González-Díaz, O., Herrera-Melián, J.A., Pérez-Peña, J., Colón, G., NaVío, J.A.: TiO2 activation by using activated carbon as a support Part II. Photoreactivity and FTIR study. Appl. Catal. B, Environ. 44, 153–160 (2003b)

    Article  Google Scholar 

  • Cao, X.Y., Shiraishi, F.: A mechanism of photocatalytic and adsorptive treatment of 2, 4-dinitrophenol on a porous thin film of TiO2 covering granular activated carbon particles. Chem. Eng. J. 160, 651–659 (2010)

    Article  CAS  Google Scholar 

  • Chen, X.Y., Liu, S.X., Chen, X.: Characterization and activity of TiO2/wAC composite photocatalyst prepared by acid catalyzed hydrolysis method. Acta Phys. Chim. Sin. 22, 517–524 (2006)

    CAS  Google Scholar 

  • Choi, Y., Choi, W., Lee, C.H., Hyeon, T., Lee, H.I.: Visible light-induced degradation of carbon tetrachloride on dye-Sensitized TiO2. Environ. Sci. Technol. 35, 966–970 (2001)

    Article  Google Scholar 

  • Colon, G., Hidalgo, M.C., Macias, M.: Enhancement of TiO2/C photocatalytic activity by sulfate promotion. Appl. Catal. A, Gen. 259, 235–243 (2004)

    Article  CAS  Google Scholar 

  • Cordero, T., Chovelon, J.M., Duchamp, C., Ferronato, C., Matos, J.: Surface nano-aggregation and photocatalytic activity of TiO2 on H-type activated carbons. Appl. Catal. B, Environ. 73, 227–235 (2007)

    Article  CAS  Google Scholar 

  • Haick, H., Paz, Y.: Long-range effects of noble metals on the photocatalytic properties of titanium dioxide. J. Phys. Chem. B 107, 2319–2326 (2003)

    Article  CAS  Google Scholar 

  • Ingaki, M., Hirose, Y., Matsunaga, T., Tsumura, T., Toyoda, M.: Carbon coating of anatase-type TiO2 through their precipitation in PVA aqueous solution. Carbon 41, 2619–2624 (2003)

    Article  Google Scholar 

  • Jung, Y.J., Kim, S., Park, S.J., Kim, J.M.: Preparation of functionalized nanoporous carbons for uranium loading. Colloids Surf. A, Physicochem. Eng. Asp. 313–314, 292–295 (2008)

    Article  Google Scholar 

  • Lee, D.K., Kim, S.C., Cho, I.C., Kim, S.J., Kim, S.W.: Photocatalytic oxidation of microcystin-LR in a fluidized bed reactor having TiO2-coated activated carbon. Sep. Purif. Technol. 34, 59–68 (2004)

    Article  CAS  Google Scholar 

  • Lettmann, C., Hildenbrand, K., Kisch, H., Macyk, W., Maier, W.F.: Visible light photodegradation of 4-chlorophenol with a coke-containing titanium dioxide photocatalyst. Appl. Catal. B, Environ. 32, 215–221 (2011)

    Article  Google Scholar 

  • Li, J.N., Qi, T., Wang, L.N., Liu, C.H., Zhang, Y.: Synthesis and characterization of imidazole-functionalized SBA-15 as an adsorbent of hexavalent chromium. Mater. Lett. 61, 3197–3200 (2007)

    Article  CAS  Google Scholar 

  • Liu, S.X., Sun, C.L.: Preparation and performance of photocatalytic regenerationable activated carbon prepared via sol-gel TiO2. J. Environ. Sci. 18, 557–561 (2006)

    CAS  Google Scholar 

  • Liu, S.X., Sun, C.L., Zhang, S.R.: Photocatalytic regeneration of coal-based activated carbon. Chin. J. Catal. 24, 355–358 (2003)

    CAS  Google Scholar 

  • Liu, S.X., Sun, C.L., Zhang, S.R.: Photocatalytic regeneration of exhausted activated carbon saturated with phenol. Bull. Environ. Contam. Toxicol. 73, 1017–1024 (2004)

    Article  CAS  Google Scholar 

  • Liu, S.X., Chen, X.Y., Chen, X.: A TiO2/AC composite photocatalyst with high activity and easy separation prepared by a hydrothermal method. J. Hazard. Mater. 143, 257–263 (2007)

    Article  CAS  Google Scholar 

  • Matos, J., Laine, J., Herrman, J.M.: Synergy effect in the photocatalytic degradation of phenol on a suspended mixture of titania and activated carbon. Appl. Catal. B, Environ. 18, 281–285 (1998)

    Article  CAS  Google Scholar 

  • Matos, J., Laine, J., Herrman, J.M.: Association of activated carbons of different origins with titania in the photocatalytic purification of water. Carbon 37, 1870–1877 (1999)

    Article  CAS  Google Scholar 

  • Przepiórski, J., Yoshizawa, N., Yamada, Y.: Activated carbons containing TiO2: Characterization and influence of a preparation method on the state of TiO2 supported. J. Mater. Sci. 36, 4249–4257 (2001)

    Article  Google Scholar 

  • Ravichandran, L., Selvam, K., Swaminathan, M.: Highly efficient activated carbon loaded TiO2 for photo defluoridation of pentafluorobenzoic acid. J. Mol. Catal. A, Chem. 317, 89–96 (2010)

    Article  CAS  Google Scholar 

  • Schmidt, G.T., Vlasova, N., Zuzaan, D., Kersten, M., Daus, B.: Adsorption mechanism of arsenate by zirconyl-functionalized activated carbon. J. Colloid Interface Sci. 317, 228–234 (2008)

    Article  CAS  Google Scholar 

  • Shin, Y.S., Fryxell, G.E., Um, W.Y., Parker, K., Mattigod, S.V., Skaggs, R.: Sulfur-functionalized mesoporous carbon. Adv. Funct. Mater. 17, 2897–2901 (2007)

    Article  CAS  Google Scholar 

  • Torimoto, T., Okawal, Y.: Effect of activated carbon content in TiO2-loaded activated carbon on photodegradetion behaviors of dichloromethane. J. Photochem. Photobiol. A, Chem. 103, 153–157 (1997)

    Article  CAS  Google Scholar 

  • Tryba, B., Morawski, A.W., Inagaki, M.: A new route for preparation of TiO2-mounted activated carbon. Appl. Catal. B, Environ. 46, 203–208 (2006)

    Article  Google Scholar 

  • Velasco, L.F., Parra, J.B., Ania, C.O.: Role of activated carbon features on the photocatalytic degradation of phenol. Appl. Surf. Sci. 256, 5254–5258 (2010)

    Article  CAS  Google Scholar 

  • Wang, X.J., Hu, Z.H., Chen, Y.J., Zhao, G.H., Liu, Y.F., Wen, Z.B.: A novel approach towards high-performance composite photocatalyst of TiO2 deposited on activated carbon. Appl. Surf. Sci. 255, 3953–3958 (2009)

    Article  CAS  Google Scholar 

  • Yap, P.S., Lim, T.T., Lim, M., Srinivasan, M.: Synthesis and characterization of nitrogen-doped TiO2/AC composite for the adsorption-photocatalytic degradation of aqueous bisphenol-A using solar light. Catal. Today 151, 8–13 (2010)

    Article  CAS  Google Scholar 

  • Yu, J.C., Yu, J., Zhao, J.C.: Enhanced photocatalytic activity of mesoporous and ordinary TiO2 thin films by sulfuric acid treatment. Appl. Catal. B, Environ. 36, 31–43 (2002)

    Article  CAS  Google Scholar 

  • Zang, L., Lange, C., Abraham, I.: Amorphous microporous titania modified with platinum(IV) chloride-a new type of hybrid photocatalyst for visible light detoxification. J. Photochem. Photobiol. A, Chem. 102, 10765–10771 (1998)

    CAS  Google Scholar 

  • Zhu, B., Zou, L.D.: Trapping and decomposing of color compounds from recycled water by TiO2 coated activated carbon. J. Environ. Manag. 90, 3217–3225 (2009)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. Liu.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Li, W., Liu, S. Bifunctional activated carbon with dual photocatalysis and adsorption capabilities for efficient phenol removal. Adsorption 18, 67–74 (2012). https://doi.org/10.1007/s10450-011-9381-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10450-011-9381-z

Keywords

  • Photocatalysis
  • Adsorption
  • Activated Carbon
  • Titanium dioxide
  • Bifunctional carbon